• 한국수소및신에너지학회논문집
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• 제15권4호
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• pp.348-354
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• 2004

Hydrogen gas has several merits such as lower ignition energy, wide flammability and shorter quenching distance. It leads to high thermal efficiency but backfire occurrence. In this study, feasibility of expansion of BFL(Back-Fire Limit) equivalence ratio and combustion characteristics by a dilution of hydrogen fuel are experimently examined by using experimental heavy duty single cylinder hydrogen fueled engine. As results, it is found that BFL equivalence ratio is expanded to rich range and torque is increased.

• Journal of Microbiology and Biotechnology
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• 제24권11호
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• pp.1542-1550
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• 2014

Co-digesting molasses wastewater and sewage sludge was evaluated for hydrogen production by response surface methodology (RSM). Batch experiments in accordance with various dilution ratios (40- to 5-fold) and waste mixing composition ratios (100:0, 80:20, 60:40, 40:60, 20:80, and 0:100, on a volume basis) were conducted. Volatile solid (VS) concentration strongly affected the hydrogen production rate and yield compared with the waste mixing ratio. The specific hydrogen production rate was predicted to be optimal when the VS concentration ranged from 10 to 12 g/l at all the mixing ratios of molasses wastewater and sewage sludge. A hydrogen yield of over 50 ml $H_2/gVS_{removed}$ was obtained from mixed waste of 10% sewage sludge and 10 g/l VS (about 10-fold dilution ratio). The optimal chemical oxygen demand/total nitrogen ratio for co-digesting molasses wastewater and sewage sludge was between 250 and 300 with a hydrogen yield above 20 ml $H_2/gVS_{removed}$.

• 한국전기전자재료학회논문지
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• 제34권4호
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• pp.246-250
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• 2021

TFTs technologies with as high mobility as possible is essential for high-performance large displays. TFTs using nanocrystalline silicon thin films can achieve higher mobility. In this work, the change of the crystalline volume fraction at different hydrogen dilution ratios was investigated by depositing nc-Si:H thin films using PECVD. It was observed that increasing hydrogen dilution ratio increased not only the crystalline volume fraction but also the crystallite size. The thin films with a high crystalline volume fraction (55%) and a low defect density (10¹⁷ cm^-3·eV^-1) were used as top gate TFTs channel layer, leading to a high mobility (55 cm²/V·s). We suggest that TFTs of high mobility to meet the need of display industries can be benefited by the formation of thin film with high crystalline volume fraction as well as low defect density as a channel layer.

• 한국전기전자재료학회논문지
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• 제21권9호
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• pp.848-852
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• 2008

Characteristics of microcrystalline-silicon thin-films deposited by plasma-enhanced chemical-vapor deposition (PECVD) method were studied. There were optimum values of RF power density and $H_2$ dilution ratio $(H_2/(SiH_4+H_2))$; maximum grain size of about 35 nm was obtained at substrate temperature of 250 $^{\circ}C$ with RF power density of 1.1 W/$cm^2$ and $H_2$ dilution ratio of 0.91. Larger grain was obtained with higher substrate temperature up to 350 $^{\circ}C$. Grain size dependence on RF power density and $H_2$ dilution ratio could be explained by etching effects of hydrogen ions and changes of species of reactive precursors on growing surface. Surface-mobility activation of reactive precursors by temperature could be a reason of grain-size dependence on the substrate temperature. Microcrystalline-silicon thin-films that could be used for flat-panel electronics such as active-matrix organic-light-emitting-diodes are expected to be fabricated successfully using these results.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2012년도 춘계학술발표회 논문집
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• pp.338-339
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• 2012

This study examined the friction and wear behavior of diamond-like carbon (DLC) films deposited from a radio frequency glow discharge using a hydrogen diluted benzene gas mixture. The DLC films were deposited on Si (100) and polished stainless steel substrates by r.f.-PACVD at hydrogen to benzene ratios, or the hydrogen dilution ratio, ranging from 0 to 2.0. The wear test was carried out in both ambient and aqueous environments using a home-made ball-on-disk type wear rig. The stability of the DLC coating in an aqueous environment was improved by diluting the benzene precursor gas with hydrogen, suggesting that hydrogen dilution during the deposition of DLC films suppress the initiation of defects in the film and improved the adhesion of the coating to the interface.

• 대한전자공학회논문지
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• 제27권9호
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• pp.1402-1408
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• 1990

We studied the electrical, optical and structural properties of microcrystalline silicon thin films prepared by a new chemical vapour deposition technique, called filament assisted(FA)-CVD. The microcrystalline silicon is sucessfully deposited when the hydrogen dilution ratio exceeds 30. The Raman peak at 520 cm-1 and the X-ray diffraction peak at 27.7\ulcorner0.2\ulcornerbecome sharper with increasing hydrogen dilution ratio. We obtain high quality microcrystalline Si by FA-CVD with optical gap of \ulcorner2.2eV and hydrogen content of \ulcorner3 at %.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2012년도 제45회 KOSCO SYMPOSIUM 초록집
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• pp.59-60
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• 2012

This paper describes gas turbine combustion characteristics of synthetic gas which is mainly composed of hydrogen and carbon monoxide. The combustion characteristics such as combustion instability, NOx and CO emission, temperatures at turbine inlet, liner and dump plane, and flame structure were investigated when changing when changing $H_2:CO$ ratio, dilution ratio, and $CH_4:syngas$ ratio. From the results, quantitative relationships are derived between key aspects of combustion performance, notably NOx emission. It is concluded that NOx emission of syngas is strongly influenced by the diluent heat capacity and combustion instability. Moreover, NOx control method using diluents such as $N_2$, $CO_2$, steam is verified.

