• 한국토양비료학회지
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• 제46권1호
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• pp.32-39
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• 2013

The relationship between relative water contents of lettuce leaves and biochemical activities in lettuce was examined in this study to explore an adaptation response of lettuce to water stress from soils. Soil water contents and relative water contents of leaves were positively related to show $R^2$=0.8728. Hydrogen peroxide contents of leaves rapidly increased with reduction of soil water content, whereas soluble protein contents and dry matters rapidly decreased. And chlorophyll a and b contents of leaves decreased with increase in carotenoid content. Furthermore, the activities of ascorbate peroxidase (APX), monodehydroascorbate reductase (MDHAR), and dehydroascorbate reductase (DHAR) increased dramatically, and mRNA transcript levels of APX, MDHAR and DHAR also increased. Relationship of relative water content of lettuce leaves to hydrogen peroxide, to ascorbate peroxidase activity, to dehydroascorbate reductase activity, and to monodehydroascorbate reductase activity was shown to be positively correlated. It is highly plausible from this study that these enzyme activities could be developed as an indicator of water states in soils.

• Corrosion Science and Technology
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• 제4권3호
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• pp.95-99
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• 2005

Wheel test and potentiodynamic polarization methods were used to evaluate the relative effectiveness of some hydrogen sulfide corrosion inhibitors for the wet gas pipeline API 5L grade X 65 steel. Five commercially corrosion inhibitors have been studied in the deoxygenated produced water solutions containing 10 ppm and 100 ppm of hydrogen sulfide. Based on the experiment results the steel corrosion inhibition mechanism in discussed and two most effective corrosion inhibitors are selected.

• 전기화학회지
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• 제14권4호
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• pp.191-195
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• 2011

Wet chemical etching methods were utilized to conduct Si surface texturing, which could enhance photoelectrochemical hydrogen generation rate. Two different etching methods tested, which were anisotropic metal-catalyzed electroless etching and isotropic etching. The Si nano-texture that was fabricated by the anisotropic etching showed ~25% increase in photocurrent for H2 generation. The photocurrent enhancement was attributed to the reduced reflection loss at the nano-textured Si surface, which provided a layer of intermediate density between water and the Si substrate.

• Korean Chemical Engineering Research
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• 제59권4호
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• pp.503-507
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• 2021

이동용 고분자전해질 연료전지(PEMFC)의 수소발생용으로써 NaBH₄는 많은 장점을 갖고 있다. 야외에서 PEMFC가 이송형으로 사용될 때 증류수대신 담수를 이용해 NaBH₄ 가수분해하면 경제적이다. 그래서 본 연구에서는 NaBH₄ 가수분해 과정에 증류수대신 담수를 이용해 수소를 발생시켰다. 활성탄 담지 Co-P-B/C 촉매를 사용해 NaBH₄ 가수분해 특성에 대해 연구하였다. 담수는 NaBH₄ 가수분해과정에서 4수화물을 발생시키지 않았고, 증류수는 4수화물 부산물이 생성되어 가수분해과정에서 많은 물이 소모되어서 NaBH₄ 25% 이상 고농도에서 반응 종료시점에는 건조한 부산물과 미반응 NaBH₄가 남았음을 확인하였다. 이 결과 담수를 사용했을 때 NaBH₄ 25% 이상 고농도에서 증류수보다 수소 수율과 수소발생속도가 더 높아 무인항공기등 이송형 연료전지에도 적용하기에 적합함을 보였다.

• 한국수소및신에너지학회논문집
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• 제7권1호
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• pp.3-9
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• 1996

금속과 물의 혼합체에 전기방전을 야기시켜 수소를 제조하는 방법은 필요시에 즉시 수소를 제조할 수 있는 유용한 방법이다. 그러나 이 방법이 실제로 이용될 수 있기 위해서는 입력되는 전기에너지당 물과의 반응을 일으키는 금속의 양이 가능한한 큰 값을 가져야 한다. 이러한 에너지 효율을 높이기 위해서는 약한 전기방전이 화학반응을 지속시킬 수 있어야 된다. 이러한 효율에 직결되는 실험변수중에서 방전 전압-전류 곡선을 측정하여 토의하였다.

