• Journal of the Korean Ceramic Society
• /
• v.41 no.4
• /
• pp.289-296
• /
• 2004

Whisker and short rod shaped hydroxyapatite (Ca$_{10}$(PO$_4$)$_{6}$(OH)$_2$ with stoichiometric composition (Ca/P=1.62 -1.67, molar ratio) has been synthesized by hydrolysis and hydrothermal reaction of aqueous $\alpha$-Ca$_3$(PO$_4$)$_2$($\alpha$-TCP) solution (pH 11), respectively. The shape of resultant HAp was mainly dependent on synthetic route and the microstructural development was on processing condition. In hydrolysis processing, the degree of intersection of whiskerlike particles and agglomeration in the apsis line increased with increasing reaction time. In hydrothermal synthesis, the reaction product obtained under excessive reaction time ($\geq$3 h at 20$0^{\circ}C$) was severely agglomerated without further grain growth above certain critical size (0.75 ${\mu}{\textrm}{m}$ in length, 0.3${\mu}{\textrm}{m}$ 11m in diameter).

• Journal of the Mineralogical Society of Korea
• /
• v.18 no.3 s.45
• /
• pp.227-236
• /
• 2005

Hydrothermal tourmaline occurs as aggregates or dissemination in the diaspore nodule from an aluminum-rich clay deposit, Milyang, southeastern Korea. Most crystals of tourmaline show complex textures that are finely zoned. The fine-scale chemical zonation of hydrothermal tourmaline reflects the fluctuation conditions that would be expected from fluid mixing in open systems. Oscillatory chemical zoning in tourmaline formed and showed similar patterns, regardless of its crystallographic directions. Mg was enriched in the early stage of crystal growth while Fe was enriched in the later stage, with fluctuations of the ratio of Fe to Mg. Chemical analysis, BSE images, and X-ray compositional maps confirm that the oscillatory Boning in tourmaline is exclusively controlled by the variations of Fe and Mg contents, but the contribution of boron to the zonation is insignificant. The fact that tourmaline altered to diaspore and dickite indicates that tourmaline was unstable with respect to these aluminous minerals as the B, Fe, and Mg activities decreased. Therefore, the aluminum activity may control the stability of tourmaline in the hydrothermal system.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.31 no.7
• /
• pp.502-509
• /
• 2018

Epitaxial ZnO nanowires (NWs) were synthesized on sapphire (001) substrates using a hydrothermal process. The effects of the pH value of the precursor solution on the structural and optical properties of the resulting NWs was studied. The epitaxial relationship and the domain matching configuration between the sapphire (001) substrate and the as-grown ZnO NWs were determined using synchrotron X-ray diffraction measurements. The (002) plane of $w{\ddot{u}}rtzite$ ZnO NW grows in the surface normal direction parallel to the sapphire (001) direction. However, three types of in-plane domain matching configurations were observed, such as the on-position, $30^{\circ}$-rotated position, and ${\pm}8.5^{\circ}$-rotated position relative to the on-position, which might be attributed to inheriting the in-plane domain configuration of the ZnO seed layer.

• Korean Chemical Engineering Research
• /
• v.59 no.2
• /
• pp.174-179
• /
• 2021

Recently, hybrid coal research is underway to upgrade low-grade coal. The hybrid coal is made by mixing low-grade coal with bioliquids such as molasses, sugar cane, and lignin. In the case of lignin used here, a large amount of lignin is included in the wastewater of the papermaking process, and thus, research on hybrid coal production using the same is attracting attention. However, since a large amount of metal ions are contained in the lignin wastewater from the papermaking process, substances that corrode the generator are generated during combustion, and the amount of fly ash is increased. To solve this problem, it is essential to remove metal ions in the lignin wastewater. In this study, metal ions were removed by ion exchange with a alumina hollow fiber membrane coated with K-Phillipsite (K-PHI) zeolite. The alumina hollow fiber membrane used as the support was prepared by the nonsolvent induced phase separation (NIPS) method, and K-PHI seeds were prepared by hydrothermal synthesis. The prepared K-PHI seed was seeded on the surface of the support and coated by secondary growth hydrothermal synthesis. The characteristic of prepared coating membrane was analyzed by Scanning Electron Microscope (SEM), X-Ray Diffraction (XRD), Energy Dispersive Spectroscopy (EDX), and the concentration of metal ions before and after ion exchange was measured by Inductively Coupled Plasma Optical Emission Spectrometer (ICP-OES). The extraction amount of K+ is 86 mg/kg, and the extraction amount of Na+ is 54.9 mg/kg. Therefore, K-PHI zeolite membrane has the potential to remove potassium and sodium ions from the solution and can be used in acidic lignin wastewater.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2016.02a
• /
• pp.146-146
• /
• 2016

Zinc Oxide (ZnO) was known as a promising material for surface acoustic wave devices, gas sensors, optical devices and solar cells due to piezoelectric material, large band gap of 3.37 eV and large exciton binding energy of 60 meV at room temperature. In particular, the alignment of ZnO nanostructures into ordered nanoarrays can bring about improved sensitivity of devices due to widen the surface area to catch a lot of gas particle. Oxygen plasma treatment is used to specify the nucleation site of round patterned ZnO nanorods growth. Therefore ZnO nanorods were grown on a quartz substrate with patterned polystyrene monolayer by hydrothermal method after oxygen plasma treatment. And then, we carried out nanostructures by adjusting the diameter of the arranged ZnO nanorods according to polystyrene spheres of various sizes. The obtained ZnO nanostructures was characterized by X-ray diffraction (XRD), Field emission scanning electron microscopy (FE-SEM).

