• Title/Summary/Keyword: Hydrogen exchange

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High Temperature Characteristics of Commercially Available Anion Exchange Membrane for Alkaline Water Electrolysis (알칼리 수전해를 위한 상용 음이온교환막의 고온 특성)

  • JANG, SU-YOEN;RYU, CHEOL-HWI;HWANG, GAB-JIN
    • Transactions of the Korean hydrogen and new energy society
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    • v.33 no.4
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    • pp.330-336
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    • 2022
  • In order to evaluate the possibility as a separator in alkaline water electrolysis, the high temperature characteristics were evaluated by measuring the membrane resistance and durability of 5 types of commercial anion exchange membranes in 7 M KOH solution and at 80℃. The membrane resistance of AEM membrane measured in 7 M KOH solution and at 80℃ had a lower value of about 8-24 times compared to the other membranes. The durability of AEM membrane tested with the soaking time in 7 M KOH solution and at 80℃ showed a very good stability and that of FAAM40 and FAAM75-PK showed secondly a good stability. The thermal stability with the soaking time in 7 M KOH solution and at 80℃ of FAAM40 and FAAM75-PK membrane analyzed by thermo-gravimetric analysis showed a good stability compared to the other membranes.

Development of WT-FC Hybrid System for Off-Grid (오프그리드용 풍력-연료전지 하이브리드 시스템 개발)

  • Choi, Jong-Pil;Park, Nae-Chun;Kim, Sang-Hun;Kim, Byeong-Hee;Nam, Yun-Su;Yu, Neung-Su
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.383-386
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    • 2007
  • This paper describes the design and integration of the wind- fuel cell hybrid system. The hybrid system components included a wind turbine, an electrolyzer (for generation of H2), a PEMFC (Proton Exchange Membrane Fuel Cell), storage system and BOP (Balance of Plant) system. The energy input is entirely provided by a wind turbine. A DC-DC converter controls the power input to the electrolyzer, which produces hydrogen and oxygen form water. The hydrogen used the fuel for the PEMFC. The hydrogen is compressed and stored in high pressure tank by hydrogen gas booster system.

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Kinetics of Hydrogen-Deuterium Exchange of 8-CH Groups in Adenosine 5$^\prime$-Monophosphate and Guanosine 5$^\prime$-Monophosphate by Laser Raman Spectroscopy

  • Kim, Sang-Kyu;Kim, Myung-Soo;Suh, Se-Won
    • Bulletin of the Korean Chemical Society
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    • v.6 no.5
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    • pp.270-272
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    • 1985
  • The rate constants of the hydrogen-deuterium exchange of 8-CH groups in 5'-rAMP and 5'-GMP were measured by laser Raman spectroscopy. The Arrhenius activation energies calculated from the rate constants measured as a function of temperature were similar for both compounds. However, the effects of pD on exchange rate constants were different for the two compounds. Our kinetic data support the exchange reaction mechanism involving an ylide type intermediate.

Hydrophobic Catalyst Mixture for the Isotopic Exchange Reaction between Hydrogen and Water

  • Paek S.;Ahn D.H.;Choi H.J.;Kim K.R.;LEE M.;YIM S.P.;CHUNG H.
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.11b
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    • pp.141-148
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    • 2005
  • Pt/SDBC catalyst, which is used for the hydrogen-water isotopic exchange reaction, was prepared. The various properties of the catalyst, such as the thermal stability, pore structure and the platinum dispersion, were investigated. A hydrophobic Pt/SDBC catalyst which has been developed for the LPCE column of the WTRF (Wolsong Tritium Removal Facility) was tested in a trickle bed reactor. An experimental apparatus was built for the test of the catalyst at various temperatures and gas velocities.

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Development of WT-FC Hybrid System for Off-Grid (오프그리드용 풍력-연료전지 하이브리드 시스템 개발)

  • Choi, Jong-Pil;Kim, Kwang-Soo;Park, Nae-Chun;Kim, Sang-Hun;Kim, Byeong-Hee;Yu, Neung-Su
    • New & Renewable Energy
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    • v.3 no.2 s.10
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    • pp.60-67
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    • 2007
  • This paper describes the design and integration of the wind-fuel cell hybrid system. The hybrid system components included a wind turbine, an electrolyzer (for generation of H2), a PEMFC (Proton Exchange Membrane Fuel Cell), hydrogen storage tank and BOP (Balance of Plant) system. The energy input is entirely provided by a wind turbine. A DC-DC converter controls the power input to the electrolyzer, which produces hydrogen and oxygen form water. The hydrogen used the fuel for the PEMFC. Hydrogen may be produced and stored in high pressure tank by hydrogen gas booster system. Wind conditions are changing with time of day, season and year. So, wind power is a variable energy source. The main purpose with these WT-FC hybrid system is to store hydrogen by electrolysis of water when wind conditions are good and release the stored hydrog en to supply the fuelcell when wind is low.

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