Analytical Science and Technology (분석과학)
- Volume 10 Issue 4
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- Pages.291-299
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- 1997
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- 1225-0163(pISSN)
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- 2288-8985(eISSN)
Synthesis of 2,2'-Iminodibenzoic Acid-Cellulose Adsorbent and Its Adsorptivity of Cu(II) and Pb(II)
2,2'-Iminodibenzoic acid-cellulose 흡착제의 합성과 Cu(II) 및 Pb(II)의 흡착에 관한 연구
- Shim, Sang-Kyun (Department of Chemistry, Dankook University) ;
- Min, Byoung-Do (Department of Chemistry, Dankook University)
- Received : 1997.05.24
- Published : 1997.08.25
Abstract
2,2'-iminodibenzoic acid-cellulose was prepared by reacting 2,2'-iminodibenzoic acid salt with cellulose-Cl obtained by chlorination of cellulose-OH which is the major component of sawdust. The adsorptivity of Pb(II) and Cu(II) was studied using the synthetic chelating adsorbent. The adsorption amounts of those ions increased with increasing pH and the optimum adsorption time of metal ion was about 1hr. The adsorptivity of Pb(II) was larger than that of Cu(II).
톱밥의 주성분인 cellulose를 이용하여 cellulose-OH를 cellulose-Cl로 전환시킨 다음 킬레이트 시약인 2,2'-iminodibenzoic acid염을 반응시켜 킬레이트 흡착제인 2,2'-iminodibenzoic acid-cellulose를 합성하였다. 그리고 합성된 흡착제를 이용하여 Pb(II)와 Cu(II)의 흡착성을 연구하였다. 흡착 특성에 대한 실험 결과, pH가 증가할수록 금속 이온의 흡착량이 증가함을 알 수 있었다. 최적 흡착 반응시간은 약 1시간, 흡착능과 회수량은 Cu(II)보다 Pb(II)의 경우가 더 좋음을 알 수 있었다.