• Rapid Communication in Photoscience
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• v.4 no.4
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• pp.82-85
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• 2015

Photoelectrochemical cell (PEC) is one of the attractive ways to produce clean and renewable energy. However, solar to hydrogen production via PEC system generally requires high external bias, because of material's innate electronic band potential relative to hydrogen reduction potential and/or charge separation issue. For spontaneous photo-water splitting, here, we design dye-sensitized solar cell (DSSC) and their monolithic tandem cell incorporated with a $BiVO_4$ photoanode. $BiVO_4$ has high conduction band edge potential and suitable band gap (2.4eV) to absorb visible light. To achieve efficient $BiVO_4$ photoanode system, electron and hole mobility should be improved, and we demonstrate a tandem cell in which $BiVO_4/WO_3$ film is connected to cobalt complex based DSSC.

• Journal of Hydrogen and New Energy
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• v.21 no.3
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• pp.241-247
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• 2010

An Energy Efficiency Resource Standards (EERS) is a simple, market-based mechanism to encourage more efficient generation, transmission, and use of electricity, natural gas and heat. An EERS consists of electric, gas and/or heating energy savings targets for utilities, often with flexibility to achieve the target through a market-based trading system. In this paper, we make persons acquainted with EERS programs of foreign countries in these days. And we analyze domestic energy demand side management (DSM) programs in order to introduce an EERS program into the country successfully. Energy efficiency potential calculated in 2007 is one of the important factors for establishing an EERS program domestically. This study may provide basic data to set the amount of energy saving when an EERS program would be phased in.

• Journal of Environmental Impact Assessment
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• v.17 no.1
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• pp.67-79
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• 2008

Global warming, which is one of the most serious challenges, has been the subject of intense debate and concern for many scientists, policy-makers, and citizens for at least the past decade. To protect the health and economic well-being of current and future generations, we must reduce our emissions like carbon dioxide. Alternatives to achieve an energy future without serious global warming are to change to clean and renewable sources of energy like the wind, the sun lights, rivers, the biomass, hydrogen, and oceans. To identify some of the key and new environmental impacts associated with renewable energy and hydrogen energy, we set up the new conceptual methodology. Specifically, new identified environmental and health impacts are related with the usage of hydrogen energy. When comparing with fossil fuel, the renewable energies can reduce the release of carbon dioxide when they are used except hydrogen produced from fossil fuel. However, all renewable energy technologies are not appropriate to all applications or locations. Our results suggest that all of alternatives to replace fossil fuel can release the several global and local impacts although they seems to be smaller than the impacts from fossil fuel. Therefore, the quantitative and detail analysis to assess environmental impacts of the alternative energies might be useful to make our decision for the future energy against the global warming.

• Transactions of the Korean Society of Automotive Engineers
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• v.19 no.1
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• pp.1-8
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• 2011

In recent years, there has been an interest in early-injection diesel engines as it has the potential of achieving a more homogeneous and leaner mixture close to TDC compared to standard diesel engine. The more homogeneous mixture may result in reduced NOx and soot emissions and higher efficiency in homogeneous charge compression ignition engines. While earlier studies have shown that a reduction in NOx emissions from HCCI engine is possible, there are some significant problems including the control of ignition timing and combustion rate. In order to investigate the effect of EGR and hydrogen enriched gas on combustion characteristics and emissions, an experiments with single cylinder CRDi engine were carried out concerning the formation of various premixed charge, which can achieved by early injection, EGR and hydrogen enriched gas. EGR was not effective to further reduce NOx and PM emissions. It was found that NOx emissions were decreased with an introduction of hydrogen enriched gas and an adequate diesel fuel amount.

• Applied Chemistry for Engineering
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• v.31 no.1
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• pp.1-6
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• 2020

Hydrogen production from biogas has received consistent attention due to the great potential to solve simultaneously the issues of energy demands and environmental problems. Practically, biomethane produced by purification/upgrading of biogas can be a good alternative to the natural gas which is a main reactant for a steam methane reforming process. Judging from the economic and environmental impacts, however, the steam biogas and dry reforming are considered to be more effective routes for hydrogen production because both processes do not require the carbon dioxide elimination step. Herein, we highlight recent studies of hydrogen production via reforming processes using biogas and effective applications for earlier commercialization.

