• Title/Summary/Keyword: Hybrid Materials

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Optical and Electrical Properties of Two-Wavelength White Tandem Organic Light-Emitting Diodes Using Red and Blue Materials (적색과 청색 물질을 사용한 2파장 방식 백색 적층 OLED의 광학 및 전기적 특성)

  • Park, Chan-Suk;Jua, Sung-Hoo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.9
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    • pp.581-586
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    • 2015
  • We studied optical and electrical properties of two-wavelength white tandem organic light-emitting diodes using red and blue materials. White fluorescent OLEDs were fabricated using Alq3 : Rubrene (3 vol.% 5 nm) / SH-1 : BD-2 (3 vol.% 25 nm) as emitting layer (EML). White single fluorescent OLED showed maximum current efficiency of 9.7 cd/A, and tandem fluorescent OLED showed 18.2 cd/A. Commission Internationale de l'Eclairage (CIE) coordinates of single and tandem fluorescent OLEDs was (0.385, 0.435), (0.442, 0.473) at $1,000cd/m^2$, respectively. White hybrid OLEDs were fabricated using SH-1 : BD-2 (3 vol.% 10 nm) / CBP : $Ir(mphmq)_2(acac)$ (2 vol.% 20 nm) as EML. White single hybrid OLED showed maximum current efficiency of 7.8 cd/A, and tandem hybrid OLED showed 26.4 cd/A. Maximum current efficiency of tandem hybrid OLED was more twice as high as single OLED. CIE coordinates of single hybrid OLED was (0.315, 0.333), and tandem hybrid OLED was (0.448, 0.363) at $1,000cd/m^2$. CIE coordinates in white tandem OLEDs compared to those for single OLEDs observed red shift. This work reveals that stacked white OLED showed current efficiency improvement and red shifted emission than single OLED.

A Study on Selective Composite Patch for Light Weight and Quality Improvement of Battery Module (배터리 모듈의 경량화 및 품질 향상을 위한 선택적 복합재료 패치에 관한 연구)

  • Lee, Seung-Chan;Ha, Sung Kyu
    • Composites Research
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    • v.32 no.1
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    • pp.13-20
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    • 2019
  • In this study, in order to improve the quality issue and component characteristics of the battery module, which is one of the major parts of the electric vehicle. The structure is reinforced by using the composite material and the mechanism structure optimization of Hybrid concept which can overcome the disadvantages of single material was performed and the performance was compared. For this purpose, figure out the main design variables of composite materials according to Classical Laminated Plate Theory (CLPT) and the algorithm for predicting composite material properties have been studied. Based on the mechanical properties of the designed composite materials, finite element analysis (FEM) and the performance of the battery module was verified. Consequently, according to the verification result, Hybrid Battery Module reinforced with Selective Composite Patch can reduce the weight by 30% and reduce the product thickness by 32.5% compared with the existing Al battery module and proved the merit of Hybrid structure such as maintaining impact performance.

Regrinding Effect of Flat End-Mill Tool for Recycling of Tungsten Carbide (WC-Co) Material (초경소재 재활용을 위한 플랫 엔드밀공구의 재연삭 효과)

  • Kang, Myung-Chang;Kim, Min-Wook;Kwon, Dong-Hee;Park, In-Duck;Jeong, Young-Keun
    • Korean Journal of Materials Research
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    • v.18 no.12
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    • pp.635-639
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    • 2008
  • In this paper, experimental studies of the regrinding of tungsten carbide (WC-Co) tools for high-speed machining were conducted. Regrinding and a subsequent evaluation test were carried out for a flat endmill tool with diameters of 10 mm and 3 mm using a CNC five-axis tool grinder and a CNC three-axis machining center. Tool wear on the two types of endmill tools increased as the cutting length increased, and the tool wear was not influenced by the regrinding state. In case of the micro endmill with a tool diameter of 3 mm, the effective regrinding time was determined for a flank wear threshold of 0.3 mm considering the tool life according to cutting length. The tool lives of the 10 mm and 3 mm endmill tools were increased by 80% and 72%, respectively. This conclusion proves the Feasibility of the recycling of tungsten carbide materials in the high-speed machining of high-hardened materials for industrial applications.

Synthesis of SiNx:H films in PECVD using RF/UHF hybrid sources

  • Shin, K.S.;Sahu, B.B.;Lee, J.S.;Hori, M.;Han, Jeon G.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.136.1-136.1
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    • 2015
  • In the present study, UHF (320 MHz) in combination with RF (13.56 MHz) plasmas was used for the synthesis of hydrogenated silicon nitride (SiNx:H) films by PECVD process at low temperature. RF/UHF hybrid plasmas were maintained at a fixed pressure of 410 mTorr in the N2/SiH4 and N2/SiH4/NH3 atmospheres. To investigate the radical generation and plasma formation and their control for the growth of the film, plasma diagnostic tools like vacuum ultraviolet absorption spectroscopy (VUVAS), optical emission spectroscopy (OES), and RF compensated Langmuir probe (LP) were utilized. Utilization of RF/UHF hybrid plasmas enables very high plasma densities ~ 1011 cm-3 with low electron temperature. Measurements using VUVAS reveal the UHF source is quite effective in the dissociation of the N2 gas to generate more active atomic N. It results in the enhancement of the Si-N bond concentration in the film. Consequently, the deposition rate has been significantly improved up to 2nm/s for the high rate synthesis of highly transparent (up to 90 %) SiNx:H film. The films properties such as optical transmittance and chemical composition are investigated using different analysis tools.

