• Journal of the Korean Institute of Gas
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• v.16 no.6
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• pp.29-33
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• 2012

This paper is an attempt to give a concise overview of the state-of-the-art in the recent liquid hydrogen safety researches with unwanted event progress. The vessel of liquified hydrogen may fail and liquid hydrogen spilled. The hydrogen will immediately start to evaporate above a pool and make a hydrogen cloud. The cloud will disperse and can produce a vapor cloud explosion. The vessel containing the liquid hydrogen may not be able to cope with the boil-off due to heat influx, especially in case of a fire, and a BLEVE may occur. In equipment where it exists as compressed gas, a leak generates a jet of gas that can self-ignite immediately or after a short delay and produce a jet flame, or in case it ignites at a source a certain distance from the leak (delayed ignition), a flash fire occurs in the open and with confinement a deflagration or even detonation may develop. The up-to-date knowledge in these events, recent progress and future research are discussed in brief.

• Fire Science and Engineering
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• v.25 no.6
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• pp.32-38
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• 2011

As the using rate of an explosive gas has been increased in the industrial site, the regional residents adjacent to the site as well as the site workers have frequently fallen into a dangerous situation. Damage caused by accident in the process using hydrogen gas is not confined only to the relevant process, but also is linked to a large scale of fire or explosion and it bring about heavy casualties. Therefore, personnel in charge should investigate the kinds and causes of the accident, forecast the scale of damage and also, shall establish and manage safety countermeasures. We, in Anti-Calamity Research Center, forecasted the scope of danger if break out a fire or/and explosion in hydrogen gas facilities of MLCC firing process. We selected piping leak accident, which is the most frequent accident case based on an actual analysis of accident data occurred. We select and apply piping leak accident which is the most frequent case based on an actual accident data as a model of damage forecasting scenario caused by accident. A jet fire breaks out if hydrogen gas leaks through pipe size of 10 mm ${\Phi}$ under pressure of 120 bar, and in case of $4kw/m^2$ of radiation level, the radiation heat can produce an effect on up to distance of maximum 12.45 meter. Herein, we are going to recommend safety security and countermeasures for improvement through forecasting of accident damages.

• Journal of Auto-vehicle Safety Association
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• v.13 no.4
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• pp.73-80
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• 2021

Recently, Korea has established a plan for the supply of hydrogen vehicles and is promoting the expansion of the supply. Risk factors for hydrogen vehicles are hydrogen leakage, jet fire, and explosion. Therefore Safety measures are necessary for this hazard. In addition, risks in semi-closed spaces such as tunnels, underground roads, and underground parking lots should be analyzed. In this study, an explosion experiment was conducted on a hydrogen tank used in a hydrogen vehicle to analyze the risk of a hydrogen vehicle explosion accident that may occur in a semi-closed space. As results, the effect on the structure and the human body was analyzed using the overpressure and impulse values for each distance generated during the explosion.

• Transactions of the Korean hydrogen and new energy society
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• v.34 no.6
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• pp.698-711
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• 2023

Consequence analysis using an ALOHA program is conducted to calculate the accidental impact ranges in the cases of hydrogen leakage, explosion, and jet fire in a hydrogen fueled combined cycle power plant. To evaluate the effect of weather conditions and topographic features on the damage range, ALOHA is executed for the power plants located in the inland and coastal regions. The damage range of hydrogen leaked in coastal areas is wider than that of inland areas in all risk factors. The obtained results are expected to be used when designing safety system and establishing safety plans.

• Transactions of the Korean hydrogen and new energy society
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• v.32 no.6
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• pp.551-564
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• 2021

The use of clean energy based on the hydrogen economy is increasing rapidly due to the greenhouse gas reduction policies and the increase in the need for hydrogen. Currently, South Korea government have been considering a plan to construct hydrogen refueling stations at expressway service area for the purpose of supplying hydrogen vehicles. In the case of a hydrogen refueling stations, a quantitative risk assessment (QRA) must be performed because it includs and uses a high pressurized hydrogen storage tank. In this study, QRA was conducted using societal risk and F-N curve by the consequence assessment (CA) of jet fire and explosion according to the population density, capacity of the high pressurized hydrogen storage tank and frequency assessment (FA) data to the general hydrogen refueling stations systems in expressway service area. In the cases of jet with a leak diameter of 7.16 mm, regardless of expressway service area location, the societal risk was over 1E-04 that was acceptable for as Low As reasonably practicable (ALARP) region (workforce), but unacceptable for ALARP region (public). In the cases of gas explosion, all expressway service area satisfy ALARP region. In the case of the population density is over 0.0727, QRA for constructing the hydrogen refueling stations, must be conducted.