• Transactions on Electrical and Electronic Materials
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• v.4 no.2
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• pp.1-4
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• 2003

The purpose of this study was to investigate the characteristics of slurry including phosphoric acid for chemical-mechanical planarization of copper and tantalum nitride. In general, the slurry for copper CMP consists of alumina or colloidal silica as an abrasive, organic acid as a complexing agent, an oxidizing agent, a film forming agent, a pH control agent and additives. Hydrogen peroxide (H$_2$O$_2$) is the material that is used as an oxidizing agent in copper CMP. But, the hydrogen peroxide needs some stabilizers to prevent decomposition. We evaluated phosphoric acid (H$_3$PO$_4$) as a stabilizer of the hydrogen peroxide as well as an accelerator of the tantalum nitride CMP process. We also estimated dispersion stability and zeta potential of the abrasive with the contents of phosphoric acid. An acceleration of the tantalum nitride CMP was verified through the electrochemical test. This approach may be useful for the development of the 2$\^$nd/ step copper CMP slurry and hydrogen peroxide stability.

• Journal of Hydrogen and New Energy
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• v.15 no.3
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• pp.250-256
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• 2004

Magnesium and its alloys have the high potential as hydrogen storage materials because of their highest hydrogen storage capacity, low density and abundant resources. But poor kinetic properties of hydriding and dehydriding and high working temperature have limited their practical applications. In this study, the Mg-Ni binary alloys with different amount of Ni were produced by gravity casting and characterized in order to investigate the relationship between the microstructures and hydriding properties. The maximum hydrogen absorption capacity decreased, but the absorption kinetics increased with Ni content. The difference in the absorption kinetics was resulted from the differences in the sort and shape of primary solid phases and eutectic microstructure.

• Journal of Hydrogen and New Energy
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• v.19 no.4
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• pp.291-298
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• 2008

Carbon monoxide(CO) is one of the contamination source in reformed hydrogen fuel with an influence on performance of polymer electrolyte membrane fuel cell(PEMFC). The studies of CO injection presented here give information about poisoning and recovery processes. The aim of this research is to investigate cell performance decline due to carbon monoxide impurity in hydrogen. Performance of PEM fuel cell was investigated using current vs. potential experiment, long time(10 hours) test, cyclic feeding test and electrochemical impedance spectra. The concentrations of carbon monoxide were changed up to 10 ppm. Performance degradation due to carbon monoxide contamination in anode fuel was observed at high concentration of carbon monoxide. The CO gas showed influence on the charge transfer reaction. The performance recovery was confirmed in long time test when pure hydrogen was provided for 1 hour after carbon monoxide had been supplied. The result of this study could be used as a basis of various reformation process design and fuel quality determination.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.08a
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• pp.69-69
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• 2013

In the area of artificial photosynthesis, particularly for the generation of hydrogen form water, much attention has been paid on organic-inorganic hybrid system. Most of all, a dye/TiO2-combined system has been suggested and its potential utility was well manifested. However, due to its complicated nature of charge interactions in between dye and TiO2 -interface there remains a great challenge to establish the charge-activity relationship, per se light driven charge generation and recombination kinetics with respect to the amount of hydrogen produced. Further complexity of that hybrid system has been witnessed when sacrificial donor and aqueous media are considered. To unveil the operating mechanism on such a dye/TiO2-combined system, we have prepared organic dyes suitable to account for the effect of sacrificial donor as well as water interactions, and prepared the typical dye-grafted TiO2 films to investigate charge-activity relationship. Femtosecond flash photolysis clearly defined the dye effects anchored on to the TiO2 platform. In addition, photodynamic data contemplated well to the dye orientation proposed by the DFT calculations. Recent findings provide fundamental understanding on the dye-grafted TiO2 system and establish a firm background how future dye-sensitized organic-inorganic hybrid system can be designed for the light driven hydrogen generation from water.

• Journal of the Korean Institute of Gas
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• v.25 no.4
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• pp.57-62
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• 2021

In this study, risk assessment was conducted in case of leakage of storage facilities (tube trailer) using the HyKoRAM program developed through international joint research. The high-pressure gas facilities in the hydrogen filling station are divided into four main categories: storage facilities (tube trailers), processing facilities (compressors), compressed gas facilities, and filling facilities (dispensers). Among them, the design specifications of the tube trailer, which is a storage facility, and the surrounding environmental conditions were reflected to construct an accident scenario with previously occurring accidents and potential accidents. Through this, we identify the risks of storage facilities at hydrogen refueling stations and suggest measures to improve the safety of hydrogen charging stations.