• Title/Summary/Keyword: Hydrogen leakage

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Experimental Study on Ventilation Efficiency of Leakage Gas Based on Supply and Exhaust Vent Location (밀폐공간에서 급·배기구 위치에 따른 누출 가스의 환기효과에 관한 실험적 연구)

  • Ha-Young Kim;Seong-Min Lee;Byeol Kim;Kwang-Il Hwang
    • Journal of Navigation and Port Research
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    • v.48 no.4
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    • pp.274-283
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    • 2024
  • Climate change is currently one of the most pressing environmental issues, primarily caused by carbon emissions from fossil fuel usage. As a result, alternative fuels that effectively reduce carbon emissions are garnering more attention. Among these alternatives, hydrogen has numerous advantages, such as its ability for large-scale storage and transport. However, it is crucial to prioritize safety measures, particularly in facilities that handle hydrogen, due to its highly flammable and fast-spreading nature. This study aims to compare and analyze the placement of supply and exhaust vents to efficiently release hydrogen in the event of a leak in an enclosed space. The experiments involved six different scenarios, each with various combinations of supply and exhaust vents. To ensure the experimental process's safety, helium, which shares similar physical properties with hydrogen, was used to analyze the internal oxygen concentration during ventilation system operations. The results revealed that among the six scenarios, Case 2, which employed a lower side supply vent and an upper side exhaust vent, exhibited the shortest ventilation time of 4 minutes and 30 seconds. Additionally, the decrease rate in oxygen concentration was examined in the upper, middle, and lower areas. Ventilation utilizing an upper surface supply vent and two exhaust vents on the upper surface and upper side (Case 6), showed lower oxygen concentration values in the upper area, while Case 2 yielded lower values in the middle and lower areas. Therefore, it is crucial to select an appropriate supply and exhaust vent configuration considering the space's characteristics and usage environment.

Leakage Current Reduction of Ni-MILC Poly-Si TFT Using Chemical Cleaning Method

  • Lee, Kwang-Jin;Kim, Doyeon;Choi, Duck-Kyun;Kim, Woo-Byoung
    • Korean Journal of Materials Research
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    • v.28 no.8
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    • pp.440-444
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    • 2018
  • An effective cleaning method for Ni removal in Ni-induced lateral crystallization(Ni-MILC) poly-Si TFTs and their electrical properties are investigated. The HCN cleaning method is effective for removal of Ni on the crystallized Si surface, while the nitric acid treatment results decrease by almost two orders of magnitude in the Ni concentration due to effective removal of diffused Ni mainly in the poly-Si grain boundary regions. Using the HCN cleaning method after the nitric acid treatment, re-adsorbed Ni on the Si surfaces is effectively removed by the formation of Ni-cyanide complexions. After the cleaning process, important electrical properties are improved, e.g., the leakage current density from $9.43{\times}10^{-12}$ to $3.43{\times}10^{-12}$ A and the subthreshold swing values from 1.37 to 0.67 mV/dec.

A Study on the Characteristics of ELB Insulating Material deteriorated by Salt water (염수에 의해 열화된 누전차단기 절연재료의 특성에 관한 연구)

  • Kim, Hyung-Rae;Kim, Dong-Ook;Kim, Hyeog-Soo;Choi, Chung-Seog;Kim, Hoon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.878-881
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    • 2001
  • In this paper, we analyzed the characteristics of insulating material with ELB(earth leakage circuit breaker) through tracking experiment and the study was carried out three different types of samples. The tracking is breakdown phenomenon of material surface that is generated on the organic insulating material. The test method applied IEC publication 587. The result of the sample breakdown by tracking was carbonized and resistance of between the electrodes is approximately 300$\Omega$. In the result of DSC analysis, the caloric peak was detected before 100$^{\circ}C$ in product of tracking. It appeared weight loss of 10.87% at 537$^{\circ}C$ on TGA. IR spectrum analysis showed carbon-hydrogen(C-H)bond on molecular structure that is the sample of tracking.

