• 한국수소및신에너지학회논문집
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• 제13권1호
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• pp.90-99
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• 2002

In order to utilize hydrogen energy in a large-scale in the future, development of effective hydrogen storage method is essentially required as well as that of efficient hydrogen production method. The hydrogen storage method using metal hydrides has been holding the spotlight as a safer and higher-density hydrogen storage method than conventional hydrogen storage methods such as liquid hydrogen or compressed hydrogen storage method. However when metals react with hydrogen to store hydrogen as metal hydrides, they undergo exothermic reactions, while metal hydrides evolve hydrogen by endothermic reaction. Therefore, hydrogen storage tank should have such structure that it can absorb or release reaction heat rapidly and efficiently. In this study, a review on the improvement of the heat release and absorption structure in the hydrogen storage tank was conducted, and as a result, a new type of hydrogen storage tank with the structure of vertical-type wall was designed and manufactured. Experimental results showed that this new type of tank could be used as an efficient hydrogen storage tank because its structure is simpler and manufacture is easier than cup-type hydrogen storage tank with the structure of packed horizontal cup.

• 한국수소및신에너지학회논문집
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• 제12권2호
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• pp.75-86
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• 2001

In this paper it has been compared briefly the hydrogen storage using hydrogen storage alloys with other technologies and introduced the general properties of hydrogen storage alloys. The recent research trends and activities related to hydrogen storage alloys were given here.

• 한국수소및신에너지학회논문집
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• 제29권3호
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• pp.251-259
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• 2018

Metal hydride based hydrogen storage under moderate temperature and pressure gives the safety advantage over the gas and liquid storage methods. Still solid-state hydrogen storage including metal hydride is below the DOE target level for automotive applications, but it can be adapted to stationary or miliary application reasonably. In order to develop a modular solid state hydrogen storage system that can be applied to a distributed power supply system composed of renewable energy - water electrolysis - fuel cell, the heat transfer and hydrogen storage characteristics of the metal hydride necessary for the module system design were investigated using AB5 type metal hydride, LCN2 ($La_{0.9}Ce_{0.1}Ni_5$). The planetary high energy mill (PHEM) treatment of LCN2 confirmed the initial hydrogen storage activation and hydrogen storage capacity through surface modification of LCN2 material. Expanded natural graphite (ENG) addition to LCN2, and compression molding at 500 atm improved the thermal conductivity of the solid hydrogen storage material.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2009년도 춘계학술대회 논문집
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• pp.315-318
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• 2009

Hydrogen is the ideal candidate as an alternative energy carrier, so many hydrogen storage methods are investigated. The hydrogen storage method using metal hydride is good candidate as energy sources for portable devices because hydrogen-storage as metal hydride shows large volumetric storage density. In this study, we investigated the variations of hydrogen charging/discharging performance of metal hydride tanks at different temperature conditions. We charged metal hydride tanks with hydrogen in low temperature because of the exothermic reactions of hydrogen absorption while we discharged in high temperature to provide sufficient heat because of the endothermic reactions of desorption. In addition, we investigated the difference of hydrogen charging/discharging performance between two tanks having different sizes.

• 한국수소및신에너지학회논문집
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• 제19권1호
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• pp.90-102
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• 2008

Hydrogen storage is widely recognized as a critical enabling technology for the successful commercialization. There are a few different approaches for hydrogen storage technology. In this paper, characteristics of hydrogen storage technologies were analyzed from the literature survey. Also, The technology trend of hydrogen production was scrutinized based on patent analysis. In patent analysis the search range was limited to the open patents issued from 1996 to 2006. The technology trend of hydrogen storage was assessed by classifying each patent based on the publishing year, country, and the type of storage technology.

