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An Economic Analysis on Slush Hydrogen Containing Liquid and Solid Phase for Long-Term and Large-Scale Storage

장주기/대용량 수소저장을 위한 액체/고체기반 Slush 수소의 저장 비용 분석

  • PARK, SUNGHO (Energy & Environment IT Group, Plant Engineering Center, Institute for Advanced Engineering (IAE)) ;
  • LEE, CHANGHYEONG (Energy & Environment IT Group, Plant Engineering Center, Institute for Advanced Engineering (IAE)) ;
  • RYU, JUYEOL (Energy & Environment IT Group, Plant Engineering Center, Institute for Advanced Engineering (IAE)) ;
  • HWANG, SEONGHYEON (Energy & Environment IT Group, Plant Engineering Center, Institute for Advanced Engineering (IAE))
  • 박성호 (고등기술연구원 플랜트엔지니어링센터 에너지환경 IT융합 그룹) ;
  • 이창형 (고등기술연구원 플랜트엔지니어링센터 에너지환경 IT융합 그룹) ;
  • 류주열 (고등기술연구원 플랜트엔지니어링센터 에너지환경 IT융합 그룹) ;
  • 황성현 (고등기술연구원 플랜트엔지니어링센터 에너지환경 IT융합 그룹)
  • Received : 2022.04.18
  • Accepted : 2022.06.07
  • Published : 2022.06.30

Abstract

Slush hydrogen containing liquid and solid hydrogen is expected to achieve zero boil-off by suppressing boil-off gas because heat of fusion for solid absorbe the heat ingress from atmosphere. In this paper, quantitative analysis on storage cost considering specific energy consumption between 1,000 m3 class liquid hydrogen storage system with re-liquefaction and slush hydrogen storage system during equivalent zero boil off period. Even though approximately 50% of total storage capacity should be converted into solid phase during the initial cargo bunkering, total energy consumption to convert into slush hydrogen is relatively 25% less than re-liquefaction energy for boil off hydrogen during zero boil off period. That's because energy consumption of slush phase change take up only 1.8% of liquefaction energy. moreover, annual revenue requirement including CAPEX, OPEX and electric cost for slush hydrogen storage could be more reduced approximately 32.5% than those of liquid hydrogen storage and specific energy storage cost ($/kg-H2) could also be lowered by about 41.7% compared with liquid hydrogen storage.

Keywords

Acknowledgement

본 연구는 국토교통부/국토교통과학기술진흥원의 지원으로 수행되었다(과제번호 22CTAP-C163636-01).