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Optimization of the Emission Spectrum of Red Color in Quantum Dot-Organic Light Emitting Diodes

  • Jeong, Byoung-Seong
    • Applied Chemistry for Engineering
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    • v.32 no.2
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    • pp.214-218
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    • 2021
  • We investigated the optimal stacked structure from the perspective of process architecture (PA) through emission spectrum analysis according to the wavelength of quantum dot (QD)-organic light-emitting diodes (OLED). We confirmed that the blue-light leakage through the QD can be minimized by increasing the QD filling density above a critical value in the red QD (R-QD) layer. In addition, when the thickness of red-color filter (R-CF) at the upper part of the R-QD increased to more than 3 ㎛, the leakage of blue light through the R-CF was effectively blocked, and a very sharp emission spectrum in the red wavelength band could be obtained. According to these outstanding results, we expect that the development of QD-OLED displays with very excellent color gamut can be possibly realized.

Characteristics of hydrogen adsorption peaks of electrodes containing ionic liquid for high temperature polymer electrolyte fuel cells (고온 연료전지용 이온성 액체를 함유한 전극의 수소 흡착피크의 특성)

  • Ryu, Sung-Kwan;Park, Jin-Soo;Yang, Tae-Hyun;Park, Seung-Hee;Park, S.H.;Yoon, Y.G.;Kim, Han-Sung;Kim, Chang-Soo
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.382-382
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    • 2009
  • In this study, we prepared electrodes containing ionic liquid for high temperature polymer electrolyte fuel cells. Effects of ILs on electrochemical properties of the electrodes were investigated carrying out measurement of cyclic voltammograms of the various electrodes with the content of IL in a strong supporting electrolyte. As the ILs content increased in electrodes, electrochemical surface area(ESA) decreased due to the leakage of ILs from Nafion ionomer. In addition, two case of cyclic voltammograms under two simulated environment, i.e. IL leakage from Nafion ionomer in I) electrode and ii) polymer electrolyte, were investigated. As a result, IL leakage from polymer electrolyte showed worse results in electrochemical properties of the electrode.

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Leakage Current and Threshold Voltage Characteristics of a-Si:H TFT Depending on Process Conditions (a-Si:H TFT의 누설전류 및 문턱전압 특성 연구)

  • Yang, Kee-Jeong;Yoon, Do-Young
    • Korean Chemical Engineering Research
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    • v.48 no.6
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    • pp.737-740
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    • 2010
  • High leakage current and threshold voltage shift(${\Delta}Vth$) are demerits of a-Si:H TFT. These characteristics are influenced by gate insulator and active layer film quality, surface roughness, and process conditions. The purpose of this investigation is to improve off current($I_{off}$) and ${\Delta}V_{th}$ characteristics. Nitrogen-rich deposition condition was applied to gate insulator, and hydrogen-rich deposition condition was applied to active layer to reduce electron trap site and improve film density. $I_{off}$ improved from 1.01 pA to 0.18 pA at $65^{\circ}C$, and ${\Delta}V_{th}$ improved from -1.89 V to 1.22 V.

A Study on the Silicon Nitride for the poly-Si Thin film Transistor (다결정 박막 트랜지스터 적용을 위한 SiNx 박막 연구)

  • 김도영;김치형;고재경;이준신
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.12S
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    • pp.1175-1180
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    • 2003
  • Transformer Coupled Plasma Chemical Vapor Deposited (TCP-CVD) silicon nitride (SiNx) is widely used as a gate dielectric material for thin film transistors (TFT). This paper reports the SiNx films, grown by TCP-CVD at the low temperature (30$0^{\circ}C$). Experimental investigations were carried out for the optimization o(SiNx film as a function of $N_2$/SiH$_4$ flow ratio varying ,3 to 50 keeping rf power of 200 W, This paper presents the dielectric studies of SiNx gate in terms of deposition rate, hydrogen content, etch rate and leakage current density characteristics lot the thin film transistor applications. And also, this work investigated means to decrease the leakage current of SiNx film by employing $N_2$ plasma treatment. The insulator layers were prepared by two step process; the $N_2$ plasma treatment and then PECVD SiNx deposition with SiH$_4$, $N_2$gases.

