• 마이크로전자및패키징학회지
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• 제13권2호
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• pp.27-31
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• 2006

본 연구는 OTS 표면 처리 유무에 따른 $HfO_2$ 위에서의 pentacene의 grain growth를 비교 연구하였다. OTS 처리에 의해 $HfO_2$의 표면은 hydrophilic에서 hydrophobic으로 변화되었으며, pentacene의 grain size는 50 nm 에서 90 nm으로 증가되었다. 이러한 pentacene의 크기 증가와 더불어 pentacene은 3-dimensional island 구조를 가지며, bulk phase 없이 thin film phase만의 출현으로 인해 OTS/$HfO_2$ 박막 위에서 pentacene은 보다 방향성을 가지며 정렬되었다.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2008년도 추계학술대회A
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• pp.1891-1895
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• 2008

Water covers 70% of the earth's surface and the human body consist of 75% of it. It is clear that water is one of the prime elements responsible for life on earth. Over the last 30 years or so, numerous studies have attempted to find out more about the water microscopically. In this paper, we investigated how the receding and advancing contact angle of the moving water droplet changes on a solid surface having various LJ epsilon parameters. To observe the dynamic contact angle history, a body force applied to all water molecules after obtained the water droplet in equilibrium with the solid surface. We obtained the density profile and receding and advancing contact angle of the moving water droplet

• International Journal of Precision Engineering and Manufacturing
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• 제9권4호
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• pp.71-73
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• 2008

The development of polymer/inorganic nanocomposites has attracted a great deal of interest due to the improved hybrid properties derived from the two different components. Various nanoscale fillers have been used to enhance polymer mechanical and thermal properties, such as toughness, stiffness, and heat resistance. The effects of the filler on the final properties of the nanocomposites are highly dependent on the filler shape, particle size, aggregate size, surface characteristics, polymer/inorganic interactions, and degree of dispersion. In this paper, we describe the influence of different $CaCO_3$ dispersion methods on the thermal properties of polyethylene terephthalate (PET)/$CaCO_3$ composites: i.e., the adsorption of $CaCO_3$ on the modified PET surface, and the hydrophobic modification of the hydrophilic $CaCO_3$ surface. We prepared PET/$CaCO_3$ nanocomposites using a twin-screw extruder, and investigated their thermal properties and morphology.

• 대한기계학회논문집B
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• 제33권8호
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• pp.559-564
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• 2009

The variation in the shape of water droplet moving on atomistically smooth solid surface in the presence of a constant body force is simulated using molecular dynamics simulation. We investigated how the advancing and receding contact angle of the moving water droplet changes on a solid surface having various characteristic energies. From the MD simulation results, we obtained the density profile defined as the number of water molecules at a given position. Then, assuming the water droplet periphery to be a circle, we calculated the contact angles by using a nonlinear fitting of the half-density contour line. The present simulation clearly shows the different profile of the advancing and receding contact angle for these three different interaction potential between the water droplet and the solid surface.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1999년도 추계학술대회 논문집
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• pp.505-508
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• 1999

In this study, weight loss, ESDD, surface conductivity and leakage current were measured at the different saline solutions by salt fog method. The magnitude of leakage current was higher at higher conductivity of 2 S/m saline water, but weight loss ESDD and surface conductivity which are indices of degradation were lower. This is considered that the current includes mainly ohmic component which doesn\`t contribute to surface degradation. In addition, it is shown that FFT could be useful in measuring initial transition from hydrophobic to hydrophilic surface.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2009년도 추계학술대회 초록집
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• pp.141-141
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• 2009

EHD(electrohydrodynamic) 증착법을 적용하여 코팅층 표면복합구조제어를 연구하였다. 이 방법을 이용하여 표면구조 제어를 통한 친/소수 코팅층 개발의 제반 조건들을 탐색한다. 화학적으로 안정한 코팅층을 형성할 수 있는 전구체 물질을 용매에 혼합하고, 전구체 물질의 농도를 조절하여 다양한 점도의 용액을 합성하고, 전기장을 적절한 범위에서 변화시키면서 용액의 점도와 전기장의 변화에 따른 코팅층의 표면형상을 체계적으로 조사하고, 주요 공정 변수인 용액 전구체농도와 전기장에 따른 표면형상 변화에 대한 공정 MAP을 조사하여 초친수/초발수 특성을 나타내는 최적 표면구조를 예측한다.

