• Title/Summary/Keyword: IPN

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AC Dielectric Breakdown Properties and Mechanical Properties of Interpenetrating Polymer Network Epoxy Resin (상호침입망목 에폭시수지의 교류 절연파괴특성 및 기계적 특성)

  • 이덕진;김명호;김경환;심종탁;손인환;김재환
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1995.11a
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    • pp.320-323
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    • 1995
  • In this paper, in order to improve withstand voltage properties of epoxy resin, IPN(interpenetrating polymer network) method was introduced and the influence was investigated. The sing1e network structure specimen(E series), simultaneous interpenetrating polymer network specimen(EMF series) and pseudo interpenetrating polymer network(EMP series) specimen were manufactured. In order to understand the internal structure properties, scanning electron microscopy method was utilized, rind glass transition temperature was measured. Also, AC voltage dielectric strength, tensile strength and impact strength were measured to investigate influence upon electrical and mechanical properties. As a result, it was confirmed that simultaneous interpenetrating polymer network specimen was the most execellent.

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Efficiency Evaluation of the Unconditional Maximum Likelihood Estimator for Near-Field DOA Estimation

  • Arceo-Olague, J.G.;Covarrubias-Rosales, D.H.;Luna-Rivera, J.M.
    • ETRI Journal
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    • v.28 no.6
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    • pp.761-769
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    • 2006
  • In this paper, we address the problem of closely spaced source localization using sensor array processing. In particular, the performance efficiency (measured in terms of the root mean square error) of the unconditional maximum likelihood (UML) algorithm for estimating the direction of arrival (DOA) of near-field sources is evaluated. Four parameters are considered in this evaluation: angular separation among sources, signal-to-noise ratio (SNR), number of snapshots, and number of sources (multiple sources). Simulations are conducted to illustrate the UML performance to compute the DOA of sources in the near-field. Finally, results are also presented that compare the performance of the UML DOA estimator with the existing multiple signal classification approach. The results show the capability of the UML estimator for estimating the DOA when the angular separation is taken into account as a critical parameter. These results are consistent in both low SNR and multiple-source scenarios.

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Dark Conductivity in Semi-Insulating Crystals of CdTe:Sn

  • Makhniy, V.P.;Sklyarchuk, V.M.;Vorobiev, Yu.V.;Horley, P.P.
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.15 no.2
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    • pp.243-248
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    • 2015
  • We prepared semi-insulating CdTe for radiation detectors by isothermal annealing of single crystals grown by Bridgeman technique in a sealed quartz container filled with Sn vapor. The resistivity of CdTe:Sn samples thus obtained was of order of $10^{10}Ohm{\cdot}cm$ at room temperature with electrons lifetime of $2{\times}10^{-8}$ s, which is appropriate for the applications desired. Analysis of electric transport characteristics depending on temperature, sample thickness and voltage applied revealed the presence of traps with concentration of about $(4-5){\times}10^{12}cm^{-3}$ with the corresponding energy level at 0.8 - 0.9 eV counted from the bottom of conduction band. The conductivity was determined by electron injection from electrodes in space charge limited current mode.

Synthesis and Physical Properties of pH-sensitive Semi-IPN Hydrogels Based on Poly( dimethylaminoethyl methacrylate-co-PEG dimethacrylate) and Poly(acrylic acid)

  • Kim Goo-Myun;Jo Won-Ho
    • Fibers and Polymers
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    • v.7 no.3
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    • pp.223-228
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    • 2006
  • Hydrogels of semi-interpenetrating polymer networks (semi-IPNs) were prepared by two step reactions. Dimethylaminoethyl methacrylate (DMAM) and poly(ethylene glycol)-dimethacrylate (PEGDM) were copolymerized to yield hydrogels, and then acrylic acid (AA) monomer were adsorbed in the hydrogels followed by polymerization of AA to produce semi-IPNs. The swelling behavior of semi-IPNs depends largely on pH of medium, showing that the degree of swelling of the semi-IPNs exhibits a minimum at pH 6.0. It is observed that the elastic modulus of semi-IPNs is closely related to its swelling behavior.

Electrochemical Properties of Lithium-Ion Polymer Battery with PMMA IPN-Based Gel Polymer Electrolyte (PMMA IPN계 겔폴리머전해질을 채용한 리튬이온폴리머전지의 전기화학적 특성)

  • 김현수;신정한;나성환;엄승욱;문성인;김상필
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.11
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    • pp.994-1000
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    • 2003
  • In this study, gel polymer electrolytes (GPE) with semi-interpenerating network of poly (methyl methacrylate) and hexanediol dimethacrylate were synthesized and their electrochemical performances were evaluated. LiCoO$_2$/GPE/graphite cells were prepared and their performances depending on discharge currents and temperatures were evaluated. The precursor containing 5 vol% curable mixture had a low viscosity relatively. GPE showed good electrochemical stability up to potential of 4.8 V vs. Li/Li$\^$+/. Ionic conductivity of the gel polymer electrolyte at room temperature and -20$^{\circ}C$ was ca. 5.9 and 1.4${\times}$10$\^$-3/ Scm$\^$-1/, respectively. LiCoO$_2$/GPE/graphite cells showed good rate capability, low-temperature performance and cycleability.

