• Nuclear Engineering and Technology
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• 제52권9호
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• pp.2041-2046
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• 2020

The present article investigates the influence of hydrogen concentration on the creep performance of cold-worked stress-relieved unirradiated Zircaloy-4 cladding tube using nanoindentation technique. The as-received Zircaloy-4 tube is hydrided to the concentrations of 600 ppm and 900 ppm using gaseous hydrogen charging method. Constant load indentation creep tests are performed for a dwell period of 600 s in the temperature range of 300℃-500 ℃ at 1000 μN, 2000 μN, and 3000 μN. The impact of hydrogen is evaluated in terms of steady state power law creep exponent and activation energy. The power law creep exponent decreases with increase in hydrogen concentration, however, it remains fairly constant with increase in temperature up to 500 ℃. Moreover, activation energy too decreases significantly with increase in hydrogen concentration. The mean stress exponent and activation energy are found to be 3.58 and 28.67 kJ/mol, respectively, for as-received sample.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2009년도 추계학술대회 논문집
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• pp.139-141
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• 2009

This study analyzed the effect of the microstructure and alloying element on hydrogen-induced delayed fracture properties for the Energy Saving Wire (ESW) developed recently. Specimens were produced with a diameter 6.5mm post to the deformation (0, 10, 20 and 30%), followed by injecting the hydrogen. The experimental results by using GAS chromatography showed that the more hydrogen was emitted for high-carbon steel (0.45%C steel and 0.35%C steel) than low-carbon steel(0.2%C-Cr steel and 0.2%C-Cr-Mo steel). And, 0.45%C steel, 0.35%C steel and 0.2%C-Cr-Mo steel exhibited the crack for 30% deformed specimen. The hydrogen emitted was analyzed with the amount, the spheroidization, and the size of the carbides.

• Nuclear Engineering and Technology
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• 제53권2호
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• pp.474-483
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• 2021

To establish the exclusive role of hydrogen on burst behaviour of Zircaloy-4 during loss-of-coolant accident transients, an extensive single-rod burst tests were conducted on both unirradiated as-received and hydrogenated Zircaloy-4 cladding tubes at different heating rates and internal overpressures. The visual observations of cladding tubes during bursting as well as post-burst are presented in detail to understand the effect of hydrogen concentration, heating rate, and internal pressure. Impact of hydrogen on burst parameters-burst stress, burst strain, burst temperature-during loss-of-coolant accident transients are compared and discussed. Rupture at multiple locations for hydrogenated cladding at lower internal pressure and higher heating rate is reported for the very first time. A novel burst criterion accounting hydrogen concentration in nuclear fuel cladding is proposed.

• 한국수소및신에너지학회논문집
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• 제22권4호
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• pp.458-464
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• 2011

Recently, one of the hydrogen production methods has attracted using dense metallic membrane. It has high hydrogen permeation and selectivity which hardly could adopt industrial product because of high cost, hydrogen embrittlment and thermal stability. Meanwhile, vanadium has high hydrogen solubility and it use to instead of Pd-Ag amorphous membrane. Aluminum carried out blocking hydrogen diffusion on grain boundary therefore protecting hydrogen embrittlement. Most of dense metallic membrane is solution diffusion mechanism. The solution diffusion mechanism was very similar hydrogen storing steps such as steps of metal hydride. Thus, V-Al composites were fabricated to use hydrogen induced mechanical alloying. The fabricated V-Al composites were characterized by XRD, SEM, EDS and simultaneous TG/DSC analyses. The hydrogenation behaviors were evaluated using a Sievert's type automatic PCT apparatus. The hydrogenation behaviors of V-Al composites was evaluated too low hydrogen stored capacity and fast hydrogenation kinetics. In PCI results, V-Al composites had low hydrogen solubility, in spite of that, hydrogen kinetics was calculated very fast and hydrogen absorption/desorption contents were same capacity.

