• Title/Summary/Keyword: Hybrid polymer

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Synergistic effect of clay and polypropylene short fibers in epoxy based ternary composite hybrids

  • Prabhu, T. Niranjana;Demappa, T.;Harish, V.;Prashantha, K.
    • Advances in materials Research
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    • v.4 no.2
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    • pp.97-111
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    • 2015
  • Polypropylene short fiber (PP)-clay particulate-epoxy ternary composites were prepared by reinforcing PP short fiber and clay particles in the range of 0.1 phr to 0.7 phr into epoxy resin. Prepared hybrid composites were characterized for their mechanical, thermal and flame retardant properties. The obtained results indicated an increase in impact resistance, tensile strength, flexural strength and Young's modulus to an extent (up to 0.5 phr clay and 0.5 phr PP short fiber) and then decreases as the reinforcing phases are further increased. The thermal stability of these materials are found to increase up to 0.2 phr clay and 0.2 phr PP addition, beyond which it is decreased. Addition of clay is found to have the negative effect on epoxy-PP short fiber composites, which is evident from the comparison of mechanical and thermal properties of epoxy-0.5 phr PP short fiber composite and epoxy-0.5 phr PP short fiber-0.5 phr clay composite hybrid. UL-94 tests conducted on the composite hybrids have showed a reduction in the burning rate. Morphological observations indicated a greater fiber pull with the addition of clay. The performed tests in the present study indicated that materials under investigation have promising applications in construction, agriculture and decorative purposes.

The Study of Biofouling Control and Cause Material in Hybrid Process of Pure Oxygen and Submerged Membrane Bio-reactor (순산소 고율포기시스템 및 침지식 MBR융합공정에서 Biofouling 제어 및 원인물질 규명에 관한 연구)

  • Lee, Sang-Min;Kim, Mi-Hyung
    • Journal of Korean Society on Water Environment
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    • v.27 no.1
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    • pp.44-53
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    • 2011
  • Membrane bio-reactor (MBR) has several advantages over the conventional activated sludge process, including a high biomass, low sludge production, and better permeate quality. Therefore, the MBR have gained popularity for municipal and industrial wastewater treatment. However the MBR usually were used for sewage and low streng th wastewater treatment because of membrane fouling problem and limitation of oxygen transfer into biomass. In this study, the hybrid process combining MBR and pure oxygen was tested for high strength organic wastewater treatment in the COD loading range from 2 to $10kgCOD/m^3{\cdot}day$. The hybrid process, membrane coupled pure oxygen high compact reactor (MPHCR), had been operated for one year and operation parameters, the effect of COD loading, MLSS concentration and the location of membrane module were studied for membrane fouling characteristic. Also membrane resistance test and the component of foulant was analyzed to investigate what is specific foulant in the MBR.

Effect of the GFRP wrapping on the shear and bending Behavior of RC beams with GFRP encasement

  • Ozkilic, Yasin Onuralp;Gemi, Lokman;Madenci, Emrah;Aksoylu, Ceyhun;Kalkan, İlker
    • Steel and Composite Structures
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    • v.45 no.2
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    • pp.193-204
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    • 2022
  • The need for establishing the contribution of pultruded FRP encasements and additional FRP wraps around these encasements to the shear strength and load-deflection behavior of reinforced concrete beams is the main motivation of the present study. This paper primarily focuses on the effect of additional wrapping around the composite beam on the flexural and shear behavior of the pultruded GFRP (Glass Fiber Reinforced Polymer) beams infilled with reinforced concrete, taking into account different types of failure according to av/H ratio (arch action, shear-tension, shear-compression and pure bending). For this purpose, nine hybrid beams with variable shear span-to-depth ratio (av/H) were tested. Hybrid beams with 500 mm, 1000 mm, and 1500 mm lengths and cross-sections of 150x100 mm and 100x100 mm were tested under three-point and four-point loading. Based on the testing load-displacement relationship, ductility ratio, energy dissipation capacity of the beams were evaluated with comprehensive macro damage analysis on pultruded GFRP profile and GFRP wrapping. The GFRP wraps were established to have a major contribution to the composite beam ductility (90-125%) and strength (40-75%) in all ranges of beam behavior (shear-dominated or dominated by the coupling of shear and flexure). The composite beams with wraps were showns to reach ductilities and strength values of their counterparts with much greater beam depth.

