• 제목/요약/키워드: Hybrid ceramic

검색결과 266건 처리시간 0.025초

고성능 리튬 이온전지를 위한 폴리머-세라믹 복합 겔 고분자 전해질 (Polymer-Ceramic Composite Gel Polymer Electrolyte for High-Electrochemical-Performance Lithium-Ion Batteries)

  • 장소현;김재광
    • 전기화학회지
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    • 제19권4호
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    • pp.123-128
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    • 2016
  • 본 연구에서는 poly(vinylidene fluoride-co-hexafluoropropylene) (PVdF-HFP)를 나노 크기의 $Al_2O_3$ 세라믹입자와 혼합하여 전기방사법으로 복합 겔 고분자 전해질을 제조하였다. $Al_2O_3$ 세라믹입자를 혼합한 복합 겔 고분자 전해질의 이온전도도는 $9.5{\times}10^{-2}Scm^{-1}$로, 순수한 PVdF-HFP 겔 고분자 전해질보다 높은 이온전도도를 나타내며 전기화학적 안정성도 5.2 V까지 개선하였다. 전기화학적 성능을 분석하기 위해서 $LiNi_{1/3}Mn_{1/3}Co_{1/3}O_2$ (NMC)양극과 함께 전지로 제작되었으며 순수 겔 고분자 전해질과 복합 겔 고분자 전해질 셀은 0.1C-rate에서 각각 $168.2mAh\;g^{-1}$$189.6mAh\;g^{-1}$의 방전 용량을 가지며 우수한 수명 특성을 보여 주었다. 따라서 고유전율 세라믹 입자의 복합화는 리튬 이온 겔 고분자 전지의 안정성과 전기화학적 특성을 향상시키는 좋은 대안이 될 것으로 판단된다.

합착용 복합레진시멘트로 합착한 Machinable Ceramic과 상아질 사이의 인장강도에 대한 실험적 연구 (TENSILE STREGNTH BETWEEN MACHINABLE CERAMIC AND DENTIN CEMENTED WITH LUTING COMPOSITE RESIN CEMENTS)

  • 조병훈
    • Restorative Dentistry and Endodontics
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    • 제23권1호
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    • pp.487-501
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    • 1998
  • In the case of CAD/CAM ceramic inlay restorations, if isthmus width is widened too much, it may cause fracture of remaining tooth structure or loss of bonding at the luting interface because of excessive displacement of buccal or lingual cusps under occlusal loads. So to clarify the criterior of widening isthmus width, this study was designed to test the tensile bond strength and bond failure mode between dentin and ceramic cemented with luting composite resin cements. Cylindrical ceramic blocks(Vita Cerec Mark II, d=4mm) were bonded to buccal dentin of 40 freshly extracted third molars with 4 luting composite resin cements(group1 : Scotchbond Resin Cement/Scotchbond Multi-Purpose, group2 : Duolink Resin Cement/ All-Bond 2, group3: Bistite Resin Cement/Ceramics Primer, and group4:Superbond C&B). Tensile bond test was done under universal testing machine using bonding and measuring alignment blocks(${\phi}ilo$ & Urn, 1992). After immersion of fractured samples into 1 % methylene blue for 24 hours, failure mode was analysed under stereomicroscope and SEM. Results: The tensile bond strength of goup 1, 2 & 4 was $13.97{\pm}2.90$ MPa, $16.49{\pm}3.90$ MPa and $16.l7{\pm}4.32$ MPa, respectively. There was no statistical differences(p>0.05). But, group 3 showed significantly lower bond stregnth($5.98{\pm}1.l7$ MPa, p<0.05). In almost all samples, adhesive fractures between dentin and resin cements were observed. But, in group 1, 2 & 4, as bond strength increased, cohesive fracture within resin cement was observed simultaneously. And, in group 3, as bond strength decreased, cohesive fracture between hybrid layer and composite resin cement was also observed. Cohesive fracture within dentin and porcelain adhesive fracture were not observed. In conclusion, although adhesive cements were used in CAD/CAM -fabricated ceramic inlay restorations, the conservative priciples of cavity preparation must be obligated.

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Processing of Vermiculite-Silica Composites with Prefer-Oriented Rod-Like Pores

  • Eom, Jung-Hye;Kim, Young-Wook;Lee, Seung-Seok;Jeong, Doo-Hoa
    • 한국세라믹학회지
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    • 제49권4호
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    • pp.347-351
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    • 2012
  • Vermiculite-silica composites with a layered structure were fabricated by adding cellulose fibers as a pore former and by a simple uniaxial pressing and subsequent sintering process. Three different combinations of additives were used and their effects on the compressive strength and thermal conductivity of the composites were investigated. Both compressive strengths (42-128 MPa) and thermal conductivities (0.75-1.48 $W/m{\cdot}K$) in the direction perpendicular to the pressing direction (T) were higher than those (19-81 MPa and 0.32-1.04 $W/m{\cdot}K$) in the direction parallel to the pressing direction (S) in all samples. The anisotropy in both properties was attributed to the microstructural anisotropy, which was caused by the layered structure developed in the composites.

압전 발전기를 이용한 에너지 수확 장치 개발 (Development of the Energy Harvesting Device using Piezoelectric Generator)

  • 전호익;정성수;정현호;박충효;박민호;박태곤
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2009년도 하계학술대회 논문집
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    • pp.439-439
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    • 2009
  • Nowadays, source of MEMS, USN, Hybrid parts pay attention to energy harvesting. On this paper, energy harvesting was studied using piezoelectric effect. And, piezoelectric generator was designed and fabricated. Generators were designed by FEM simulation program and generators were made by attaching cymbal type metal plates on upper and bottom sides of a disc type piezoelectric ceramic. Output AC power was rectified to DC power by full bridge circuit and converted to regular voltage power by DC-DC converter. The final output power was charged to Ni-Cd battery. Using fabricated generators, output voltages dependant on thickness of ceramic, displacement of vibration, frequency of vibration were measured.

