• Title/Summary/Keyword: Hybrid Platform

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Influence of Charge Transport of Pt-CdSe-Pt Nanodumbbells and Pt Nanoparticles/GaN on Catalytic Activity of CO Oxidation

  • Kim, Sun Mi;Lee, Seon Joo;Kim, Seunghyun;Kwon, Sangku;Yee, Kiju;Song, Hyunjoon;Somorjai, Gabor A.;Park, Jeong Young
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.164-164
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    • 2013
  • Among multicomponent nanostructures, hybrid nanocatalysts consisting of metal nanoparticle-semiconductor junctions offer an interesting platform to study the role of metal-oxide interfaces and hot electron flows in heterogeneous catalysis. In this study, we report that hot carriers generated upon photon absorption significantly impact the catalytic activity of CO oxidation. We found that Pt-CdSe-Pt nanodumbbells exhibited a higher turnover frequency by a factor of two during irradiation by light with energy higher than the bandgap of CdSe, while the turnover rate on bare Pt nanoparticles didn't depend on light irradiation. We also found that Pt nanoparticles deposited on a GaN substrate under light irradiation exhibit changes in catalytic activity of CO oxidation that depends on the type of doping of the GaN. We suppose that hot electrons are generated upon the absorption of photons by the semiconducting nanorods or substrates, whereafter the hot electrons are injected into the Pt nanoparticles, resulting in the change in catalytic activity. We discuss the possible mechanism for how hot carrier flows generated during light irradiation affect the catalytic activity of CO oxidation.

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Synthesis, morphology and electrochemical applications of iron oxide based nanocomposites

  • Letti, Camila J.;Costa, Karla A.G.;Gross, Marcos A.;Paterno, Leonardo G.;Pereira-da-Silva, Marcelo A.;Morais, Paulo C.;Soler, Maria A.G.
    • Advances in nano research
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    • v.5 no.3
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    • pp.215-230
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    • 2017
  • The development of hybrid systems comprising nanoparticles and polymers is an opening pathway for engineering nanocomposites exhibiting outstanding mechanical, optical, electrical, and magnetic properties. Among inorganic counterpart, iron oxide nanoparticles (IONP) exhibit high magnetization, controllable surface chemistry, spintronic properties, and biological compatibility. These characteristics enable them as a platform for biomedical applications and building blocks for bottom-up approaches, such as the layer-by-layer (LbL). In this regard, the present study is addressed to investigate IONP synthesised through co-precipitation route (average diameter around 7 nm), with either positive or negative surface charges, LbL assembled with sodium sulfonated polystyrene (PSS) or polyaniline (PANI). The surface and internal morphologies, and electrochemical properties of these nanocomposites were probed with atomic force microscopy, UV-vis and Raman spectroscopy, scanning electron microscopy, cross-sectional transmission electron microscopy, and electrochemical measurements. The nanocomposites display a globular morphology with IONP densely packed while surface dressed by polyelectrolytes. The investigation of the effect of thermal annealing (300 up to $600^{\circ}C$) on the oxidation process of IONP assembled with PSS was performed using Raman spectroscopy. Our findings showed that PSS protects IONP from oxidation/phase transformation to hematite up to $400^{\circ}C$. The electrochemical performance of nanocomposite comprising IONP and PANI were investigated in $0.5mol{\times}L^{-1}$ $Na_2SO_4$ electrolyte solution by cyclic voltammetry and chronopotentiometry. Our findings indicate this structure as promising candidate for potential application as electrodes for supercapacitors.

A Study on APC Subsidy Policies to Encourage OA Publishing (오픈액세스 확산을 위한 APC 지원 정책에 관한 연구)

  • Shin, Eun-Ja
    • Journal of the Korean Society for information Management
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    • v.31 no.3
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    • pp.249-270
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    • 2014
  • OA journal publishing has steadily increased its relative share of all scholarly journal articles by about 20%-30%. The 'Gold' OA, often preferred by readers, refers to journal articles which are more widely available through the journal's web site immediately. This study analyzed funder and university's policy for paying APCs in implementing a Gold OA. In recent years there have been a number of attempts in the UK and Europe to stimulate more systematic arrangements for paying APCs, leading funders have clearly established arrangements in place. Also OA fund made by major universities in North America provides publisher with APCs. On the other hand, it is still in early stages in paying with gold OA requirements from Korean funders and universities. The funders have a 'Green' OA policy, such as upload the article accepted version to their online platform. Although it varies by field, many Korean authors are publishing in international journals. Their articles' impacts would rise when they are published as gold OA. Therefore, funders and universities need to pay attention to gold OA publishing and set up subsidies for APCs which are required by OA or hybrid journal publishers.

