• 제목/요약/키워드: I-solution

검색결과 3,969건 처리시간 0.031초

열화학 황-요오드 수소 생산 공정의 요오드 결정화기 설계를 위한 결정 침강 모델링 (Crystal Sinking Modeling for Designing Iodine Crystallizer in Thermochemical Sulfur-Iodine Hydrogen Production Process)

  • 박병흥;정성욱;강정원
    • Korean Chemical Engineering Research
    • /
    • 제52권6호
    • /
    • pp.768-774
    • /
    • 2014
  • 황-요오드(Sulfur-Iodine, SI) 공정은 물을 분해시켜 수소를 생산하는 열화학 공정으로 공정에 사용되는 황과 요오드는 재순환된다. SI 공정 중 요오드가 분리 순환되는 Section III에서는 공정 효율 개선을 위해 다양한 방법이 개발되고 있다. EED(electro-electrodialysis)를 이용한 방법은 추가적인 화합물이 필요하지 않는 공정으로 Section III의 효율을 높일 수 있으나 공정 흐름에 포함된 요오드에 의해 상당한 부하가 걸리게 된다. 이를 해결하기 설계를 위한 기초 자료 제거 공정으로 결정화 방법이 고려되고 있다. 본 연구에서는 요오드 결정화 반응기 설계를 위한 기초 자료 확보를 위해 $I_2$ 포화 $HI_x$ 용액에서 요오드 결정의 침강 속도를 모델링 하였다. $HI_x$ 용액 조성은 열역학 모델인 UVa를 이용하여 결정하였으며 용액 물성은 순수한 물성들과 상관관계식을 활용하여 추산하였다. Multiphysics 전산툴을 이용하여 침강에 따른 속도 변화를 계산하였으며 요오드 직경과 온도에 따른 변화를 추산하였다. 직경(1.0~2.5 mm)과 온도($10{\sim}50^{\circ}C$) 범위에서 요오드는 0.5 m/s 내외의 종말 속도를 보이며 이 속도는 용액의 점도 보다 밀도에 더 크게 영향을 받는 것으로 나타났다.

Aggregation of Fibroin Molecular in Aqueous Solution

  • Son, Hyo-Jin;Hur, Won;Jeong, Jae-Ho;Kim, Ji-Young
    • 한국생물공학회:학술대회논문집
    • /
    • 한국생물공학회 2003년도 생물공학의 동향(XIII)
    • /
    • pp.634-638
    • /
    • 2003
  • For the investigation of the properties of aqueous fibroin solution, the variation of molecular weight by agregation of silk, morphology and difference of molecular weight at pI value was investigated. The distribution of molecular weight investigated using gel filtration chromatography and formation of aggregates were confirmed by using Field emission scanning electron microscope. The precipitation of fibroin solution at its pI value was compared by molecular weight distribution and the formation of fibroin aggregated were investigated. The aggregation kinetics were investigated at various condition.

  • PDF

천연염료에 관한 연구 ( I ) -자근색소의 추출 및 자외가시분광특성- (Studies on the Natural dyes( I ) -extraction and UV, VIS spectrum of coloring matter of gromwell-)

  • 조경래
    • 한국의류학회지
    • /
    • 제11권3호
    • /
    • pp.25-32
    • /
    • 1987
  • The purpose of this study is to investigate optical behaviour of coloring matter of gromwell -extracted by water, acetic acid/methanol, and the other solvents. The results were as following: UV, VIS spectra of the solution of coloring matter of gromwell extracted by water at below $80^{\circ}C$ did not reveal in the range of the visible light wavelength and coloring matter of gromwell decomposed to blue particle at $95^{\circ}C$. The solution extracted by acetic acid/methanol was tinged with reddish purple and its spectra shifted to the longer wavelength according to increase of the solvent temperature. The color of the solution extracted by water became extinct as time went by, but that extracted by acetic acid/methanol kept up original color. In case of dried gromwell, extraction by acetic acid/methanol was easier than by water, and variation of spectra did not appear but showed hypochromic shift.

  • PDF

EXISTENCE AND UNIQUENESS THEOREMS OF SECOND-ORDER EQUATIONS WITH INTEGRAL BOUNDARY CONDITIONS

  • Bougoffa, Lazhar;Khanfer, Ammar
    • 대한수학회보
    • /
    • 제55권3호
    • /
    • pp.899-911
    • /
    • 2018
  • In this paper, we consider the second-order nonlinear differential equation with the nonlocal boundary conditions. We first reformulate this boundary value problem as a fixed point problem for a Fredholm integral equation operator, and then present a result on the existence and uniqueness of the solution by using the contraction mapping theorem. Furthermore, we establish a sufficient condition on the functions ${\mu}$ and $h_i$, i = 1, 2 that guarantee a unique solution for this nonlocal problem in a Hilbert space. Also, accurate analytic solutions in series forms for this boundary value problems are obtained by the Adomian decomposition method (ADM).

ASYMPTOTIC BEHAVIORS OF FUNDAMENTAL SOLUTION AND ITS DERIVATIVES TO FRACTIONAL DIFFUSION-WAVE EQUATIONS

  • Kim, Kyeong-Hun;Lim, Sungbin
    • 대한수학회지
    • /
    • 제53권4호
    • /
    • pp.929-967
    • /
    • 2016
  • Let p(t, x) be the fundamental solution to the problem $${\partial}^{\alpha}_tu=-(-{\Delta})^{\beta}u,\;{\alpha}{\in}(0,2),\;{\beta}{\in}(0,{\infty})$$. If ${\alpha},{\beta}{\in}(0,1)$, then the kernel p(t, x) becomes the transition density of a Levy process delayed by an inverse subordinator. In this paper we provide the asymptotic behaviors and sharp upper bounds of p(t, x) and its space and time fractional derivatives $$D^n_x(-{\Delta}_x)^{\gamma}D^{\sigma}_tI^{\delta}_tp(t,x),\;{\forall}n{\in}{\mathbb{Z}}_+,\;{\gamma}{\in}[0,{\beta}],\;{\sigma},{\delta}{\in}[0,{\infty})$$, where $D^n_x$ x is a partial derivative of order n with respect to x, $(-{\Delta}_x)^{\gamma}$ is a fractional Laplace operator and $D^{\sigma}_t$ and $I^{\delta}_t$ are Riemann-Liouville fractional derivative and integral respectively.

