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Evaluation of the efficiency of cleaning method in direct contact membrane distillation of digested livestock wastewater

  • Kim, Sewoon;Park, Ki Young;Cho, Jinwoo
    • Membrane and Water Treatment
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    • v.8 no.2
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    • pp.113-123
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    • 2017
  • This study investigated effects of physical and chemical cleaning methods on the initial flux recovery of fouled membrane in membrane distillation process. A laboratory scale direct contact membrane distillation (DCMD) experiment was performed to treat digested livestock wastewater with 3.89 mg/L suspended solids, 874.7 mg/L COD, 543.7 mg/L nitrogen, 15.6 mg/L total phosphorus, and pH of 8.6. A hydrophobic PVDF membrane with an average pore size of $0.22{\mu}m$ and a porosity of 75 % was installed inside a direct contact type membrane distillation module. The temperature difference between feed and permeate side was maintained at $40^{\circ}C$ with the feed and permeate stream velocity of 0.18 m/s. The results showed that the permeate flux decreased from $22.1L{\cdot}m^{-2}{\cdot}hr^{-1}$ to $19.0L{\cdot}m^{-2}{\cdot}hr^{-1}$ after 75 hours of distillation. The fouled membrane was cleaned first by physical flushing and consecutively by chemicals with NaOCl and citric acid. After the physical cleaning the flux was recovered to 92 % as compared with the initial clean water flux of the virgin membrane. Then 94 % of the flux was recovered after cleaning by 2,000 ppm NaOCl for 90 minutes and finally 97 % of flux recovered after 3 % citric acid for 90 minutes. SEM-EDS and FT-IR analysis results presented that the foulants on the membrane surface were removed effectively after each cleaning step. The contact angle measurement showed that the hydrophobicity of the membrane surface was also restored gradually after each cleaning step to reach nearly the same hydrophobicity level as the virgin membrane.

Evaluation of Adult Lung CT Image for Ultra-Low-Dose CT Using Deep Learning Based Reconstruction

  • JO, Jun-Ho;MIN, Hyo-June;JEON, Kwang-Ho;KIM, Yu-Jin;LEE, Sang-Hyeok;KIM, Mi-Sung;JEON, Pil-Hyun;KIM, Daehong;BAEK, Cheol-Ha;LEE, Hakjae
    • Korean Journal of Artificial Intelligence
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    • v.9 no.2
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    • pp.1-5
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    • 2021
  • Although CT has an advantage in describing the three-dimensional anatomical structure of the human body, it also has a disadvantage in that high doses are exposed to the patient. Recently, a deep learning-based image reconstruction method has been used to reduce patient dose. The purpose of this study is to analyze the dose reduction and image quality improvement of deep learning-based reconstruction (DLR) on the adult's chest CT examination. Adult lung phantom was used for image acquisition and analysis. Lung phantom was scanned at ultra-low-dose (ULD), low-dose (LD), and standard dose (SD) modes, and images were reconstructed using FBP (Filtered back projection), IR (Iterative reconstruction), DLR (Deep learning reconstruction) algorithms. Image quality variations with respect to varying imaging doses were evaluated using noise and SNR. At ULD mode, the noise of the DLR image was reduced by 62.42% compared to the FBP image, and at SD mode, the SNR of the DLR image was increased by 159.60% compared to the SNR of the FBP image. Based on this study, it is anticipated that the DLR will not only substantially reduce the chest CT dose but also drastic improvement of the image quality.

