• Bulletin of the Korean Chemical Society
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• v.25 no.3
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• pp.351-356
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• 2004

Selected MPEG-b-PDLLA block copolymers have been synthesized by ring-opening polymerization with systematic variation of the chain lengths of the resident hydrophilic and hydrophobic blocks. The size and shape of the micelles that spontaneously form in solution are then controlled by the characteristics of the block copolymer template. All the materials prepared in this study showed the tunable pore size of 20-80 ${\AA}$ with the increase of hydrophobic chain lengths and up to 660 $m^2$/g of specific surface area. The formation mechanism of these nanoporous structures obtained by controlling the micelle size has been confirmed using both liquid and solid state $^{13}C\;and\;^{29}Si$ NMR techniques. This work verifies the formation mechanism of nanoporous structures in which the pore size and wall thickness are closely dependent on the size of hydrophobic cores and hydrophilic shells of the block copolymer templates.

• JSTS:Journal of Semiconductor Technology and Science
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• v.4 no.2
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• pp.128-132
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• 2004

This paper presents the design, fabrication sequence and measurement results of a highly sensitive capacitive-type humidity sensor using a polyimide film without hydrophobic elements. The structure of the humidity sensor is MIM (metalinsulator-metal). For a high sensitivity, a modified aromatic polyimides as a moisture absorbing layer has been synthesized instead of using general polyimides containing hydrophobic elements. The polyimide film was obtained by synthesizing and thermally polymerizing polyamic acid composed of m-pyromellitic dianhydride, phenelenediamine and dimethylacetamide. Characteristics of fabricated sensors which include sensitivity, hysteresis and stability have been measured. The measurement result shows the percent normalized capacitance change of 0.37/%RH over a range from 10 to 90%RH, hysteresis of 0.77% over the same %RH range and maximum drift of 0.25% at 50%RH. The result shows that the developed humidity sensor can be applied to evaluate a hermeticity of various sensors and actuator systems as well as micro packages.

• Corrosion Science and Technology
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• v.7 no.6
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• pp.344-349
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• 2008

Epoxy coatings were prepared to give a different corrosion protection by reacting it with two different kinds of curing agent, and then effects of the curing agents on the structure, surface hydrophobic tendency, water transport behavior and hence corrosion protection of epoxy coatings were examined using hygrothermal cyclic test, and impedance analysis. In the results of EIS, the corrosion protection of epoxy coating cured by polyamide shows better than epoxy coating cured by polyamide epoxy adduct. It was well agreed with its water transport behavior and hydrophobic tendency.

• Bulletin of the Korean Chemical Society
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• v.6 no.3
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• pp.128-131
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• 1985

A series of copolymer membranes of 2-hydroxyethylmethacrylate (HEMA) with selected hydrophobic monomers were prepared without crosslinking agents. The equilibrium water content, the partition coefficient, and the permeability of the solutes such as urea, methylurea, 1,3-di-methylurea, and acetamide via these membranes were measured. The partition coefficient data show that as the hydrophobicity of solutes increased, the partition of solutes were dictated by hydrophobic interaction between solute and polymer matrix. Diffusion coefficients obtained in these experiments decrease as the water content of polymer membrane decreases. This decrease is blunt as the excess heat capacities, ${\phi}C^0_p$ (excess) in aqueous solution at infinite dilution of solute increases. To investigate the relationship between water content and diffusion coefficient, the results of the diffusion experiments were examined in light of a free-volume model of diffusive transport. The remarkable increase of urea mobility in the polymer network containing relatively larger bulk water can be considered as water structure breaking effect.

• Proceedings of the Korean Society of Applied Pharmacology
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• 1995.04a
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• pp.60-60
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• 1995

새로운 혈소판 활성화인자 (PAF) 수용체 결합 저해활성 유효성분인 pinusolide ($IC_{50}$/=2.5$\times$$10^{-7}$M)와 arctigenin($IC_{50}$/=5.2$\times$$10^{-6}$M)을 측백엽(Biota orientalis)과 우방자(Arctium lappa)로부터 분리하여 이미 보고한 바 있다. PAF 수용체에 대한 구조활성 상관관계를 규명하고자 또한 용해도가 우수한 강력한 PAF 길항제를 개발하고자 이 길항제들의 유도체들을 다양한 유기화학반응을 이용하여 합성하였고 in vitro PAF receptor binding assay로 그 활성의 강도를 비교 검토하였다. 그 결과, lactone ring 부분은 unsaturated lactone이 saturated lactone보다 활성이 강하였고 ring이 개열되면 활성이 현저히 감소하였다. pinusolide 경우 exocylclic double bond 부분은 sp$^2$구조의 hydrophobic한 유도체가 활성이 강하였으며, methyl ester 부분은 hydrophobic한 유도체가 활성이 강하였다. Arctigenin의 경우 aromatic unit가 hydrophobic할수록 활성이 강하였다.

