• Title/Summary/Keyword: I/O ratios

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The Control of Side Reactions in Bunsen Reaction Section of Sulfur-Iodine Hydrogen Production Process (황-요오드 수소 생산 공정의 분젠 반응 부분에서 부반응 제어)

  • Lee, Kwang-Jin;Hong, Dong-Woo;Kim, Young-Ho;Park, Chu-Sik;Bae, Ki-Kwang
    • Transactions of the Korean hydrogen and new energy society
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    • v.19 no.6
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    • pp.490-497
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    • 2008
  • For continuous operation of the sulfur-iodine(SI) thermochemical cycle, which is expected practical method for massive hydrogen production, suggesting operation conditions at steady state is very important. Especially, in the Bunsen reaction section, the Bunsen reaction as well as side reactions is occurring simultaneously. Therefore, we studied on the relation between the variation of compositions in product solution and side reactions. The experiments for Bunsen reaction were carried out in the temperature range, from 268 to 353 K, and in the $I_2/H_2O$ molar ratio of $0.094{\sim}0.297$ under a continuous flow of $SO_2$ gas. As the result, sulfur formed predominantly with increasing temperature and decreasing $I_2/H_2O$ molar ratios. The molar ratios of $H_2O/H_2SO_4$ and $HI/H_2SO_4$ in global system were decreased as the more side reaction occurred. A side reactions did not appear at $I_2/H_2O$ molar ratios, saturated with $I_2$, irrespective of the temperature change. We concluded that it caused by the increasing stability of an $I_{2x}H^+$ complex and a steric hindrance with increasing $I_2/HI$ molar ratios.

PHOTOIONIZATION MODELS OF THE WARM IONIZED MEDIUM IN THE GALAXY (우리은하 중온 이온화 매질의 광이온화 모델)

  • Seon, Kwang-Il
    • Publications of The Korean Astronomical Society
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    • v.22 no.4
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    • pp.89-95
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    • 2007
  • The warm ionized medium (WIM) outside classical H II regions is a fundamental gas-phase constituent of the Milky Way and other late-type spiral galaxies, and is traced by faint emission lines at optical wavelengths. We calculate the photoionization models of the WIM in the Galaxy by a stellar UV radiation with the effective temperature 35,000 K assuming not only spherical geometry but also plane parallel geometry, and compare the results with the observed emission line ratios. We also show the dependence of the emission line ratios on various gas-phase abundances. The emergent emission-line ratios are in agreement with the average-values of observed ratios of [S II] ${\lambda}6716/H{\alpha}$, [N II] ${\lambda}6583/H{\alpha}$, [O I] ${\lambda}6300/H{\alpha}$, [O III] ${\lambda}5007/H{\alpha}$, He I ${\lambda}5876/H{\alpha}$. However, their extreme values could not be explained with the photoionization models. It is also shown that the addition of all stellar radiation from the OB stars in the Hipparcos stellar catalog resembles that of an O7-O8 type star.

The narrow emission-line properties of radio-loud AGNs in the SDSS archive

  • Son, Donghoon;Woo, Jong-Hak
    • The Bulletin of The Korean Astronomical Society
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    • v.40 no.1
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    • pp.74.4-75
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    • 2015
  • We investigate the narrow emission-line ratios of 64 radio-loud (log $L_{1.4GHz}$ > 40) AGNs available in the SDSS archive, in order to examine whether there is a systematic difference in the accretion disk condition of radio-loud AGNs compared to radio-quiet AGNs and compact young radio-loud AGNs. The fluxes of narrow-emission lines, [O II], [Ne III], [O III], [O I], [Ar III], are measured for diagnostics. Based on the [O I]/[O III] and [Ar III]/[O III] ratios with photoionization models, we constrain the states of the accretion disk. We will present the results of the emission-line diagnostics.