Physicochemical properties of different phases of titanium dioxide nanoparticles

  • Dong, Vu Phuong;Yoo, Hoon
    • International Journal of Oral Biology
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    • v.46 no.3
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    • pp.105-110
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    • 2021
  • The physicochemical properties of crystalline titanium dioxide nanoparticles (TiO2 NPs) were investigated by comparing amorphous (amTiO2), anatase (aTiO2), metaphase of anatase-rutile (arTiO2), and rutile (rTiO2) NPs, which were prepared at various calcination temperatures (100℃, 400℃, 600℃, and 900℃). X-ray diffraction (XRD) and scanning electron microscopy (SEM) analyses confirmed that the phase-transformed TiO2 had the characteristic features of crystallinity and average size. The surface chemical properties of the crystalline phases were different in the spectral analysis. As anatase transformed to the rutile phase, the band of the hydroxyl group at 3,600-3,100 cm-1 decreased gradually, as assessed using Fourier transform infrared spectroscopy (FT-IR). For ultraviolet-visible (UV-Vis) spectra, the maximum absorbance of anatase TiO2 NPs at 309 nm was blue-shifted to 290 nm at the rutile phase with reduced absorbance. Under the electric field of capillary electrophoresis (CE), TiO2 NPs in anatase migrated and detected as a broaden peak, whereas the rutile NPs did not. In addition, anatase showed the highest photocatalytic activity in an UV-irradiated dye degradation assay in the following order: aTiO2 > arTiO2 > rTiO2. Overall, the phases of TiO2 NPs showed characteristic physicochemical properties regarding size, surface chemical properties, UV absorbance, CE migration, and photocatalytic activity.

Performance Evaluation of Mortar Containing Mechanochemical Treated Self-Healing Admixtures (기계·화학 처리 자기치유 혼화재가 포함된 모르타르의 성능평가)

  • Park, Dong-Cheol;Kwon, Hyuk;Lee, Jung-Woo;Hwang, Moo-Yeon;Kim, Tae-Hyung
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.3
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    • pp.367-374
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    • 2021
  • In this study, the applicability of mechanochemical process for the manufacture of self-healing admixtures and the effect of mechanochemical process on the self-healing performance were evaluated. The self-healing admixtures were adopted as a highly reactive materials(expansive agent, swelling material and crystal growth agent) for mechanochemical processes. The self-healing admixtures for the mechanochemical process application were evaluated by X-Ray Diffraction and Fourier Transform Infrared Spectroscopy analysis, water permeability performance was used to evaluate self-healing performance of mortar. As a result of the evaluation, the self-healing performance of the WM(With-Mortar)3 sample to which mechanochemical process increased by 4.1% compared to the WM1 sample that was not treated, and the average healing index was 94.3%.

Synthesis and Characterization of Swallow-Tail Perylene Bisimide as Organic Phosphor for Hybrid LED (Hybrid LED용 유기 형광체로서의 Swallow-Tail Perylene Bisimide 제조 및 특성 연구)

  • Jung, Sung Bong;Jeong, Yeon Tae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.32 no.1
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    • pp.86-92
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    • 2019
  • Although perylene bisimide derivatives have advantages such as excellent thermal stability and high luminance efficiency, they have poor solubility characteristics in organic solvents. In this research, in order to improve the solubility characteristics, we prepared perylene bisimide derivatives (1C) and (2C) with swallow-tail substituted imide, which is known to lead to excellent solubility. The structures and properties of swallow-tail perylene bisimide (1C) and (2C) were analyzed by $^1H-NMR$, FT-IR, UV/Vis spectroscopy, and thermogravimetric analysis (TGA). The maximum absorption wavelengths of (1C) and (2C) in the UV/Vis spectrum were 558 nm and 556 nm, respectively, and the maximum emission wavelengths were 602 nm and 600 nm, respectively. In the TGA, (1C) demonstrated good thermal stability with less than 5 wt% weight loss up to $242^{\circ}C$. In the solubility test, (1C) and (2C) exhibited solubilities of more than 5 wt% in chloroform, ethyl acetate, and dimethylformamide, but not in methanol. When the compounds (1C) and (2C) were mixed with PMMA (polymethyl methacrylate), thin films showed peaks at 679 nm and 677 nm, respectively, in the photoluminescence spectra. (1C) was found to be a possible candidate as red organic phosphor for hybrid LEDs.

