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http://dx.doi.org/10.5012/bkcs.2013.34.12.3743

Hydrothermal Synthesis, Crystal Structures and Properties of Zinc(II) Di-nuclear Complex and Copper(I) Coordination Polymer Based on Building Block 2-Phenyl-4,6-di(pyridin-2-yl)pyrimidine  

Zhao, Pusu (New Materials & Function Coordination Chemistry Laboratory, Qingdao University of Science and Technology)
Jing, Wang (New Materials & Function Coordination Chemistry Laboratory, Qingdao University of Science and Technology)
Jing, Long (New Materials & Function Coordination Chemistry Laboratory, Qingdao University of Science and Technology)
Jian, Fangfang (New Materials & Function Coordination Chemistry Laboratory, Qingdao University of Science and Technology)
Li, Yufeng (New Materials & Function Coordination Chemistry Laboratory, Qingdao University of Science and Technology)
Publication Information
Bulletin of the Korean Chemical Society / v.34, no.12, 2013 , pp. 3743-3748 More about this Journal
Abstract
A tetradentate ligand of 2-phenyl-4,6-di(pyridin-2-yl)pyrimidine (L) has been synthesized and its complexes with $ZnI_2$ and CuI have been obtained by hydrothermal method. single crystal X-ray diffraction analysis indicates that ligand L coordinates with Zn(II) ions to form a simple four-coordinate di-nuclear complex, while the complexation of L with Cu(I) constructs a one-dimensional chain polymer. The existence of $I^-$ ion hampers the L to assemble grid-type complexes with Zn(II) and Cu(I). Fluorescence spectra show that the L emits blue fluorescence while its Cu(I) polymer decrease the fluorescence intensity and Zn(II) complex quenches the fluorescence.
Keywords
Pyrimidine derivative; Zinc(II) Di-nuclear complex; Copper(I) polymer; Crystal structure; Fluorescence;
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