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임베디드 커패시터를 이용한 하이브리드 자동차 커패시터 모듈 특성 연구 (Ceramic capacitor module for hybrid-electric vehicles using embedded capacitor)

  • 윤중락;문봉화;이경민;한정우
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2009년도 하계학술대회 논문집
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    • pp.18-18
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    • 2009
  • 본 논문은 X8R 온도 특성을 가지는 유전체 원료를 이용하여 고용량이면서 고압화가 가능한 적층 칩 캐패시터를 제작하였다. 대형 고압용 적층 칩 캐패시터를 위한 내부 전극 설계 및 외부 전극 형성 방법에 대한 연구도 함께 진행하였다. 적층 칩 캐패시터를 하이브리드 자동차 및 산업용 인버터의 DC-Link으로 사용하기 적합한 모듈을 제작하였으며 모듈 설계시 고유전율의 에폭시-세라믹 필름을 하였다. 본 모듈을 평가한 결과 기존 캐패시터 모듈에 비하여 2/3 크기의 소형화를 얻을 수 있었으며 ripple 전류 및 발열 특성이 매우 우수함을 확인하였다.

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Trends in Computational Materials Science Based on Density Functional Theory

  • Lee, June Gunn
    • 한국세라믹학회지
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    • 제53권2호
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    • pp.184-193
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    • 2016
  • This review deals with computational treatments of subatomic levels of matter based on density functional theory (DFT), and tries to identify several current trends, which are largely consequences of the ever-increasing power of computers, which has substantially extended the performance of conventional DFT beyond its original scope. This review mainly focuses on the conceptual outline, rather than on lines of equations, highlighting several examples of calculations for each topic. It should be noted that these issues are hardly new to leading groups in the field, but certainly are for materials people in general. It should also be noted that the on-going efforts will continue and lead to a larger system size, a longer time scale, a higher accuracy, and a better efficiency of calculation for years to come.

Fabrication of a (100) Silicon Master Using Anisotropic Wet Etching for Embossing

  • Jung, Yu-Min;Kim, Yeong-Cheol
    • 한국세라믹학회지
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    • 제42권10호
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    • pp.645-648
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    • 2005
  • To fabricate a (100) silicon hard master, we used anisotropic wet etching for the embossing. The etching chemical for the sili­con wafer was a TMAH 25$\%$ solution. The anisotropic wet etching produces a smooth sidewall surface inclined at 54.7°, and the surface roughness of the fabricated master is about 1 nm. After spin coating an organic-inorganic sol-gel hybrid resin on a silicon substrate, we used the fabricated master to form patterns on the silicon substrate. Thus, we successfully obtained patterns via the hot embossing technique with the (100) silicon hard master. Moreover, by using a single hydrophobic surface treatment of the master, we succeeded in achieving uniform surface roughness of the embossed patterns for more than ten embossments.

Nanostructured Bulk Ceramics (Part II. Superplasticity and High Strain Rate Superplasticity)

  • Han, Young-Hwan;Mukherjee, Amiya K.
    • 한국세라믹학회지
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    • 제46권4호
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    • pp.345-349
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    • 2009
  • In Part II, the paper will describe a three-phase alumina-based nanoceramic composite demonstrating superplasticity at a surprisingly lower temperature and higher strain rate. One important factor in the processing of these nanocomposites was the use of the electrical field assisted sintering method, SPS. These improvements in mechanical properties were briefly discussed in the context of the results from the microstructural investigations. SPS forming approach provides a new route for low temperature and high-strain-rate superplasticity for nanostructured materials and should impact and interest a broad range of scientists in materials research and superplastic forming technology.

원판형 압전 세라믹을 이용한 에너지 수확 (Energy Harvesting Using Disc Type Piezoelectric Ceramics)

  • 전호익;정성수;정현호;박민호;박태곤
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2009년도 춘계학술대회 논문집
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    • pp.53-54
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    • 2009
  • Nowadays, source of MEMS, USN, Hybrid parts pay attention to energy harvesting. On this paper, energy harvesting was studied using piezoelectric effect. And, piezoelectric generator was designed and fabricated. Generators were designed by FEM simulation program and generators were made by attaching cymbal type metal plates on upper and bottom sides of a disc type piezoelectric ceramic. Using fabricated generators, output voltages dependant on thickness of ceramic, displacement of vibration, frequency of vibration were measured.

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ER 유체용 압축전극이 ER 유체의 전기유변학적 특성에 미치는 영향 (The Effect of Compressing ER Electrode on Electrorheological Properties of Anhydrous ER Fluids)

  • 안병길
    • Tribology and Lubricants
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    • 제18권1호
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    • pp.16-23
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    • 2002
  • For increasing the yield stress of ER fluids, the compressing ER electrode was developed and the compressing electrorheological (ER) behavior of anhydrous ER fluids in silicone oil of phosphorous ester cellulose powder was investigated. Under constant electric field, not only the current density but also the yield stress of anhydrous ER fluids were studied as varying the compressing length of ER electrode distance. From the experimental results the compressing of ER electrode had a large influence to the ER properties of anhydrous ER fluids. The current density was proportional to the compressing length of ER electrode under constant electric field and volume fraction also tile compressing yield stress was proportional to the volume fraction of dispersed particles under constant electric field and compressing length. When the ER electrode was compressed with 150mm after charging the electric field, 4 kV, tile yield stress of phosphoric ester cellulose ER fluids increased to thirteen times comparing with the yield stress measured at normal electrode.