Production of Polypyrrole Coated PVA Nanoweb Electroconductive Textiles for Application to ECG Electrode (심전도용 전극으로의 적용을 위한 폴리피롤 코팅 PVA 나노웹 전기전도성 텍스타일의 제조)

  • Kim, Jae-Hyun;Yang, Hyuk-Joo;Cho, Gil-Soo
    • Fashion & Textile Research Journal
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    • v.21 no.3
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    • pp.363-369
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    • 2019
  • This study developed electroconductive textiles by coating polypyrrole to PET nonwoven-based Polyvinyl Alcohol (PVA) nanoweb made by electrospinning and applying the developed electrotextiles as ECG Electrodes. To find the optimum coating conditions for high electrical conductivity, the ratios of 2.6-Naphthalenedisulfonic acid with Disodium Salt (NDS) vs Ammonium Persulfate (APS) as an oxidant and a doping agent in the solution were changed from 3:7 to 7:3; the immersion time of the specimen in the solution was 1 hour. PVA nanowebs coated with polypyrrole under various conditions were filmed with FE-SEM. FT-IR analysis was also performed to examine the presence of polypyrrole nanoparticles in the PVA nanoweb. The electrical resistance of the treated specimens were measured with a Multimeter. Consequently, the PVA Nano Web was undamaged even after heat treatment that allowed for coating. Uniform polypyrrole nanoparticles then formed on the surface of the PVA nanoweb after coating. The measured electrical resistance was shown to be at least $12K{\Omega}/{\Box }$ from a maximum of $3,456K{\Omega}/{\Box }$. The proper amount of NDS content had a positive effect on the conductivity improvement of electroconductive textiles; in addition, the highest electrical conductivity was achieved with a ratio of 3:7 between NDS and APS.

Clinical Effectiveness of Acupuncture in the Treatment of Non-Alcoholic Fatty Liver Disease: A Systematic Review (비알코올성 지방간 질환에 대한 침치료의 효과 : 체계적 고찰)

  • Hyun, Joon;Lee, Joo-bok;Kim, So-yeon;Han, Chang-woo
    • The Journal of Internal Korean Medicine
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    • v.39 no.6
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    • pp.1206-1224
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    • 2018
  • Purpose: This systematic review was planned and performed in order to determine the clinical effectiveness of acupuncture for non-alcoholic fatty liver disease (NAFLD). Methods: We searched related randomized controlled trials in several medical online databases, including China National Knowledge Infrastructure (CNKI), Excerpta Medica dataBASE (EMBASE), Public/Publisher MEDLINE (PubMed), Cochrane Central Register of Controlled Trials (CENTRAL), National Digital Science Library (NDSL), and Research Information Sharing Service (RISS). NAFLD related outcomes were extracted from the included trials and meta-analyzed. Results: From the 8 included trials, the values of the following examinations were extracted: liver ultrasonography, liver CT, body fat CT, aspartate transaminase (AST), alanine transaminase (ALT), gamma-glutamyltransferase (GGT), total cholesterol (TC), triglyceride (TG), low density lipoprotein (LDL) cholesterol, high density lipoprotein (HDL) cholesterol, fasting blood sugar (FBS), hosmeostatic model assessment for insulin resistance (HOMA-IR), weight, body mass index (BMI), waist hip ratio (WHR), obesity degree, body fat mass, body fat rate, leptin, malondialdehyde (MDA), and super oxide dismutase (SOD). In the 4 outcomes, cure rate in liver ultrasonography (RR=1.56; 95%CI=1.05~2.31; P=0.03), cure rate in liver CT (RR=2.23; 95%CI=1.33~3.72; P=0.002), TC (MD=-0.78; 95%CI=-1.41~-0.15; P=0.02), and TG (MD=-2.05; 95%CI=-3.88~-0.21; P=0.03), acupuncture was more effective than the control intervention. Conclusions: In this meta-analysis, acupuncture relieved hepatic steatosis, and reduced TC, and TG in NAFLD patients. more well-planned studies are still needed due to the heterogeneity and the considerable methodological flaws in the analyzed trials.