• Journal of the Korean Society for Geothermal and Hydrothermal Energy
• /
• v.12 no.1
• /
• pp.17-22
• /
• 2016

It is very important to obtain a out-of season production in horticultural greenhouses corresponding with higher crop prices. A ground source heat pump system has been highly spotlighed as an energy efficient heating system for the greenhouse. This paper investigated the operating cost of the ground source heat pump system with the variation of generating temperature and designing methods for heating system of the greenhouse. Even though the COP of the ground source heat pump system decreased with an increment of generating temperature in heating mode, the operating cost could be reduced. By adopting the high temperature heat pump system and heat storage tank, it could be achieved to save energy and reduce the operating time of auxiliary oil heating system for producing good plant-growth in the greenhouse.

• Journal of the Korean Society for Geothermal and Hydrothermal Energy
• /
• v.3 no.1
• /
• pp.17-22
• /
• 2007

The growth of domestic energy demand is rapidly increased for the industrialization and the improvement of the living standards. It is also recognised that the importance of the use of environmentally friendly energy and high efficient equipment. Ground Source heat pumps (GSHP) using earth as heat source or sink are outstanding environmentally friendly energy systems which have high thermal efficiency when compared to conventional heating and cooling system. So government employs a policy and increase investment for expanding renewable energy market volume. Especially is established a system for obligatory usage of renewable energy to achieve 5% renewable energy diffusion rate by 2011. And the market demand for the ground source heat pump is rapidly growing due to its strong advantages. However domestic situation usually have been depended on the import of ground source heat pumps. In this paper, the results of development of a ground source heat pump using refrigerant R410A are reported.

• The Transactions of The Korean Institute of Electrical Engineers
• /
• v.66 no.10
• /
• pp.1488-1493
• /
• 2017

Boron-doped ZnO:Al films were deposited by rf magnetron sputtering. The structural and optical property variations of the films with the boron amounts were studied. ZnO nanorods were grown on $SiO_2/Si$ wafers and glass by a hydrothermal method. ~50 nm-thick boron-doped ZnO:Al films were deposited on the substrates as seed layers. The mixed solution of zinc nitrate hexahydrate and hexamethylenetetramine in DI water was used as a precursor for ZnO nanorods. The concentration of zinc nitrate hexahydrate and that of hexamethylenetetramine were 0.05 mol, respectively. ZnO nanorods were grown at $90^{\circ}C$ for 2 hours. X-ray diffraction was conducted to observe the crystallinity of ZnO nanorods. A field emission scanning electron microscope was employed to study the morphology of nanorods. Optical transmittance was measured by a UV-Vis spectrophotometer, and photoluminescence was carried out with 266 nm light. The ZnO nanorods grown on the 0.5 wt% boron-doped ZnO seed layer showed the best crystallinity.

• Journal of the Optical Society of Korea
• /
• v.18 no.4
• /
• pp.307-316
• /
• 2014

Improved power conversion efficiency of hybrid solar cells with ITO/ZnO seed layer/ZnO NRs/ZnS QDs/P3HT/PCBM/Ag structure was obtained by optimizing the growth period of ZnO nanorods (NRs). ZnO NRs were grown using a hydrothermal method on ZnO seed layers, while ZnS quantum dots (QDs) (average thickness about 24 nm) were fabricated on the ZnO NRs by the successive ionic layer adsorption and reaction (SILAR) technique. Morphology, crystalline structure and optical absorption of layers were analyzed by a scanning electron microscope (SEM), X-ray diffraction (XRD) and UV-Visible absorption spectra, respectively. The XRD results implied that ZnS QDs were in the cubic phase (sphalerite). Other experimental results showed that the maximum power conversion efficiency of 4.09% was obtained for a device based on ZnO NR10 under an illumination of one Sun (AM 1.5G, $100mW/cm^2$).

• Journal of the Korean Society for Geothermal and Hydrothermal Energy
• /
• v.12 no.2
• /
• pp.13-18
• /
• 2016

Energy saving has been main concern, thus government supporting policies which are based on Fundamentals of Low-carbon Green Growth Act', 'Green Building Support Act, have been prepared in Korea. The objective of this study is to estimate energy conservation effectiveness and economic advantage assuming that lighting equipments and heat source equipments would be retrofitted. Office building, which has total floor area of $30,000m^2$, was a subject of this study. From the estimations, electric rate will be decreased by 62,886,000 won per year due to lighting equipments retrofit, and gas rate will be decreased 11,141,000 won or 17,332,000 won per year due to heat source equipments retrofit (in case of COP 1.2 or 1.5). Payback period of each case that are calculated by energy saving cost and retrofit cost are estimated 27.9 year, 38.6 year and 29.2 year, thus economic supporting policies is necessary for effective energy saving in buildings. Meanwhile payback period of heat source equipment for new building is estimated 6.1 year and 8.3 year.