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Physical characteristics of ceramic/glass-polymer based CAD/CAM materials: Effect of finishing and polishing techniques

  • Ekici, Mugem Asli;Egilmez, Ferhan;Cekic-Nagas, Isil;Ergun, Gulfem
    • The Journal of Advanced Prosthodontics
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    • v.11 no.2
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    • pp.128-137
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    • 2019
  • PURPOSE. The aim of this study was to compare the effect of different finishing and polishing techniques on water absorption, water solubility, and microhardness of ceramic or glass-polymer based computer-aided design and computer-aided manufacturing (CAD/CAM) materials following thermocycling. MATERIALS AND METHODS. 150 disc-shaped specimens were prepared from three different hybrid materials and divided into five subgroups according to the applied surface polishing techniques. All specimens were subjected up to #4000 grit SiC paper grinding. No additional polishing has been done to the control group (Group I). Other polishing procedures were as follows: Group II: two-stage diamond impregnated polishing discs; Group III: yellow colored rubber based silicone discs; Group IV: diamond polishing paste; and Group V: Aluminum oxide polishing discs. Subsequently, 5000-cycles of thermocycling were applied. The analyses were conducted after 24 hours, 7 days, and 30 days of water immersion. Water absorption and water solubility results were analyzed by two-way ANOVA and Tukey post-hoc tests. Besides, microhardness data were compared by Kruskal-Wallis and MannWhitney U tests (P<.05). RESULTS. Surface polishing procedures had significant effects on water absorption and solubility and surface microhardness of resin ceramics (P<.05). Group IV exhibited the lowest water absorption and the highest microhardness values (P<.05). Immersion periods had no effect on the microhardness of hybrid ceramic materials (P>.05). CONCLUSION. Surface finishing and polishing procedures might negatively affect physical properties of hybrid ceramic materials. Nevertheless, immersion periods do not affect the microhardness of the materials. Final polishing by using diamond polishing paste can be recommended for all CAD/CAM materials.

Development of an Oraganic-Inorganic Hybrid Coating Solution for Improvement in Flame Retardant Properties of Wallpapers (벽지의 방염특성을 개선하기 위한 유-무기 하이브리드 코팅 용액 개발)

  • Jeong, Gyu Jin;Kang, Tae Wook;Kim, Jin Ho;Kim, Bong Man;Seo, Eun Kyung;Bae, Byungseo;Kim, Sun Woog
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.35 no.2
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    • pp.178-183
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    • 2022
  • For enhancing the flame-retardant properties of wallpapers, we developed an organic-inorganic hybrid solution with ZrSiO4 as a functional ceramic powder, coated on non-woven fabric using dip coating, spray coating, and slot-die coating methods. Their flame retardant properties were characterized by a 45° combustion tester, which is manufactured according to the flame-retardant performance standard (KOFEIS 1001 and KS F 2819). In organic-inorganic hybrid solution, with increasing the concentration of acid-catalyst (acetic acid), the precipitation of ZrSiO4 powders increased, and the flame retardant properties decreased. The highest flame retardant result was obtained for the solution adding 5 wt% acetic acid. The optimization of the coating method and coating number resulted in the most excellent flame-retardant properties being obtained for the non-woven fabric coated for 5 or 7 times by dip coating method, and their flame-retardant properties corresponded to class 2 flame-retardant performance of wallpapers.

Characteristics of Al Films Prepared by Oblique Angle Deposition (빗각 증착으로 제조한 Al 박막의 특성)

  • Park, Hye-Sun;Yang, Ji-Hoon;Jung, Jae-Hun;Song, Min-A;Jeong, Jae-In
    • Journal of the Korean institute of surface engineering
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    • v.45 no.3
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    • pp.111-116
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    • 2012
  • Oblique angle deposition (OAD) is a physical vapor deposition method which utilizes non-normal angles between the substrate and the vaporizing source. It has been known that tilting the substrate changes the properties of the film deposited on it, which was thought to be a result of morphological change of the film. In this study, OAD has been applied to prepare single and multilayer Al films by magnetron sputtering. The magnetron sputtering source of 4 inch diameter was used to deposit the films. Al films have been deposited on Si wafers and cold-rolled steel sheets. The multilayer films were prepared by changing the tilting angle upside down at each layer interval, which means that when the first layer was deposited at an angle of $+45^{\circ}$, the second layer was deposited at an angle of $-45^{\circ}$, and vice versa. The microstructure, surface roughness and reflectance of the films were investigated using a scanning electron microscope, a surface profiler and a spectrophotometer, respectively. The corrosion resistance was measured and compared using the salt spray test. The single layer film prepared at an oblique angle of $60^{\circ}$ prepared at other angles. However, for the multilayer films, the film prepared at an oblique angle of $45^{\circ}$ showed the most compact and featureless structure. The multilayer films were found to exhibit higher corrosion resistance than the single layer films.