References

  1. IPCC, "Climate change 2021: the physical science basis", IPCC Sixth Assessment Report, 2021. Retrieved from https://www.ipcc.ch/report/ar6/wg1/.
  2. European Environment Agency (EEA), "Observed trends in total greenhouse gas concentration levels between 1860 and 2018, considering all greenhouse gases and other forcing agents (including aerosols)", EEA, 2021. Retrieved from https://www.eea.europa.eu/dataandmaps/daviz/observed-trends-in-total-global-8#tab-googlechartid_chart_11.
  3. M. Gardiner, "Energy requirements for hydrogen gas comp ression and liquefaction as related to vehicle storage needs", DOE Hydrogen and Fuel Cells Program Record, 2009. Retrieved from https://www.hydrogen.energy.gov/pdfs/9013_energy_requirements_for_hydrogen_gas_ compression.pdf.
  4. S. H. Park, J. K. Ahn, J. Y. Ryu, and A. R. Ko, "Performance evaluation and optimization of hydrogen liquefaction process using the liquid air for pre-cooling", Trans Korean Hydrogen New Energy Soc, Vol. 30, No. 6, 2019, pp. 490-498, doi: https://doi.org/10.7316/KHNES.2019.30.6.490.
  5. S. M. Aceves, F. E. Loza, E. L. Orozco, T. O. Ross, A. H. Weisberg, T. C. Brunner, and O. Kircher, "Highdensity automotive hydrogen storage with cryogenic capable pressure vessels", Int. J. Hydrogen Energy, Vol. 35, No. 3, 2010, pp. 1219-1226, doi: https://doi.org/10.1016/j.ijhydene.2009.11.069.
  6. I. K. Jung and B. H. Kang, "Thermal analysis of a liquid hydrogen vessel with multi-layer-insulation and vapor-cooled shield", Trans Korean Hydrogen New Energy Soc, Vol. 16, No. 3, 2005, pp. 284-289. Retrieved from https://www.koreascience.or.kr/article/JAKO200521036737858.page.
  7. M. Aziz, "Liquid hydrogen: a review on liquefaction, storage, transportation, and safety", Energies, Vol. 14, No. 18, 2021, pp. 5917, doi: https://doi.org/10.3390/en14185917.
  8. T. Jin, Y. J. Li, Z. B. Liang, Y. Q. Lan, G. Lei, and X. Gao, "Numerical prediction of flow characteristics of slush hydrogen in a horizontal pipe", Int. J. Hydrogen Energy, Vol. 42, No. 6, 2017, pp. 3778-3789, doi: https://doi.org/10.1016/j.ijhydene.2016.09.054.
  9. B. Kim, D. Kwon, and S. Jeong, "Temperature distribution of long-length high temperature superconducting cable cooled by slush-nitrogen", Cryogenics, Vol. 124, 2021, doi: https://doi.org/10.1016/j.cryogenics.2021.103369.
  10. Y. Li, T. Jin, S. Wu, J. Wei, J. Xia, and T. G. Karayiannis, "Heat transfer performance of slush nitrogen in a horizontal circular pipe", Thermal Science and Engineering Progress, Vol. 8, 2018, pp. 66-77, doi: https://doi.org/10.1016/j.tsep.2018.08.001.
  11. R. F. Dwyer, G. A. Cook, and D. H. Stellrecht, "Laboratory production of fluid hydrogen slush", Ind. Eng. Chem. Prod. Res. Dev., Vol. 3, No. 4, 1964, pp. 316-320, doi: https://doi.org/10.1021/i360012a015.
  12. R. O. Voth, "Producing liquid-solid mixtures of hydrogen using an auger", NBSIR 78-875, 1978. Retrieved from https://www.govinfo.gov/content/pkg/GOVPUB-C13-62e13fd5155dd401e4978eda74dca0a3/pdf/GOVPUB-C13-62e13fd5155dd401e4978eda74dca0a3.pdf.
  13. D. E. Daney, V. D. Arp, and R. O. Voth, "Hydrogen slush production with a large auger", Advances in Cryogenic Engineering, Vol. 35, 1990, pp. 1767-1776. Retrieved from https://link.springer.com/chapter/10.1007/978-1-4613-0639-9_208.
  14. A. M. Swanger, W. U. Notardonato, J. E. Fesmire, K. M. Jumper, W. L. Johnson, and T. M. Tomsik, "Large scale production of densified hydrogen to the triple point and below", IOP Conf. Ser.: Mater. Sci. Eng., Vol. 278, 2017, pp. 8, doi: https://doi.org/10.1088/1757-899X/278/1/012013.
  15. W. U. Notardonato, A. M. Swanger, J. E. Fesmire, K. M. Jumper, W. L. Johnson, and T. M. Tomsik, "Final test results for the ground operations demonstration unit for liquid hydrogen", Cryogenics, Vol. 88, 2017, pp. 147-155, doi: https://doi.org/10.1016/j.cryogenics.2017.10.008.
  16. C. H. Lee, J. Y. Ryu, G. Sohn, and S. H. Park, "Technical review on liquid/solid (slush) hydrogen production unit for long-term and bulk storage", Trans Korean Hydrogen New Energy Soc, Vol. 32, No. 6, 2021, pp. 565-572, doi: https://doi.org/10.7316/KHNES.2021.32.6.565.
  17. M. Hurskainen, "Liquid organic hydrogen carriers (LOHC): concept evaluation and techno-economics", VTT Technical Research Centre of Finland, VTT Research Report No. VTT-R-00057-19, 2019. Retrieved from https://cris.vtt.fi/en/publications/liquid-organic-hydrogen-carriers-lohc-concept-evaluation-and-tech.
  18. D. Hart, J. Howes, P. E. Dodds, N. Hughes, B. Fais, N. Sabio, and M. Crowther, "Scenarios for deployment of hydrogen in contributing to meeting carbon budgets and the 2050 target", Committee on Climate Change Final Report, 2015. Retrieved from https://www.theccc.org.uk/wp-content/uploads/2015/11/E4tech-for-CCC-Scenarios-for-deployment-of-hydrogen-in-contributing-to-meeting-carbon-budgets.pdf.
  19. E. Connelly, M. Penev, A. Elgowainy, and C. Hunter, "Current status of hydrogen liquefaction costs", DOE Hydrogen and Fuel Cells Program Record, 2019. Retrieved from https://www.hydrogen.energy.gov/pdfs/19001_hydrogen_liquefaction_costs.pdf.