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Exposure Assessments for Children in Homes and in Daycare Centers to NO2, PMs and Black Carbon

  • Lee, Jae Young;Kim, Changhyeok;Kim, Jongbum;Ryu, Sung Hee;Bae, Gwi-Nam
    • Asian Journal of Atmospheric Environment
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    • v.12 no.3
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    • pp.204-214
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    • 2018
  • Indoor air quality was investigated in homes and daycares located in areas with heavy traffic in Seoul, South Korea from November 2013 to January 2014. Indoor and outdoor air quality measurements were collected for 48 hours in four children's homes and daycare centers. The I/O ratio (Indoor to outdoor ratio) for each major air pollutant ($NO_2$, black carbon, $PM_{10}$, and $PM_{2.5}$) was calculated, and $NO_2$ and $PM_{10}$ concentration profiles were analyzed based on indoor activity diaries recorded during the 48 hours. Most I/O ratios for $NO_2$, black carbon, $PM_{10}$, and $PM_{2.5}$ at daycare centers were less than one. At homes, I/O ratios for black carbon, $PM_{10}$, and $PM_{2.5}$ were less than one; however, most I/O ratios for $NO_2$ were greater than one due to the usage of gas stoves. The children's exposure to indoor air pollutants was calculated using a time-weighted average exposure method, and the daily intake level for each pollutant was determined.

Comparison of Phosphorus and Nitrogen Removal Characteristics between A2/O and Modified Phostrip Processes (A2/O공정과 수정 Phostrip공정과의 질소 및 인제거 특성비교)

  • Kim, Kwang-Soo;Kim, I-Tai
    • Journal of Korean Society on Water Environment
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    • v.21 no.6
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    • pp.664-668
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    • 2005
  • An experimental study for the comparison of nitrogen and phosphorus removal efficiencies between $A^2/O$ and modified Phostrip (M-Phostrip process) were carried out with bench-scale reactors. In case of nitrogen removal efficiencies both of processes showed similar ones when influent organic loadings were high. However, M-phostrip process was more effective than $A^2/O$ at low organic loadings. This is why M-phostrip process consumes the whole mass of influent organics as a carbon sources for denitrification in anoxic reactor but the anoxic reactor of $A^2/O$ process utilizes the residual carbon followed by consumming a part of influent carbon for phosphorus release in anaerobic reactor. $A^2/O$ process required the influent COD/T-P and COD/TKN ratios were more than 56 and 10, respectively, to take place the phosphorus release in anaerobic process and phosphorus uptake in oxic process. However, the luxury uptake of phosphorus in M-phostrip process was not affected by influent COD/T-P and COD/TKN ratios and the adverse effect of nitrate in return sludge introduced to the p-stripper from the 2nd clarifier was not significant due to the configurational advantage of the p-stripper.

Parametric Sensitivity Analyses of Linear System relative to the Characteristic Ratios of Coefficient (I) : A General Case (계수의 특성비에 대한 선형계의 파라미터적 감도해석(I): 일반적인 경우)

  • 김영철;김근식
    • Journal of Institute of Control, Robotics and Systems
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    • v.10 no.3
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    • pp.205-215
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    • 2004
  • The characteristic ratio assignment (CRA) method〔1〕 is new polynomial approach which allows to directly address the transient responses such as overshoot and speed of response time in time domain specifications. The method is based on the relationships between time response and characteristic ratios($\alpha_i$ ) and generalized time constant (T), which are defined in terms of coefficients of characteristic polynomial. However, even though the CRA can apply to developing a linear controller that meets good transient responses, there are still some fundamental questions to be explored. For the purpose of this, we have analyzed several sensitivities of a linear system with respect to the changes of coefficients itself and $\alpha_i$ of denominator polynomial. They are (i) the unnormalized root sensitivity : to determine how the poles change as $\alpha_i$ changes, and (ii) the function sensitivity to determine the sensitivity of step response to the change of o, and to analyze the sensitivity of frequency response as o, changes. As an other important result, it is shown that, under any fixed T and coefficient of the lowest order of s in denominator, the step response is dominantly affected merely by $\alpha_1, alpha_2 and alpha_3$ regardless of the order of denominator higher than 4. This means that the rest of the$\alpha_i$ s have little effect on the step response. These results provide some useful insight and background theory when we select $\alpha_i$ and T to compose a reference model, and in particular when we design a low order controllers such as PID controller.

Dry Etching Behaviors of ZnO and $Al_2O_3$ Films in the Fabrication of Transparent Oxide TFT for AMOLED Display Application

  • Yoon, S.M.;Hwang, C.S.;Park, S.H.;Chu, H.Y.;Cho, K.I.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08b
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    • pp.1273-1276
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    • 2007
  • We provide a newly developed dry etching process for the fabrication of ZnO-based oxide TFTs. The etching characteristics of ZnO (active layer) and $Al_2O_3$ (gate insulator) thin films were systematically investigated when the etching gas mixtures and their mixing ratios were varied in the heliconplasma etching system.