Recent Advances in DNA Sequencing by End-labeled Free-Solution Electrophoresis (ELFSE)

  • Won, Jong-In
    • Biotechnology and Bioprocess Engineering:BBE
    • /
    • 제11권3호
    • /
    • pp.179-186
    • /
    • 2006
  • End-Labeled Free-Solution Electrophoresis (ELFSE) is a new technique that is a promising bioconjugate method for DNA sequencing (or separation) and genotyping by both capillary and microfluidic device electrophoresis. Because ELFSE enables high-resolution electrophoretic separation in aqueous buffer alone (i.e., without a polymer matrix), it eliminates the need to load viscous polymer networks into electrophoresis microchannels. To achieve microchannel DNA separations with high performance, ELFSE requires monodisperse perturbing entities (i.e., drag-tags), which create a large amount of frictional drag when pulled behind DNA during free-solution electrophoresis, and which have other properties suitable for microchannel electrophoresis. In this article, the theoretical concepts of ELFSE and the required characteristics of the drag-tag molecules for the ultimate performance of ELFSE are reviewed. Additionally, the merits and limitations of current drag-tags are also discussed in the context of recent experimental data of ELFSE separation (or sequencing).

천이박리유동의 직접수치모사 Part I:주 불안정성 (Drirect Numerical Simulation of Transitional Separated Flows Part I:Primary Instability)

  • 양경수
    • 대한기계학회논문집B
    • /
    • 제20권9호
    • /
    • pp.2965-2972
    • /
    • 1996
  • Transitional flow in an obstructed channel is investigated using numerical simulation. Two-dimensional thin obstacles are mounted symmetrically in the vertical direction and periodically in the streamwise direction. Flow separation occurs at the tip of the sharp obstacles. Depending on the Reynolds number, the flow undergoes Hopf bifurcation as the primary instability leading to a two-dimensional unsteady periodic solution. At higher Reynolds numbers, the unsteady solution exhibits a symmetry-breaking bifurcation which results in an unsteady asymmetric solution. The results are compared with experiments currently available, and show a good agreement.

Triangular units based method for simultaneous optimizations of planar trusses

  • Mortazavi, Ali;Togan, Vedat
    • Advances in Computational Design
    • /
    • 제2권3호
    • /
    • pp.195-210
    • /
    • 2017
  • Simultaneous optimization of trusses which concurrently takes into account design variables related to the size, shape and topology of the structure is recognized as highly complex optimization problems. In this class of optimization problems, it is possible to encounter several unstable mechanisms throughout the solution process. However, to obtain a feasible solution, these unstable mechanisms somehow should be rejected from the set of candidate solutions. This study proposes triangular unit based method (TUBM) instead of ground structure method, which is conventionally used in the topology optimization, to decrease the complexity of search space of simultaneous optimization of the planar truss structures. TUBM considers stability of the triangular units for 2 dimensional truss systems. In addition, integrated particle swarm optimizer (iPSO) strengthened with robust technique so called improved fly-back mechanism is employed as the optimizer tool to obtain the solution for these class of problems. The results obtained in this study show the applicability and efficiency of the TUBM combined with iPSO for the simultaneous optimization of planar truss structures.

도전성 고분자 Poly( 3- Alkylthiophene ) 용액의 광학적 성질 (Optical Properties of Conducting Polymer Poly(3-Alkylthiophene) Solution)

  • 박정학;사공건;임장석;김태성;구할본
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 1990년도 하계학술대회 논문집
    • /
    • pp.221-223
    • /
    • 1990
  • In this study, we have studied the optioal properties and $I_2$ doping effect of Poly(3-Akkylthiophene) solution. The end of speotrum absorbance on the solutions of Poly(3 - Octylthiophene), Poly (3-Dodecylthiophene) and Poly(3-Dooooylthiophene) was dependent on temperature. It is bellved that conrod-coil transition dependent on temperature was rod-coil transition. And absortance peak of Poly (3-Dodecylthiophene) in dichloromethane solution increased with increasing the $I_2$ dopant.

  • PDF

마이크로컴퓨터에 의한 시설재배의 자동화에 관한 기초연구(I) (A Fundamental Study for the Automatic Control System in Greenhouse Using Microcomputer(I))

  • 김철수;김진현
    • Journal of Biosystems Engineering
    • /
    • 제19권2호
    • /
    • pp.99-111
    • /
    • 1994
  • Automatic control system using microcomputer that have been studied in greenhouse, however, it was very difficult operation with success due to handicap for a various conditions and cultivated plants. This study was performed in order to develop of the basic program and hardware system for automatic control in greenhouse, such as automatic supplying of water, liquefied fertilizer solution and chemical solution. The results were summarized as follows. 1. The program for soil moisture control used by the switch type tensiometer was well operated. 2. The proximity switch was applied as well to water level control but it was very expensive, so low-priced sensor has to be developed. 3. The water meter was not excellent for mixing control of liquefied fertilizer, chemical and water, so water meter for only agricalture has to be developed. 4. Interface system for this study was suited to the developed controller. 5. Automatic control system to supply for water, liquefied fertilizer and chemical solution that was well operated as a fundamental study for product of controller.

  • PDF