• Journal of the Korean Society for Precision Engineering
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• v.31 no.2
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• pp.171-178
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• 2014

In this study, the apparent contact angle on the hydrophilic/hydrophobic surfaces with micropillars was studied. The previous researches showed that the Wenzel equation and the Cassie-Baxter equation were thermodynamically derived for the rough hydrophilic/hydrophobic surfaces and generally referenced on the field of wetting phenomena. For the verification of both equations, the apparent contact angle on the hydrophilic/hydrophobic surfaces with micro-pillars was measured. In the comparison between the measured and estimated apparent contact angles with the equations, the differences between the apparent contact angles were analyzed. Conclusively, the available range and limitation of theoretical equations were investigated and further researches about the apparent contact angle on the rough surfaces were proposed.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.12 no.1
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• pp.95-101
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• 2000

The effect of surface contact angle on the behavior of frost formation in a fin-tube heat exchanger is investigated experimentally. It is shown that both heat exchangers with hydrophilic and hydrophobic surfaces appear to have a better thermal performance than bare aluminium heat exchanger, but the improvements are very small. There is a little increase in the amount of the frost deposited onto the heat exchanger with both hydrophilic and hydrophobic surface. However, the effect of contact angle on the frost density is observed ; the frost with high density forms on the heat exchanger with hydrophilic surface ; and the frost with low density is deposited onto the heat exchanger with hydrophobic surface when compared with the frost deposited onto the heat exchanger with bare aluminium surface. This may be attributed to the fact that the shape of water droplets which condense on the surface of heat exchanger at the early stage of frosting varies with contact angle, and thus makes a difference on the structure of frost formation. From the experiments with different relative humidity of inlet air, it is shown that the variations of operating parameter make no influence on the effect of surface contact angle on the frosting behavior in the heat exchanger.

• Tribology and Lubricants
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• v.37 no.1
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• pp.1-6
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• 2021

This paper presents the experimental results of hydrophobic surfaces developed using a stereolithography-based additive-manufacturing technique. The additive manufacturing technique can be used to manufacture objects with complex geometries from computer-aided design data. Several additive manufacturing methods, such as selective laser sintering, fused deposition modeling, stereolithography apparatus (SLA), and inkjet-based system, have been developed. The SLA is a form of three-dimensional printing technology used to create prototypes, patterns, and production parts in successive layers through photochemical processes. Light causes chemical monomers and oligomers to cross-link together to form objects composed of polymers. Moreover, this method is economical for fabricating surfaces with high output resolution and quality. Here, we fabricate various surfaces using different shapes using an SLA. The surfaces with micro-patterns are fabricated for 10 cases, including the biomimetic surface. The fabricated surfaces with various micro-patterns are evaluated for hydrophobicity performance based on the static contact angle. The contact angle is measured three times for each case, and the averaged value is used. The results indicate that the arrangements in a staggered structure have a larger contact angle than those in a line when the same micro-pattern is applied. Moreover, the mimetic surfaces exhibit more hydrophobic characteristics than those of artificial micro-patterns.

• Journal of the Korean Recycled Construction Resources Institute
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• v.9 no.4
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• pp.469-477
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• 2021

In this study, the mechanical property of anti-fouling coating using CNF was evaluated to prevent the durability and stability of structure exposed the marine environment. Anti-fouling coating using CNF was prepared by CNF, AKD and waste glass powder, and contact angle test, drying time, viscosity analysis and microstructure were performed. When coating on one number of times, It was showed to relatively high hydrophobic performance in steel. And It was confirmed that the contact angle increased as the content of AKD increased in cement mortar. When coating on three number of times, the surface was confirmed super-hydrophobic at maximum of 151.6°. When mixing waste glass powder, the surface was showed to relatively high hydrophobic. It is pseudo plastic fluid when CNF and distilled water were prepared in a ratio of 1:1, And Anti fouling coating is judged to be suitable for use as coating on marine structure.

• Journal of Environmental Science International
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• v.12 no.1
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• pp.77-80
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• 2003

The interaction of mastoparan B, a cationic tetradecapeptide amide isolated from the hornet Vespa basalis, with phospholipid bilayers was studied with synthetic mastoparan B and its analogue with Ala instead of hydrophobic 12th amino acid residue in mastoparan B. MP-B and its derivative, [12-Ala]MP-B were synthesized by the solid-phase peptide synthesis method. MP-B and its analogue, [12-Ala]MP-B adopted an unordered structure in buffer solution. In the presence of neutral and acidic liposomes, the peptides took an $\alpha$-helical structure. The two peptides interacted with neutral and acidic lipid bilayers. These results indicated that the hydrophobic face in the amphipathic $\alpha$-helix of MP-B critically affected the biological activity and helical content.