• Journal of the Korean Institute of Gas
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• v.13 no.1
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• pp.45-51
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• 2009

A safety assessment was performed through the process analysis of hydrogen station. The purpose of this study provides basic information for the standard establishment about hydrogen stations. The processes of hydrogen stations were classified by four steps (process of manufacture, compression, storage, charge). FMEA (Failure Mode and Effect Analysis) method was applied to evaluate safety. Each risk element is following; S (severity), O (occurrence), D (detection). And the priority of order was decided by using RPN (Risk Priority Number) value multiplying three factors. Scenarios were generated based on FMEA results. And consequence analysis was practiced using PHAST program. In the result of C.A, jet fire and explosion were shown as accident types. In case of leakage of feed line in PSA process, concentration of CO gas is considered to prevent CO gas poisoning when the raw material that can product CO gas was used.

• Fire Science and Engineering
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• v.33 no.1
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• pp.23-29
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• 2019

Rechargeable battery such as lithium-ion battery has been noticed as a kinds of the energy storage system in the recent energy utilization and widely used actually in various small electronic equipment and electric vehicles. However, many thermal runaway caused battery accidents occurred recently, which still is obstacle for advanced application of lithium ion battery. One of the main differences to general fires is the existence of ionized electrolyte with electron during combustion. Therefore, we simply simulated the ion addition effects of battery fires by introducing an ionized fuel in jet diffusion flames. When the ionized methane through a corona discharge was used as fuel, the overall flame stability and shape such as flame length showed no significant difference from normal methane flame, but NOx and CO emissions measured at the post flame region decreased. The ion addition effect of methane oxidation was also numerically simulated with the modeling of hydrogen addition in the mixture. It was confirmed that the hydrogen addition at a fixed temperature had a similar effects on ionization of methane and hence could be modeled successfully.

• Journal of Korean Tunnelling and Underground Space Association
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• v.24 no.6
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• pp.659-677
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• 2022

Hydrogen is emerging as a next-generation energy source and development and supply of FCEV (hydrogen fuel cell electric vehicle) is expected to occur rapidly. Accordingly, measures to respond to hydrogen car accidents are required and researches on the safety of hydrogen cars are being actively conducted. In this study, In this study, we developed a hydrogen car accident scenarios suitable for domestic conditions for the safety evaluation of hydrogen car in road tunnels through analysis of existing experiments and research data and analyzed and presented the hazard distance according to the accident results of the hydrogen car accident scenarios. The accident results according to the hydrogen car accident scenario were classified into minor accidents, general fires, jet flames and explosions. The probability of occurrence of each accident results are predicted to be 93.06%, 1.83%, 2.25%, and 2.31%. In the case of applying the hydrogen tank specifications of FCEV developed in Korea, the hazard distance for explosion pressure (based on 16.5 kPa) is about 17.6 m, about 6 m for jet fire, up to 35 m for fireball in road tunnel with a standard cross section (72 m²).

• Journal of Internet Computing and Services
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• v.24 no.6
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• pp.171-180
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• 2023

Hydrogen energy technology is gaining importance in the era of the Fourth Industrial Revolution, offering military advantages when applied to military vehicles due to its characteristics such as reduced greenhouse gas emissions, noise, and low vibration. Korea's military has initiated the Army Tiger 4.0 plan, focusing on hydrogen application, downsizing, and AI-based smart features. The Ministry of National Defense plans to collaborate with the Ministry of Environment to expand hydrogen charging stations nationwide, anticipating increased deployment of military hydrogen vehicles. However, considering the Jet Fire and VCE(Vapor Cloud Explosion) nature of hydrogen, ensuring safety during installation is crucial. Current military guidelines specify a minimum safety distance of 2m from adjacent buildings for charging stations. Scientific methods have been employed to quantitatively assess the accident damage range of hydrogen, proposing a minimum safety distance beyond the affected area.

• Journal of Korean Tunnelling and Underground Space Association
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• v.23 no.1
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• pp.47-60
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• 2021

Hydrogen is a next-generation energy source, and according to the roadmap for activating the hydrogen economy, it is expected that industries to stably produce, store, and transport of hydrogen as well as the supply of hydrogen fuel cell vehicles will be made rapidly. Accordingly, safety measures for accidents of hydrogen vehicles in confined spaces such as tunnels are required. In this study, as part of a study to ensure the safety of hydrogen fuel cell vehicles in road tunnels, a basic investigation and research on the risk of fire and explosion due to gas leakage and hydrogen tank rupture among various hazards caused by hydrogen fuel cell vehicle accidents in tunnels was conducted. The following results were obtained. In the event of hydrogen fuel cell vehicle accidents, the gas release rate depends on the orifice diameter of TPRD, and when the gas is ignited, the maximum heat release rate reaches 3.22~51.36 MW (orifice diameter: 1~4 mm) depending on the orifice diameter but the duration times are short. Therefore, it was analyzed that there was little increase in risk due to fire. As the overpressure of the gas explosion was calculated by the equivalent TNT method, in the case of yield of VCE of 0.2 is applied, the safety threshold distance is analyzed to be about 35 m, and number of the equivalent fatalities are conservatively predicted to reach tens of people.