• 한국환경보건학회지
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• 제26권4호
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• pp.49-57
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• 2000

This study was carried out to find the optimal condition to treat refractory organic matter which can’t treat clearly with biological treatment and to find the optimal division dosage and division dose timing in the modification of Fenton oxidation which is used resolve the problem that hydrogen peroxide is too expensive. The results are following; 1. The highest TOC removal efficiency was 41% and color removal efficiency was 64% when the dilution magnitude of leachate is fold. This suggests that dilution is efficiency when high concentration of leachate is treated. 2. The removal efficiency of TOC and color increased up to the molar ratio between ferrate and hydrogen peroxide was 1:1. However above that ratio, removal efficiency hardly increased. The highest removal efficiency of TOC and color were 38% and 71% when the mole ratio of ferrate to hydrogen peroxide was 1.5:1. 3. When the mole ratio between ferrate and hydrogen peroxide was fixed, the removal efficiency of TOC and color increased as the dosage of hydrogen peroxide increased. 4. pH of samples were adjusted at pH 3, 5, 7, 9, 11. After oxidation reaction, pH of samples were dropped to 2.59, 2.54, 5.34, 6.36 and 9.68. The highest color removal efficiency was 75.7% when initial pH was at pH 7. 5. The removal of TOC and color was ended within 10. min. and the removal efficiency increased logarithmically within 10min. However after 10 min., the removal efficiency of hardly increased. 6. The color removal efficiency was higher with modification of fentone oxidation than that with fentone oxidation by 5%. Optimal division dosage ratio was 1:1 and optimal dose timing ratio was 2:1. However the TOC removal efficiency was not higher with modification of Fenton oxidation than that with Fenton oxidation.7. The CO $D_{Mn}$ /BO $D_{5}$ Ratio decreased with the time went by. It meant bioresolution increased as time went by. However, after 15 min., the CO $D_{Mn}$ /BO $D_{5}$ Ratio did not decrease any more. 8. In the case of $H_2O$$_2$ Divisiom Dose experiment, the increase of bioresolution was highest at the $H_2O$$_2$ Division dosage Ratio of 3:7.3:7.

• 한국수소및신에너지학회논문집
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• 제21권6호
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• pp.553-560
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• 2010

The characteristics of syngas-oxyfuel combustion has been investigated experimentally in the present study. Experimental measurements were conducted to aid a fundamental design of a syngas-oxyfuel combustor with a double coaxial burner configuration. To examine the effects of different syngas fuels on combustion characteristics, various fuel types are utilized such as commercial coal gases (Texaco, Shell), COG (cokes oven gas), and $CH_4$ as a main component of natural gas. $CO_2$ was added to the four fuel types as a diluent gas to reduce the flame temperature. The flame images and emission characteristics of NOx and CO were examined for various equivalence ratio and $CO_2$ dilution ratio. The results show that CO emission was rapidly increased as equivalence ratio approached the stoichiometry condition by reducing the amount of oxygen. As the $CO_2$ dilution increased, CO emission increased while NOx emission decreased due to reduced flame temperature. When the syngas-oxyfuel combustor is operated with 20~40% of $CO_2$ dilution ratio, the CO and NOx emission levels were kept below 50 ppm and 25 ppm, respectively, with a high concentration of $CO_2$ over 95 vol.% in exhaust gases.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2003년도 춘계학술발표강연 및 논문개요집
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• pp.98-98
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• 2003

비정질 실리콘 박막을 태양전지, 박막 트랜지스터, 이미지 센서, 컬러 디텍터 등에 적용하기 위한 많은 연구가 진행되고 있다. 이중 태양전지에 적용하기 위한 비정질 실리콘 박막은 p/i/n 다이오드 구조를 형성하게 되는데, 태양전지의 효율을 증가시키기 위해 결정질을 형성하거나 실리콘 화합물 박막을 적용한다. 본 연구에서는 비정질 태양전지의 흡수층(absorption layer)으로 사용되는 수소화된 비정질 박막의 결정화에 수소의 희석비가 미치는 영향을 파악하고자 하였다. PECVD 장비로 실란(SiH$_4$)과 수소(H$_2$) 가스를 이용하여 실리콘 박막을 증착하였고, 수소의 희석비(dilution ratio)를 변화시켜 비정질 실리콘 박막 내에 결정질 실리콘이 형성되는 정도를 관찰하였다. SEM과 Raman Spectroscopy를 이용해 박막의 두께 및 결정화도를 측정하였다. 실란에 대한 수소의 희석비가 증가할수록 증착률은 낮아지지만, 결정화도가 높아지는 것을 관찰할 수 있었다. 본 연구에서 형성한 결정질 실리콘 박막을 태양전지의 흡수층에 적용하면 효율 증가에 크게 기여할 것으로 판단된다.