Synthesis and Characterization of Organo-Clay Based Thermotropic Liquid Crystalline Polyester Nanocomposites (유기화 점토를 이용한 열방성 액정 폴리에스테르 나노복합재료의 합성과 특성 연구)

  • 서보수;장진해
    • Polymer(Korea)
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    • v.25 no.6
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    • pp.876-883
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    • 2001
  • A thermotropic liquid crystalline polyester (TLCP) containing a side group was, synthesized from ethoxyhydroquinone and bromoterephthalic acid. Intercalation of TLCP in layered clays is accomplished by heating the polymer with hexadecyl ammonium-montmorillonite ($C_{16}$) above melting transition temperature ($T_m$). Liquid crystallinity of the TLCP/$C_{16}$-hybrid was observed up to 6 wt% $C_{16}$-MMT. Some of the $C_{16}$-MMTs in TLCP were highly dispersed in a nanometer scale, but some of them were agglomerated. Thermal and morphological properties of the nanocomposites were examined by differential scanning calorimetry (DSC), thermogravimetric analyzer (TGA), polarized optical microscope, and electron microscopes (SEM and TEM).

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A Fundamental Study on Polymer/Metal Additive Method using a UV Laser for Consumer-oriented 3D Helmet Products (소비자 지향 3차원 헬멧제품 제작을 위한 UV레이저 기반의 폴리머/금속적층에 대한 기초연구)

  • Kang, Bo-Seok;Ahn, Dong-Gyu;Shin, Bo-Sung;Shin, Jong-Kuk
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.15 no.6
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    • pp.89-94
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    • 2016
  • Consumer orientation requires that companies understand consumer needs and produce products that meet their expectations. This study proposes a new additive method that creates a polymer/metal bonding layer and thus can lighten the weight of helmets to develop a consumer-oriented 3D printing helmet. The composite solution is experimentally prepared with copper formate and a photopolymer resin. Stereolithography apparatus and photothermal reactions are introduced to fabricate an adhesive hybrid layer of copper metal and polymer. A UV pulse laser with a 355 nm wavelength was installed to simplify this process. Resistance, adhesion, and accuracy were investigated to evaluate the properties of the layer produced.

Early Stage Growth Structure and Stress Relaxation of CoCrPt Thin Films on Spherically Modulated Polymer Surface

  • Kim, Sa-Rah;Jeong, Jun-Ho;Shin, Sung-Chul;Son, Vo Thanh;Jeon, Bo-Geon;Kim, Cheol-Gi;Jeong, Jong-Ryul
    • Journal of Magnetics
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    • v.15 no.1
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    • pp.12-16
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    • 2010
  • Combined study of in-situ stress measurements and atomic force microscopy (AFM) revealed drastic stress relaxation in the CoCrPt and PS(styrene)-PVP(vinyl pyridine) polymer hybrid structure that was closely related to the growth structure of the film. We have observed not only no large initial growth stress at the initial stages of film growth but also twice smaller stress in magnitude with opposite sign in the CoCrPt/PS-PVP/Si sample. The microstructural studies using AFM at the various film growth stages revealed that the film growth structure plays an important role in the stress relaxation mechanism of CoCrPt films on a corrugated polymer surface.

Effect of ${\gamma}$-Ray Irradiation on Surface Oxidation of Ultra High Molecular Weight Polyethylene/Zirconia Composite Prepared by in situ Ziegler-Natta Polymerization

  • Kwak, Soon-Jong;Noh, Dong-Il;Chun, Heung-Jae;Lim, Youn-Mook;Nho, Young-Chang;Jang, Ju-Woong;Shim, Young-Bock
    • Macromolecular Research
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    • v.17 no.8
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    • pp.603-608
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    • 2009
  • Novel ultra-high molecular weight polyethylene (UHMWPE)/zirconia composites were previously prepared by the in situ polymerization of ethylene using a Ti-based Ziegler-Natta catalyst supported on to the surface of zirconia, as a bearing material for artificial joints. Tribological tests revealed that a uniform dispersion of zirconia in UHMWPE markedly increased the wear resistance. The effects of zirconia content on the oxidation behavior of the ${\gamma}$-ray-treated UHMWPE/zirconia composite surfaces were examined. The oxidation index that estimates the oxidation degree as the content of total carbonyl compounds was monitored using Fourier transform infrared spectroscopy-attenuated total reflectance. The changes in the surface composition due to the oxidation were confirmed by electron spectroscopy for chemical analysis. The extent of oxidation decreased with increasing zirconia content, which was attributed to the increased crystallinity as well as the decreased polymer portion of the UHMWPE/zirconia composites.