Dielectric Breakdown Characteristics of Epoxy Composites due to Voltage Wave Pattern (전압파형에 따른 에폭시 복합재료의 절연파괴특성)

  • Kim, M.H.;Park, C.O.;Lee, Y.S.;Lee, D.J.;Kim, J.H.
    • Proceedings of the KIEE Conference
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    • 1997.07e
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    • pp.1767-1769
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    • 1997
  • In this paper, interpenetrating polymer network method was introduced in order to improve withstand voltage properties of epoxy resin. The single network structure specimen(E series), simultaneous interpenetrating polymer network specimen(EM series) and pseudo interpenetrating polymer network(EMP series) specimen were manufactured. In order to investigate influence upon electrical properties, dc, ac, and impulse voltage dielectric strength were measured. As a result, it was confirmed that electrical properties of epoxy composites can be superior as IPN introduced to it bring about firm and high density of inner structure.

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Ferromagnetic Domain Behaviors in Mn doped ZnO Film

  • Soundararajan, Devaraj;Santoyo-Salazar, Jaime;Ko, Jang-Myoun;Kim, Ki-Hyeon
    • Journal of Magnetics
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    • v.16 no.3
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    • pp.216-219
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    • 2011
  • Mn doped ZnO films were prepared on Si (100) substrates using sol-gel method. The prepared films were annealed at $550^{\circ}C$ for decomposition and oxidation of the precursors. XRD analysis revealed the presence of ZnMnO hexagonal wurtzite phase along with the presence of small quantity of $ZnMn_2O_3$ secondary phase and poor crystalline nature. The 2D, 3D views of magnetic domains and domain profiles were obtained using magnetic force microscopy at room temperature. Rectangular shaped domains with an average size of 4.16 nm were observed. Magnetic moment measurement as a function of magnetic field was measured using superconducting quantum interference device (SQUID) magnetometry at room temperature. The result showed the ferromagnetic hysteresis loop with a curie temperature higher than 300 K.

A study on the AC dielectric breakdown characteristics and mechanical characteristics of interpenetraing polymer network epoxy composites (상호침입망목 에폭시 복합재료의 교류절연파괴 특성 및 기계적 특성에 관한 연구)

  • 손인환;이덕진;김명호;김경환;김재환
    • Electrical & Electronic Materials
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    • v.9 no.7
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    • pp.702-707
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    • 1996
  • In this paper, in order to improve the withstand voltage properties of epoxy resin, IPN(interpenetrating polymer network) method was introduced and the influence was investigated. The single network structure specimen(E series), simultaneous interpenetrating polymer network specimen(EM series) and pseudo interpenetrating polymer network(EMP series) specimen were manufactured. In order to understand the internal structure properties, scanning electron microscopy method was utilized, and glass transition temperature was measured. Also, AC voltage dielectric breakdown strength, tensile strength and impact strength were measured to investigate the influence upon electrical and mechanical properties. As a result, it was confirmed that simultaneous interpenetrating polymer network specimen was the most execellent.

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Pulsatile Interpenetrating Polymer Networks Hydrogels Composed of Poly(vinyl alcohol) and Poly(acrylic acid) ; Synthesis, Characterization, and its Application to Drug Delivery Systems

  • Shin, Heung-Soo;Kim, So-Yeon;Lee, Young-Moo
    • Proceedings of the KOSOMBE Conference
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    • v.1996 no.11
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    • pp.281-285
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    • 1996
  • Pulsatile swelling behaviors and their application to drug delivery system were studied by using interpenetrating polymer networks(IPN) hydrogels constructed with poly(vinyl alcohol) and poly(acrylic acid). The PVA/PAAc IPNs hydrogels were symthesized by UV irradiation tallowed by repetitive freezing and thawing method. These hydrogels showed pH and temperature sensitive swelling behaviors. From the release experiment, the release amount of model drug incorporated into these hydrogels showed pulsatile patterns. Permeability coefficients obtained by various solutes differed in response to changes of permeation conditions.

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Semi-interpenetrating Solid Polymer Electrolyte for LiCoO2-based Lithium Polymer Batteries Operated at Room Temperature

  • Nguyen, Tien Manh;Suk, Jungdon;Kang, Yongku
    • Journal of Electrochemical Science and Technology
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    • v.10 no.2
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    • pp.250-255
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    • 2019
  • Poly(ethylene oxide) (PEO)-based solid polymer electrolytes (SPEs) show promise for improving the lithium ion battery safety. However, due to oxidation of the PEO group and corrosion of the Al current collector, PEO-based SPEs have not previously been effective for use in $LiCoO_2$ (LCO) cathode materials at room temperature. In this paper, a semi-interpenetrating polymer network (semi-IPN) PEO-based SPE was applied to examine the performance of a LCO/SPE/Li metal cell at different voltage ranges. The results indicate that the SPE can be applied to LCO-based lithium polymer batteries with high electrochemical performance. By using a carbon-coated aluminum current collector, the Al corrosion was mostly suppressed during cycling, resulting in improvement of the cell cycle stability.