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Comparison of Respiratory Mechanics and Gas Exchange Between Pressure-controlled and Volume-controlled Ventilation (압력조절환기법과 용적조절환기법의 호흡역학 몇 가스교환의 비교)

  • Jeong, Seong-Han;Choi, Won-Jun;Lee, Jung-A;Kim, Jin-A;Lee, Mun-Woo;Shin, Hyoung-Shik;Kim, Mi-Kyeong;Choe, Kang-Hyeon
    • Tuberculosis and Respiratory Diseases
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    • v.46 no.5
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    • pp.662-673
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    • 1999
  • Background : Pressure-controlled ventilation (PCV) is frequently used recently as the initial mode of mechanical ventilation in the patients with respiratory failure. Theoretically, because of its high initial inspiratory flow, pressure-controlled ventilation has lower peak inspiratory pressure and improved gas exchange than volume-controlled ventilation (VCV). But the data from previous studies showed controversial results about the gas exchange. Moreover, the comparison study between PCV and VCV with various inspiration : expiration time ratios (I : E ratios) is rare. So this study was performed to compare the respiratory mechanics and gas exchange between PCV and VCV with various I : E raitos. Methods : Nine patients receiving mechanical ventilation for respiratory failure were enrolled. They were ventilated by both PCV and VCV with various I : E ratios (1 : 2, 1 : 1.3 and 1.7 : 1). $FiO_2$, tidal volume, respiratory rate and external positive end-expiratory pressure (PEEP) were kept constant throughout the study. After 20 minutes of each ventilation mode, arterial blood gas, airway pressures, expired $CO_2$ were measured. Results : In both PCV and VCV, as the I : E ratio increased, the mean airway pressure was increased, and $PaCO_2$ and physiologic dead space fraction were decreased. But P(A-a)$O_2$ was not changed. In all three different I : E ratios, peak inspiratory pressure was lower during PCV, and mean airway pressure was higher during PCV. But $PaCO_2$ level, physiologic dead space fraction and P(A-a)$O_2$ were not different between PCV and VCV with three different I : E ratios. Conclusion : There was no difference in gas exchange between PCV and VCV under the same tidal volume, frequency and I : E ratio.

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Dry Etching Process for the Fabrication of Transparent InGaZnO TFTs

  • Yoon, S.M.;Cheong, W.S.;Hwang, C.S.;Kopark, S.H.;Cho, D.H.;Shin, J.H.;Ryu, M.;Byun, C.W.;Yang, S.;Lee, J.I.;Chung, S.M.;Chu, H.Y.;Cho, K.I.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.222-225
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    • 2008
  • We proposed the dry etching process recipe for the fabrication of In-Ga-Zn-O (IGZO)-based oxide TFTs, in which the etching behaviors of IGZO films were systematically investigated when the etching gas mixtures and their mixing ratios were varied. Good device characteristics of the fabricated TFT were successfully confirmed.

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Characterization of the fracture toughness and fatigue crack propagation of reduced activation ferritic steel(RAFs) (저방사화 페라이트강(RAFs)의 파괴인성 및 피로균열진전 특성)

  • Kim, Dong-Hyun;Yoon, Han-Ki;Kim, Sa-Wong;Kohyama, A.
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.13-18
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    • 2004
  • The objective of this study is to investigate fracture toughness and fatigue crack propagation behavior in the Reduced Activation Ferritic Steel (RAFs) JLF-I. The fracture toughness tests were performed with various size(plane size and thickness) and various side groove of specimens. The fatigue crack propagation behavior of the JLF-I steel was investigated by the constant-amplitude loading test for the stress ratios R=O.I, 0.3 and 0.5 respectively. The effects of stress ratios and specimen size on the fatigue crack growth behaviors for JLF-I steel were discussed within the Paris law. The test results showed the standard CT specimen with the side groove of 40 % represented a valid fracture toughness. The fracture resistance curve increased with increasing plane size and decreased with increasing thickness. However, the fracture resistance curve of half size specimen was similar to that of the standard specimen. The fatigue crack propagation rate of a half size specimen was similar to that of a full size specimen at the stress ratios of 0.1, 0.3 and 0.5 respectively. The fatigue crack propagation behavior of this material were evaluated by using a half size specimen.

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