PSO based neural network to predict torsional strength of FRP strengthened RC beams

  • Narayana, Harish;Janardhan, Prashanth
    • Computers and Concrete
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    • v.28 no.6
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    • pp.635-642
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    • 2021
  • In this paper, soft learning techniques are used to predict the ultimate torsional capacity of Reinforced Concrete beams strengthened with Fiber Reinforced Polymer. Soft computing techniques, namely Artificial Neural Network, trained by various back propagation algorithms, and Particle Swarm Optimization (PSO) algorithm, have been used to model and predict the torsional strength of Reinforced Concrete beams strengthened with Fiber Reinforced Polymer. The performance of each model has been evaluated by using statistical parameters such as coefficient of determination (R2), Root Mean Square Error (RMSE), and Mean Absolute Percentage Error (MAPE). The hybrid PSO NN model resulted in an R2 of 0.9292 with an RMSE of 5.35 for training and an R2 of 0.9328 with an RMSE of 4.57 for testing. Another model, ANN BP, produced an R2 of 0.9125 with an RMSE of 6.17 for training and an R2 of 0.8951 with an RMSE of 5.79 for testing. The results of the PSO NN model were in close agreement with the experimental values. Thus, the PSO NN model can be used to predict the ultimate torsional capacity of RC beams strengthened with FRP with greater acceptable accuracy.

Forming Simulation of EV Motor Hairpin by Implementing Mechanical Properties of Polymer Coated Copper Wire (고분자 필름 및 구리선 이종 물성을 고려한 EV모터용 헤어핀 성형 공정 해석)

  • D. C. Kim;Y. J. Lim;M. Baek;M. G. Lee;I. S. Oh
    • Transactions of Materials Processing
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    • v.32 no.3
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    • pp.122-128
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    • 2023
  • As electric vehicles (EV) have increasingly replaced the conventional vehicles with internal combustion engines (ICE), most of automotive makers are actively devoting to the technology development of EV parts. Accordingly, the manufacturing process for power source has been also shifting from engine/transmission to EV motor/reducer system. However, lack of experience in developing the EV motor still remains as a technical challenge. In this paper, we employed the forming simulation based on finite element modeling to solve this problem. In particular, in order to increase the accuracy of the forming simulation, we introduced the elastic-plastic constitutive model parameters for polymer-copper hybrid wire by investigating the individual strain-stress curves, and elastic modulus of polymer and copper. Then, the reliability of modeling procedure was confirmed by comparing the simulated results with experiments. Finally, the identified mechanical properties and finite element modeling were applied to a hairpin forming process, which involves multiple deformation paths such as bending, pressing, widening, and twisting. The proposed numerical approach can replace common experience or experiment based trials by reducing production time and cost in the future.

Fabrication of Superhydrophobic Micro-Nano Hybrid Structures by Reactive Ion Etching with Au Nanoparticle Masks (나노입자 마스크를 이용하여 제작한 초소수성 마이크로-나노 혼성구조)

  • Lee, C.Y.;Yoon, S.B.;Jang, G.E.;Yun, W.S.
    • Journal of the Korean Vacuum Society
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    • v.19 no.4
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    • pp.300-306
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    • 2010
  • Superhydrophobic micro-nano hybrid structures were fabricated by reactive ion etching of hydrophobic polymer micro patterns using gold nanoparticles as etch masks. Micro structures of perfluoropolyether bisurethane methacrylate (PFPE) were prepared by soft-lithographic technique using polydimethylsiloxane (PDMS) molds. Water contact angles on the surfaces of various PFPE micro structures and corresponding micro-nano hybrid structures were compared to examine the effects of micro patterning and nanostructure formation in the manifestation of superhydrophobicity. The PFPE micro-nano hybrid structures exhibited a very stable superhydrophobicity, while the micro-only structures could not reach the superhydrophobicity but only showed the unstable hydrophobicity.