• 한국압력기기공학회 논문집
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• 제4권2호
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• pp.1-6
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• 2008

Very High Temperature Gas Cooled Reactor (VHTR) has been selected as a high energy heat source for nuclear hydrogen generation. The VHTR can produce hydrogen from heat and water by using a thermo-chemical process or from heat, water, and natural gas by steam reformer technology. A co-axial double-tube primary hot gas duct (HGD) is a key component connecting the reactor pressure vessel and the intermediate heat exchanger (IHX) for the VHTR. In this study, a preliminary design analysis for the primary HGD of the nuclear hydrogen system was carried out. These preliminary design activities include a determination of the size, a strength evaluation and an appropriate material selection. The determination of the size was undertaken based on various engineering concepts, such as a constant flow velocity model, a constant flow rate model, a constant hydraulic head model, and finally a heat balanced model.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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• pp.716-717
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• 2006

Gas release behavior from aluminum and Al 7075 alloy powders during heating in argon was investigated by in-situ gas chromatography. Water vapor, hydrogen, carbon mono-oxide were detected as individual evolution spectra against heating temperature and time. The mechanisms of water and hydrogen evolutions were studied in detail for the determination of effective degassing condition. Magnesium in the alloy powder was found to lower the hydrogen evolution temperature to enhance overall hydrogen release.

• Bulletin of the Korean Chemical Society
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• 제25권12호
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• pp.1869-1873
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• 2004

trans-Dihydroxo[5,10,15,20-tetrakis(n-pyridyl)porphyrinato]tin(IV) (n = 3 and 4) complexes have been synthesized and fully characterized. X-ray structural analysis of trans-dihydroxo[5,10,15,20-tetrakis(4-pyridyl)porphyrinato]tin(IV) reveals that the supramolecular hydrogen bondings between the hydroxotin(IV) porphyrins and lattice water molecules form a hydrogen-bonded two-dimensional network. The hydrogen bonding mode between the tin(IV) porphyrins and the water molecules closely resembles that of the hydrogenbonded outer-sphere intermediate in the acidolysis of dihydroxotin(IV) porphyrins.

• 멤브레인
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• 제32권6호
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• pp.475-485
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• 2022

지속적인 화석연료의 과도한 소비는 지구온난화와 기후환경 위기를 초래하고 있다. 이에 따라 화석연료의 대체 에너지 중 수소에너지가 주목받고 있는데, 수소에너지는 공해물질의 배출이 없고 자원적인 제약이 없다는 장점이 있다. 이에 따라 물의 전기분해를 이용하여 수소를 생산하는 수전해 시스템 및 수소에너지를 연료로 사용하여 전기를 생산하는 연료전지 시스템과 관련된 다양한 연구가 진행되고 있다. 본 연구에서는 수전해 시스템과 연료전지의 핵심 소재 중 하나인 음이온 전도성 이오노머 소재를 대상으로 과량의 수화 상태를 반영하여 3D 이오노머 모델을 제작하였다. 최종적으로 과량의 수화상태에서 이오노머의 구조적인 안정성과 성능 분석을 통해, 수전해 시스템과 연료전지의 핵심 소재인 음이온 전도성 이오노머 설계에 있어서 성능향상 인자를 제시하고자 하였다.

• 한국수소및신에너지학회논문집
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• 제33권6호
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• pp.607-615
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• 2022

In this study, economic analysis program was developed for economic evaluation of hydrogen production, storage/delivery, and utilization technologies as well as overseas import of hydrogen. Economic analysis program can be used for the estimation of the levelized cost of hydrogen for hydrogen supply chain technologies. This program include five hydrogen production technology on steam methane reforming and water electrolysis, two hydrogen storage technologies (high compressed gas and liquid hydrogen storage), three hydrogen delivery technologies (compressed gas delivery using tube trailer, liquid hydrogen, and pipeline transportation) and six hydrogen utilization technologies on hydrogen refueling station and stationary fuel cell system. In the case of overseas import hydrogen, it was considered to be imported from five countries (Austraila, Chile, India, Morocco, and UAE), and the transportation methods was based on liquid hydrogen, ammonia, and liquid organic hydrogen carrier. Economic analysis program that was developed in this study can be expected to utilize for planning a detailed implementation methods and hydrogen supply strategies for the hydrogen economy road map of government.