Analysis of Tropospheric Carbon Monoxide and Ozone Production in East Asia

  • Lee S. H.;Choi G. H.;Lim H. S.;Lee J. H.;Seo D.C.;Jun J. N.;Jung J. H.;Kim I. S.;Kim J.
    • Proceedings of the KSRS Conference
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    • 2004.10a
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    • pp.182-183
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    • 2004
  • Atmospheric carbon monoxide (CO) and ozone $(O_3)$ play the important trace gases in tropospheric chemistry, through its concentration in the troposphere directly influences the concentrations of tropospheric hydroxyl (OH). Understanding the impact of CO and $O_3$ on the global tropospheric chemistry requires measurements of the global atmospheric CO and $O_3$ distributions. This study focuses on the identification of CO and O3 released in the East Asia between March 2000 and February 2004. During the period, the MOPITT instrument onboard the Earth Observing System (EOS)-Terra platform collected extensive measurement of CO. So we have used MOPITT data at 700hPa to analyze seasonal distribution of CO concentration. And the O3 measurements for this study were Total Ozone Mapping Spectrometer (TOMS) and Dobson spectrometer provided NASA/GSFC and Yonsei University, Korea. During springtime, the CO and O3 concentrations were increased over East Asia for April, May, and June. CO and O3 transport and chemistry in the springtime in East Asia are studied by use of the HYbrid Single Particle Lagrangian Integrated Trajectory (HYSPLIT) model.

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Anti-inflammatory and Anti-Oxidant Effects of Oxypaeoniflorin, Paeoniflorin and Paeonia lactiflora cv. 'Red Charm' Flower Petal Extracts in Macrophage Cells

  • Kim, Soo-Ah;Jang, Eun-Seo;Lee, A-Yeon;Lee, Soo-Jung;Kim, June-Hyun
    • Korean Journal of Plant Resources
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    • v.33 no.3
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    • pp.153-162
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    • 2020
  • The root extracts of Paeonia lactiflora cv. 'Red Charm' has been studied by many groups, however, little attention has been paid to its flower petal. Paeonia is the genus in the Paeoniaceae family. 'Red Charm' Paeonia is a soft-stemmed herbaceous peony hybrid of P. officinalis and P. lactiflora. We previously showed the flower petal extract of Red Charm might have anti-oxidant and anti-inflammatory activities, however, it was not clear which components might be involved in this activity. Bioinformatics analysis previously indicated these extracts have potential anti-oxidant materials. One of them is identified as paeoniflorin, which is major component in root extract of Red Charm. In this study, we compared paeoniflorin and oxypaeoniflorin using DPPH assays to measure its anti-oxidant activities. Oxypaeoniflorin showed higher levels of radical scavenging activity, similar to ascorbic acid control, whereas paeoniflorin did not. Furthermore, nitric oxide assay showed they have similar anti-inflammatory effects. Taken together, these results suggest oxypaeoniflorin may play a more important role in the anti-oxidant activity of the flower petal and root extracts of Red Charm, compared to paeoniflorin. Further studies may be able to provide a platform to develop potential dual effects therapeutics for oxidant-mediated and inflammation-mediated disease in the near future.

Sensor Module Architecture and Data Processing Framework for Energy Efficient Seamless Signal Processing in WSN (무선 센서네트워크에서의 저전력 연속 신호처리를 위한 센서모듈 아키텍처 및 데이터처리 프레임워크)

  • Hong, Sang-Gi;Kim, Nae-Soo;Kim, Whan-Woo
    • Journal of the Institute of Electronics Engineers of Korea CI
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    • v.48 no.6
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    • pp.9-16
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    • 2011
  • Due to the development and proliferation of ubiquitous technologies and services, various sensor network applications are being appeared on the stage. The needs for algorithms requiring sensor data fusion and complex signal processing with a high-performance processor such as a digital signal processor are also increased. However, it is difficult to use such processor for the low-power sensor network operating with a battery because of power consumption. This paper proposes a hybrid-type sensor module architecture supporting wakeup/sleep software framework for the wireless sensor node and shows the implemented sensor node platform and performances focused on the energy consumption and wakeup time.

Single Nucleotide Polymorphism Marker Discovery from Transcriptome Sequencing for Marker-assisted Backcrossing in Capsicum