Fuzzy Based Failure Mode and Effect Analysis (FMEA) of Hydrogen Production Process Using the Thermococcus Onnurineus NA1 (퍼지기반 해양 미생물 이용 수소 제조 공정의 고장유형 및 영향분석)

  • PARK, SUNG HO;AHN, JUNKEON;KIM, SU HYUN;YOO, YOUNG DON;CHANG, DAEJUN;KANG, SUNGKYUN
    • Journal of Hydrogen and New Energy
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    • v.29 no.4
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    • pp.307-316
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    • 2018
  • In this study, the failure mode and effect analysis (FMEA) of hydrogen production process by using the Thermococcus onnurineus NA1 was conducted and advanced methodology to compensate the weakness of previous FMEA methodology was applied. To bring out more quantitative and precise FMEA result for bio-hydrogen production process, fuzzy logic and potential loss cost estimated from ASPEN Capital Cost Estimator (ACCE) was introduced. Consequently, risk for releasing the flammable gases via internal leakage of steam tube which to control the operating temperature of main reactor was caution status in FMEA result without applying the fuzzification and ACCE. Moreover, probability of the steam tube plugging caused by solid property like medium was still caution status. As to apply the fuzzy logic and potential loss cost estimated from ACCE, a couple of caution status was unexpectedly upgraded to high dangerous status since the potential loss cost of steam tube for main reactor and decrease in product gases are higher than expected.

Preparation of Thin Film Electrolyte for Solid Oxide Fuel Cell by Sol-Gel Method and Its Gas Permeability (졸-겔법을 이용한 고체산화물연료전지의 전해질 박막 제조 및 가스 투과도)

  • Son, Hui-Jeong;Lee, Hye-Jong;Lim, Tak-Hyoung;Song, Rak-Hyun;Peck, Dong-Hyun;Shin, Dong-Ryul;Hyun, Sang-Hoon;Kilner, John
    • Journal of the Korean Ceramic Society
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    • v.42 no.12 s.283
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    • pp.827-832
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    • 2005
  • In this study, thin electrolyte layer was prepared by 8YSZ ($8mol\%$ Yttria-Stabilized Zirconia) slurry dip and sol coating onto the porous anode support in order to reduce ohmic resistance. 8YSZ polymeric sol was prepared from inorganic salt of nitrate and XRF results of xerogel powder exhibited similar results $(99.2\pm1wt\%)$ compared with standard sample (TZ-8YS, Tosoh Co.). The dense and thin YSZ film with $1{\mu}m$ thickness was synthesized by coating of 0.7M YSZ sol followed by heat-treatment at $600^{\circ}C$ for 1 h. Thin film electrolyte sintered at $1400^{\circ}C$ showed no gas leakage at the differential pressure condition of 3 atm.

Investigation of the Bonding Stress of the 2nd Barrier for LNG Carrier Cargo Containment System Considering Various Working Conditions (다양한 작업 조건을 고려한 LNG 운반선 화물창 2차 방벽의 극저온 접착강도 분석)

  • Jeong-Hyeon Kim;Hee-Tae Kim;Byeong-Kwan Hwang;Seul-Kee Kim;Tae-Wook Kim;Doo-Hwan Park;Jae-Myung Lee
    • Journal of the Korean Society of Industry Convergence
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    • v.26 no.3
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    • pp.499-507
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    • 2023
  • The core of the liquefied natural gas (LNG) carrier cargo containment system (CCS) is to store and transport LNG safely under temperatures below -163 degrees Celsius. The secondary barrier of the LNG CCS is adopted to prevent LNG leakage from CCS to the ship's hull structure. Recently, as the size of the LNG CCS increases, various studies have been conducted on the applied temperature and load ranges. The present study investigates the working condition-dependent bonding strength of the PU15 adhesives of the secondary barrier. In addition, the mechanical performance is analyzed at a cryogenic temperature of -170 degrees Celsius, and the failure surface and failure mode are investigated depending on the working condition of the bonded process. Even though the RSB and FSB-based fracture mode was confirmed, the results showed that all the tested scenarios satisfied the minimum requirement of the regulation.