Properties of TiN Films Fabricated by Oblique Angle Deposition (빗각 증착으로 제조된 TiN 박막의 특성)

  • Jung, Jae-Hun;Yang, Ji-Hoon;Park, Hye-Sun;Song, Min-A;Jeong, Jae-In
    • Journal of the Korean institute of surface engineering
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    • v.45 no.3
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    • pp.106-110
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    • 2012
  • Oblique angle deposition (OAD) is a physical vapor deposition where incident vapor flux arrives at non-normal angles. It has been known that tilting the substrate changes the properties of the film, which is thought to be a result of morphological change of the film. In this study, OAD has been applied to prepare single and multilayer TiN films by cathodic arc deposition. TiN films have been deposited on cold-rolled steel sheets and stainless steel sheet. The deposition angle as well as substrate temperature and substrate bias was changed to investigate their effects on the properties of TiN films. TiN films were analyzed by color difference meter, scanning electron microscopy, nanoindenter and x-ray diffraction. The color of TiN films was not much changed according to the deposition conditions. The slanted and zigzag structures were observed from the single and multilayer films. The relation between substrate tilting angle (${\alpha}$) and the growth column angle (${\beta}$) followed the equation of $tan{\alpha}=2tan{\beta}$. The indentation hardness of TiN films deposited by OAD was low compared with the ones prepared at normal angle. However, it has been found that $H^3/E^2$ ratio of 3-layer TiN films prepared at OAD condition was a little higher than the ones prepared at normal angle, which can confirm the robustness of prepared films.

Effect of the Kind and Content of Raw Materials on Mechanical Performances of Hybrid Composite Boards Composed of Green Tea, Charcoals and Wood Fiber (녹차-숯-목재섬유 복합보드의 역학적 성능에 미치는 구성원료의 종류 및 배합비율의 영향)

  • Park, Han-Min;Heo, Hwang-Sun;Sung, Eun-Jong;Nam, Kyeong-Hwan;Lim, Jae-Seop
    • Journal of the Korean Wood Science and Technology
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    • v.41 no.1
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    • pp.64-76
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    • 2013
  • In this study, eco-friendly hybrid composite boards were manufactured from green tea, three kinds of charcoals and wood fiber for developing interior materials to reinforce the strength performances and the functionalities in addition to performances of the green tea-wood fiber hybrid boards. The effects for the kind and the component ratio of raw materials on mechanical properties were investigated. Bending strength performances of hybrid composite boards were highest in the hybrid composite boards composed of green tea, fine charcoal and wood fiber on average. However, the difference caused by the kind of charcoals was not large. These values were was markedly improved than those of green tea - wood fiber hybrid composite boards reported in previous researches. And it was found that the bending strength performance decreased with increasing component ratios of green tea and charcoals. The difference between urea resins used as the binder showed the higher value in hybrid composite boards using $E_1$ grade urea resin than in those using $E_0$ grade urea resin, but the difference between hybrid composite boards manufactured by both resins decreased markedly than the green tea - wood fiber hybrid composite boards reported in previous research. The internal bond strength of hybrid composite boards was in the order of hybrid composite boards with fine charcoal, activated charcoal and black charcoal, and it was found that the hybrid composite boards with fine charcoal had a similar values to control boards composed of only wood fiber.

Electrochemical Behavior Depending on Designed-Anode and Cathodes of Hybrid Supercapacitors (하이브리드 슈퍼커패시터의 음극 및 양극 설계에 따른 전기화학적 거동)

  • Shin, Seung-Il;Lee, Byung-Gwan;Ha, Min-Woo;An, Geon-Hyoung
    • Korean Journal of Materials Research
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    • v.29 no.12
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    • pp.774-780
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    • 2019
  • The performance of Li-ion hybrid supercapacitors (asymmetric-type) depends on many factors such as the capacity ratio, material properties, cell designs and operating conditions. Among these, in consideration of balanced electrochemical reactions, the capacity ratio of the negative (anode) to positive (cathode) electrode is one of the most important factors to design the Li-ion hybrid supercapacitors for high energy storing performance. We assemble Li-ion hybrid supercapacitors using activated carbon (AC) as anode material, lithium manganese oxide as cathode material, and organic electrolyte (1 mol L-1 LiPF6 in acetonitrile). At this point, the thickness of the anode electrode is controlled at 160, 200, and 240 ㎛. Also, thickness of cathode electrode is fixed at 60 ㎛. Then, the effect of negative and positive electrode ratio on the electrochemical performance of AC/LiMn2O4 Li-ion hybrid supercapacitors is investigated, especially in the terms of capacity and cyclability at high current density. In this study, we demonstrate the relationship of capacity ratio between anode and cathode electrode, and the excellent electrochemical performance of AC/LiMn2O4 Li-ion hybrid supercapacitors. The remarkable capability of these materials proves that manipulation of the capacity ratio is a promising technology for high-performance Li-ion hybrid supercapacitors.