  • Kang, Jin-Ho;Yang, Hee-Bum;Jeong, Hyeon-Seok;Choe, Phillip;Kwon, Jin-Kyung;Kang, Byoung-Cheorl
    • Horticultural Science & Technology
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    • v.32 no.4
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    • pp.535-543
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    • 2014
  • Backcross breeding is the method most commonly used to introgress new traits into elite lines. Conventional backcross breeding requires at least 4-5 generations to recover the genomic background of the recurrent parent. Marker-assisted backcrossing (MABC) represents a new breeding approach that can substantially reduce breeding time and cost. For successful MABC, highly polymorphic markers with known positions in each chromosome are essential. Single nucleotide polymorphism (SNP) markers have many advantages over other marker systems for MABC due to their high abundance and amenability to genotyping automation. To facilitate MABC in hot pepper (Capsicum annuum), we utilized expressed sequence tags (ESTs) to develop SNP markers in this study. For SNP identification, we used Bukang $F_1$-hybrid pepper ESTs to prepare a reference sequence through de novo assembly. We performed large-scale transcriptome sequencing of eight accessions using the Illumina Genome Analyzer (IGA) IIx platform by Solexa, which generated small sequence fragments of about 90-100 bp. By aligning each contig to the reference sequence, 58,151 SNPs were identified. After filtering for polymorphism, segregation ratio, and lack of proximity to other SNPS or exon/intron boundaries, a total of 1,910 putative SNPs were chosen and positioned to a pepper linkage map. We further selected 412 SNPs evenly distributed on each chromosome and primers were designed for high throughput SNP assays and tested using a genetic diversity panel of 27 Capsicum accessions. The SNP markers clearly distinguished each accession. These results suggest that the SNP marker set developed in this study will be valuable for MABC, genetic mapping, and comparative genome analysis.

Flexible 3D ZnO/Polymer Composite by Simple-Step Growth Processing for Highly Photocatalytic Performance

  • Lee, Hyun Uk;Park, So Young;Seo, Jung Hye;Son, Byoungchul;Lee, Jouhahn
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.412-412
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    • 2014
  • Zinc oxide (ZnO) is one of the most powerful materials for purifying organic pollutants using photocatalytic activity. In this study, we have introduced a novel method to design highly photoreactive flexible 3 dimensional (3D) ZnO nanocomposite [F-ZnO-m (m: reaction time, min)] by electrospinning and simple-step ZnO growth processing (one-step ZnO seed coating/growth processing). Significantly, the F-ZnO-m could be a new platform (or candidate) as a photocatalytic technology for both morphology control and large-area production. The highest photocatalytic degradation rate ([k]) was observed for F-ZnO-m at 2.552 h-1, which was 8.1 times higher than that of ZnO nanoparticles (NPs; [k] = 0.316 h-1). The enhanced photocatalytic activity of F-ZnO-m may be attributed to factors such as large surface area. The F-ZnO-m is highly recyclable and retained 98.6% of the initial decolorization rate after fifteen cycles. Interestingly, the F-ZnO-m samples show very strong antibacterial properties against both Gram-negative Escherichia coli (E. coli) and Gram-positive Staphylococcus aureus (S. aureus) after exposure to UV-light for 30 min. The antibacterial properties of F-ZnO-m samples are more effective than those of ZnO NPs. More than 96.6% of the E. coli is sterilized after ten cycles. These results indicate that F-ZnO-m samples might have utility in several promising applications such as highly efficient water/air treatment and inactivation of pathogenic microorganisms.

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An Integrated Method of Iterative and Incremental Requirement Analysis for Large-Scale Systems (시스템 요구사항 분석을 위한 순환적-점진적 복합 분석방법)

  • Park, Jisung;Lee, Jaeho
    • KIPS Transactions on Software and Data Engineering
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    • v.6 no.4
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    • pp.193-202
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    • 2017
  • Development of Intelligent Systems involves effective integration of large-scaled knowledge processing and understanding, human-machine interaction, and intelligent services. Especially, in our project for development of a self-growing knowledge-based system with inference methodologies utilizing the big data technology, we are building a platform called WiseKB as the central knowledge base for storing massive amount of knowledge and enabling question-answering by inferences. WiseKB thus requires an effective methodology to analyze diverse requirements convoluted with the integration of various components of knowledge representation, resource management, knowledge storing, complex hybrid inference, and knowledge learning, In this paper, we propose an integrated requirement analysis method that blends the traditional sequential method and the iterative-incremental method to achieve an efficient requirement analysis for large-scale systems.

A Survey on Admission Control Mechanisms for providing QoS in the IEEE 802.11 Wireless LANs (IEEE 802.11 무선랜에서 QoS 제공을 위한 허가 제어 연구)

  • Lee, Kye-Sang
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • v.9 no.2
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    • pp.535-538
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    • 2005
  • Wireless LANs based on the IEEE 802.11 standard are widely spread for use nowadays. Traffic which are conveyed over the WLANs change rapidly from normal data such a Email and Web pages, to multimedia data of high resolution video and voice. To meet QoS (Quality of Service) required by these multimedia traffic, the IEEE 802 committee recently has developed a new standard, IEEE 802.11e. IEEe 802.11.e contains two MAC mechanisms for providing QoS: EDCA(Enhanced Distributed Channel Access) and HCCA (HCF Controlled Channel Access). Using these standardized MAC mechanisms as a building platform, various admission control mechanisms can be combined to offer QoS gurantees for multimedia traffic. This paper surveys these research efforts.

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