• 한국수소및신에너지학회논문집
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• 제23권2호
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• pp.191-197
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• 2012

The hydrogen storage is one of the key technologies to achieve the successful hydrogen economy and a chain to connect hydrogen production to its utilization. In this paper, characteristics and strong candidates of hydrogen storage technologies were analyzed from the objective information of patents. Also, the hydrogen storage technology trends and gaps were assessed using statistical or qualitative analysis. In this study the patents applied in Korea, Japan, US and EU from 10 or 20 years ago to 2011 were analyzed. The result of patent analysis could be used for developing or searching for promising technology of the hydrogen storage.

• 한국군사과학기술학회지
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• 제13권6호
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• pp.1153-1171
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• 2010

Hydrogen is the most abundant element in the universe. Although hydrogen can produce three times more energy than gasoline and seven times than coal, the most challenging problem in utilizing hydrogen as energy carrier is its storage problem. In contrast to the liquid hydrocarbon, hydrogen can not be stored or transported easily and safely because of its extremely low boiling point(21K). Recently scientists have made a tremendous achievement in storing hydrogen capacity in solid state materials such as carbon based and metal organic frameworks materials as well as metal hydrides. In this review the author reviewed the status of the hydrogen storage technologies in solid state, the advantages and disadvantages in each category of materials and the future prospects of hydrogen storage.

• 한국수소및신에너지학회논문집
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• 제19권1호
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• pp.77-89
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• 2008

There are several materials for the hydrogen storage such as hydrogen storage alloy, carbon nanomaterials, non-carbon nanomaterials, compounds etc. Efficient and inexpensive hydrogen storage is an essential prerequisite for the utilization of hydrogen, one of the new and clean energy sources. Many researches have been widely performed for the hydrogen storage techniques and materials having high storage capacity and stability. In this paper, the patents concerning the carbon nanomaterial hydrogen storage method were gathered and analyzed. The search range was limited in the open patents of Korea(KR), Japan(JP), USA(US) and European Union(EP) from 1996 to 2006. Patents were gathered by using key-words searching and filtered by filtering criteria. The trends of the patents was analyzed by the years, countries, companies, and technologies.

• 한국수소및신에너지학회논문집
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• 제33권3호
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• pp.247-254
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• 2022

Slush hydrogen containing liquid and solid hydrogen is expected to achieve zero boil-off by suppressing boil-off gas because heat of fusion for solid absorbe the heat ingress from atmosphere. In this paper, quantitative analysis on storage cost considering specific energy consumption between 1,000 m³ class liquid hydrogen storage system with re-liquefaction and slush hydrogen storage system during equivalent zero boil off period. Even though approximately 50% of total storage capacity should be converted into solid phase during the initial cargo bunkering, total energy consumption to convert into slush hydrogen is relatively 25% less than re-liquefaction energy for boil off hydrogen during zero boil off period. That's because energy consumption of slush phase change take up only 1.8% of liquefaction energy. moreover, annual revenue requirement including CAPEX, OPEX and electric cost for slush hydrogen storage could be more reduced approximately 32.5% than those of liquid hydrogen storage and specific energy storage cost ($/kg-H₂) could also be lowered by about 41.7% compared with liquid hydrogen storage.

• Bulletin of the Korean Chemical Society
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• 제33권9호
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• pp.3033-3038
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• 2012

The hydrogen storage mechanism of graphite was studied by measuring the electrical resistance change. Graphite was expanded and activated to allow for an easy hydrogen molecule approach and to enlarge the adsorption sites. A vanadium catalyst was simultaneously introduced on the graphite during the activation process. The hydrogen storage increased due to the effects of expansion, activation, and the catalyst. In addition, the electrical resistance of the prepared samples was measured during hydrogen molecule adsorption to investigate the hydrogen adsorption mechanism. It was found that the electrical resistance changed as a result of the easy hydrogen molecule approach, as well as of the adsorption process and the catalyst. It was also notable that the catalyst improved not only the hydrogen storage capacity but also the speed of hydrogen storage based on the response time. The hydrogen storage mechanism is suggested based on the effects of expansion, activation, and the catalyst.