• 한국건축시공학회지
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• 제17권6호
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• pp.493-498
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• 2017

본 연구는 습식형 기포콘크리트의 단열성능 향상을 위한 소수성 에어로겔 기술 융합의 기초연구이다. 주요 실험변수는 에어로겔 혼입양으로서 기포 부피 대비 0%에서 40%로 변화하였다. 실험결과 에어로겔 혼입 기포 콘크리트의 압축강도는 일반 기포콘크리트에 비해 약 17%~34% 낮았다. 에어로겔이 기포 콘크리트 열전도율 저감에 미치는 영향도 미미하였는데, 이는 소수성 에어로겔의 비균질 분포 및 부분적 응집 때문이다. 따라서 에어로겔 혼입 기포콘크리트의 강도 및 열전도율 향상을 위해서는 에어로겔에 친수성을 부여하는 기술이 요구된다.

• Bulletin of the Korean Chemical Society
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• 제35권3호
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• pp.783-792
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• 2014

The binding interaction between a hemolytic peptide ${\delta}$-lysin and a zwitterionic lipid bilayer POPC was investigated through a series of molecular dynamics (MD) simulations. ${\delta}$-Lysin is a 26-residue, amphipathic, ${\alpha}$-helical peptide toxin secreted by Staphylococcus aureus. Unlike typical antimicrobial peptides, ${\delta}$-lysin has no net charge and it is often found in aggregated forms in solution even at low concentration. Our study showed that only the monomer, not dimer, inserts into the bilayer interior. The monomer is preferentially attracted toward the membrane with its hydrophilic side facing the bilayer surface. However, peptide insertion requires the opposite orientation where the hydrophobic side of peptide points toward the membrane interior. Such orientation allows the charged residues, Lys and Asp, to have stable salt bridges with the lipid head-group while the hydrophobic residues are buried deeper in the hydrophobic lipid interior. Our simulations suggest that breaking these salt bridges is the key step for the monomer to be fully inserted into the center of lipid bilayer and, possibly, to translocate across the membrane.

• 한국의류학회지
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• 제25권8호
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• pp.1444-1452
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• 2001

Textile materials are frequently in contact with surfactant solutions during their manufacturing or finishing processes as well as cleaning processes in use. Liquid wetting, wicking and absorbency of textile materials, and the liquid properties, surface characteristics and pore geometry of textile materials, and the liquie-solid interactions, In this paper, 10 different nonionic surfactants, including Span 20, Twen 20, 40, 60, 80, 21, 61, 81, 65, 85, were used. The surfactants were characterized by their hydrophile-lipophile-balance (HLB) values, structures, and surface tensions. The 0.1g/dL and 1.0g/dL surfactant solutions, which were both above critical micelle concentration (CMC), were used to see the concentration effects on the wetting and absorbency of cotton fabrics. The wetting behavior and liquid retention properties of hydrophobic cotton fabrics with different nonionic surfactant solutions are reported. The contact angles are greatly decreased and the water retention values are greatly increased by adding most of the surfactants studied into the system. The extents of this effects are influenced by the characteristics of surfactants and its solutions. Hydrophilic surfactants which have low number of carbon atoms or unsaturated hydrophobe structures are more effective in improving the wetting and absorbancy of hydrophobic cotton fabrics. The water retention of hydrophobic cotton fabrics has positive relations with $cos{\theta}$, adhesion tension and work of adhesion. The 1.0g/dL surfactant solutions show similar, but slightly improved wetting and absorbency characteristics of hydrophobic cotton fabrics compared to the 0.1g/dL surfactant solutions.

• Carbon letters
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• 제18권
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• pp.24-29
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• 2016

High pollutant-loading capacities (up to 319 times its own weight) are achieved by three-dimensional (3D) macroporous, slightly reduced graphene oxide (srGO) sorbents, which are prepared through ice-templating and consecutive thermal reduction. The reduction of the srGO is readily controlled by heating time under a mild condition (at 1 10⁻² Torr and 200℃). The saturated sorption capacity of the hydrophilic srGO sorbent (thermally reduced for 1 h) could not be improved further even though the samples were reduced for 10 h to achieve the hydrophobic surface. The large meso- and macroporosity of the srGO sorbent, which is achieved by removing the residual water and the hydroxyl groups, is crucial for achieving the enhanced capacity. In particular, a systematic study on absorption parameters indicates that the open porosity of the 3D srGO sorbents significantly contributes to the physical loading of oils and organic solvents on the hydrophilic surface. Therefore, this study provides insight into the absorption behavior of highly macroporous graphene-based macrostructures and hence paves the way to development of promising next-generation sorbents for removal of oils and organic solvent pollutants.