• 한국가스학회:학술대회논문집
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• 한국가스학회 2006년도 추계학술발표회 논문집
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• pp.183-186
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• 2006

• 한국마린엔지니어링학회:학술대회논문집
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• 한국마린엔지니어링학회 2006년도 전기학술대회논문집
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• pp.97-98
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• 2006

• Corrosion Science and Technology
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• 제10권4호
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• pp.131-135
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• 2011

The demands of high-strength steel have been steadily increased to reduce the weight of vehicles. Although the TRIP steel has been the promising candidate material for the purpose, high strength hinders the application due to the susceptibility to hydrogen delayed fracture in the corrosive environment. Moreover, the testing method was not specified in the ISO standards. In this work, the test method to evaluate the susceptibility of hydrogen delayed fracture was studied by slow strain rate testing technique. The four test experimental parameters were studied : strain rate, hydrogen charging time, holding time after hydrogen charging, and holding time after cadmium plating. The steel was fractured by hydrogen in case the strain rate was in the range of $1{\times}10^{-4}{\sim}5{\times}10^{-7}/sec$. It was confirmed that the slow strain rate test is effective method to evaluate the susceptibility to hydrogen delayed fracture. The holding time over 24 hrs after hydrogen charging, nullified the hydrogen effect, that is, the specimen was no more susceptible to hydrogen after 24 hrs even though the specimen was fully hydrogen-charged. Moreover, cadmium electroplating could not prevent from diffusing out the hydrogen from the steel in the experiment. The effective experimental procedures were discussed.

• 한국해양공학회지
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• 제1권1호
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• pp.111-119
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• 1987

The corrosion fatigue crack propagation characteristics of SS41 steel in 3.5% NaCl solution have been evaluated for loading frequencies of 1Hz and 0.2Hz. A sine wave loading profile was used for fatigue testing. Each test was carried out at a constant stress ratio, R(0.1). The main results are summarized as follows; 1. Fatigue crack propagation rate was higher in 3.5% NaCl solution than in air, higher in the base metal than in the weld metal, and higher at f =0.2Hz than at f =1Hz. 2. The crack closure level of the base metal was not influenced by cyclic frequencies, but that of the weld metal was much influenced. 3. When the crack closure effect was eliminated in the evaluation of crack propagation characteristics by using $\Delta K_{eff}$, the envirommental influence was distinctly observed. At the base metal, crack propagation rate was enhanced by the hydrogen embrittlement, and the weld metal was reduced by the crac closure. 4. There was clearly observed hydrogen embrittlement and severely corroded aspect at fracture surface of lower frequency than that of higher frequency, and at that of base metal than that of the weld metal.

• 한국해양공학회지
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• 제1권2호
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• pp.113-122
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• 1987

Ships and offshore strrctures are exposed to the corrosive surroundings, and the extablishment of the design criteria and the elucidation on the influence by this environment are requested to maintain the safety and to demonstrate the function of the structure. In this paper, the fatigue-crack-growth behavior on the compact tension specimens of quenched, tempered HT80 grade steels and RA36 high tensile steels having a single edge fatigue cracked notch respectively, were investigated under the repeated tensile stress with constant stroke in sea water for the welded parts by shielded metal arc welding. Main results obtained are summerized as follows; 1. The fatigue-crack-growth rates da/dN in sea water appeared to be greater behavior than those in air environment at the same stress intensisy factor range $\DeltaK$. 2. The correlation data of da/dN$\DeltaK$ of the two kinds of high tensile steels in sea water showed no great difference, however, the correlation data of da/dN$\DeltaK/\sigma_y$($\sigma_y$ stands for yield strength of the material) showed that the fatigue-crack-growth behavior of RA36 plate is affected by active path corrosion(APC) mechanism, while that of HT80 grade plate is mainly affected by hydrogen embrittlement mechanism.

• 대한기계학회논문집A
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• 제37권6호
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• pp.753-760
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• 2013

금속 재료의 수소취화 현상에 대한 분석은 수소플랜트의 안전성 평가를 위해 매우 중요하다. 수소환경하 취화된 재료의 기계적 물성과 파괴인성은 구조 건전성 평가에 가장 기본적이며 중요한 자료이다. 본 논문은 최근에 개발된 유한요소 해석 기반 현상학적 손상해석을 소형펀치 실험에 적용하고 Inconel 617 재료의 대기 중 소형펀치 실험결과와 비교 함으로써 손상해석 기법의 적용 타당성을 보였다. 또한 역변환 기법을 사용하여 소형펀치 실험으로부터 인장물성을 예측하고 인장실험으로부터 구한 재료 물성과 비교하여 적용 가능성을 검증하였다. 검증된 결과를 바탕으로 수소취화된 시편에 대한 소형펀치 실험결과에 역변환 기법과 손상해석을 적용하여 수소취화 된 재료의 기계적물성과 파괴인성을 예측하였다.