Preparation and Characterization of SPAES/SPVdF-co-HFP Blending Membranes for Polymer Electrolyte Membrane Fuel Cells (고분자 전해질 연료전지용 술폰화된 폴리(아릴렌 이써 설폰)/SPVdF-co-HFP 브렌딩 멤브레인의 제조 및 특성 분석)

  • PARK, CHUL JIN;KIM, AE RHAN;YOO, DONG JIN
    • Journal of Hydrogen and New Energy
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    • v.30 no.3
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    • pp.227-236
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    • 2019
  • In this work, preparation and characterizations of hybrid membranes containing sulfonated poly(arylene ether sulfone) (SPES) and sulfonated poly(vinylidene fluoride-co-hexafluoropropylene) (SPVdF-co-HFP) (20, 30 or 40 wt%) were carried out. The structure of hybrid membranes was confirmed using X-ray diffraction (XRD) analysis and the Fourier transform infrared (FT-IR) spectroscopy. The prepared SPAES/SPVdF-30 membrane exhibits higher ionic conductivity of 68.9 mS/cm at $90^{\circ}C$ and 100% RH. Besides, the other studies showed that the hybrid membrane has good oxidation stability, thermal stability, and mechanical stability. Thus, we believe that the prepared hybrid membrane is suitable for the development of membranes for fuel cell applications.

Shield Ratio and Thrust Performance Analysis According to The S-Type Nozzle of The Centerline Shape (S-형 노즐 형상의 중심선 형태에 따른 차폐율과 추력 성능 해석)

  • Jin, Juneyub;Park, Youngseok;Kim, Jaewon;Lee, Changwook
    • Journal of the Korean Society of Propulsion Engineers
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    • v.25 no.3
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    • pp.42-55
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    • 2021
  • In this study, the effect of nozzle performance according to the selection of the center line equation. Three of S-type nozzles and three of double S-type nozzles were designed using the curve equation and design parameters, and the nozzle shielding performance was evaluated using the shielding ratio definition. In order to analyze the internal flow of the nozzle, the characteristics of the velocity distribution and pressure distribution were studied, and the nozzle performance was evaluated through the total thrust ratio(f) and the nozzle insulation efficiency coefficient(η). On the other hand, the centerline with a sharply change in curvature at the entrance has a low nozzle performance and a high shielding rate. The double S-type nozzle is excellent nozzle performance and shielding rate by using a smooth centerline at the first curvature.

Synthesis of Polyurethane Foam at Room Temperature by Controlling the Gelling Reaction Time (겔화 반응 시간 조절을 통한 상온에서의 폴리우레탄 폼 합성)

  • Lee, Hojoon;Oh, Chungik;Liow, Chi Hao;Kim, Soyeon;Han, Youngjoon;Oh, Min-Seok;Joo, Hyeong-Uk;Chang, Soo-Ho;Hong, Seungbum
    • Applied Chemistry for Engineering
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    • v.31 no.6
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    • pp.630-634
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    • 2020
  • We developed a processing recipe to synthesize flexible polyurethane foam with a pore size of 335 ± 107 ㎛. The gelling reaction time was varied from 0 to 30 minutes and the physical properties of the foam were evaluated. The gelling reaction where the polypropylene glycol and tolylene 2,4-diisocyanate (TDI) were reacted to form urethane prepolymer, proceeded until a chemical blowing agent, deionized water, was introduced. Fourier transform infrared (FT-IR) spectra showed that the composition of the foam did not change but the foam height reached a peak value when the gelling reaction time was 10 minutes. We found that increasing the gelling time lessened the coalescence and helped the formation of cells. Lastly, the repeatability of polyurethane foam was confirmed by one-way analysis of variance (ANOVA) by synthesizing ten identical polyurethane foams under the same experimental conditions, including the gelling reaction time. Overall, the new time parameter in-between the gelling and blowing reactions will give extra stability in manufacturing identical polyurethane foams and can be applied to various polyurethane foam processes.