• 제목/요약/키워드: Homogeneous Solution

검색결과 561건 처리시간 0.023초

Numerical Analysis of Damping Effect of Liquid Film on Material in High Speed Liquid Droplet Impingement

  • Sasaki, Hirotoshi;Ochiai, Naoya;Iga, Yuka
    • International Journal of Fluid Machinery and Systems
    • /
    • 제9권1호
    • /
    • pp.57-65
    • /
    • 2016
  • By high speed Liquid Droplet Impingement (LDI) on material, fluid systems are seriously damaged, therefore, it is important for the solution of the erosion problem of fluid systems to consider the effect of material in LDI. In this study, by using an in-house fluid/material two-way coupled method which considers reflection and transmission of pressure, stress and velocity on the fluid/material interface, high-speed LDI on wet/dry material surface is simulated. As a result, in the case of LDI on wet surface, maximum equivalent stress are less than those of dry surface due to damping effect of liquid film. Empirical formula of the damping effect function is formulated with the fluid factors of LDI, which are impingement velocity, droplet diameter and thickness of liquid film on material surface.

Fabrication of Nano-sized Titanate Powder via a Polymeric Steric Entrapment Route and Planetary Milling Process

  • Lee, Sang-Jin;Lee, Chung-Hyo
    • 한국세라믹학회지
    • /
    • 제39권4호
    • /
    • pp.336-340
    • /
    • 2002
  • Pure and nano-sized $TiO_2$ and $CaTiO_3$ powders were fabricated by a polymeric steric entrapment route and planetary milling process. An ethylene glycol was used as a polymeric carrier for the preparation of organic-inorganic precursors. Titanium isopropoxide and calcium nitrate were dissolved in liquid-type ethylene glycol without any precipitation. At the optimum amount of the polymer, the metal cations were dispersed in solution and a homogeneous polymeric network was formed. The dried precursor ceramic gels were turned to porous powders through calcination process. The porous powders were crystallized at low temperatures and the crystalline powders were planetary milled to nano size.

Anisotropic absorption of CdSe/ZnS quantum rods embedded in polymer film

  • Mukhina, Maria V.;Maslov, Vladimir G.;Baranov, Alexander V.;Artemyev, Mikhail V.;Fedorov, Anatoly V.
    • Advances in nano research
    • /
    • 제1권3호
    • /
    • pp.153-158
    • /
    • 2013
  • An approach to achieving of spatially homogeneous, ordered ensemble of semiconductor quantum rods in polymer film of polyvinyl butyral is reported. The CdSe/ZnS quantum rods are embedded to the polymer film. Obtained film is stretched up to four times to its initial length. A concentration of quantum rods in the samples is around $2{\times}10^{-5}$ M. The absorption spectra, obtained in the light with orthogonal polarization, confirm the occurrence of spatial ordering in a quantum rod ensemble. Anisotropy of the optical properties in the ordered quantum rod ensemble is examined. The presented method can be used as a low-cost solution for preparing the nanostructured materials with anisotropic properties and high concentration of nanocrystals.

Műller Formulation for Analysis of Scattering from 3-D Dielectric Objects with Triangular Patching Model

  • Lee, Chang-Hyun;Cho, Jin-Sang;Jung, Baek-Ho;Sarkar Tapan K.
    • Journal of Electrical Engineering and Technology
    • /
    • 제2권1호
    • /
    • pp.129-135
    • /
    • 2007
  • In this paper, we present a set of numerical schemes to solve the Muller integral equation for the analysis of electromagnetic scattering from arbitrarily shaped three-dimensional (3-D) dielectric bodies by applying the method of moments (MoM). The piecewise homogeneous dielectric structure is approximated by planar triangular patches. A set of the RWG (Rao, Wilton, Glisson) functions is used for expansion of the equivalent electric and magnetic current densities and a combination of the RWG function and its orthogonal component is used for testing. The objective of this paper is to illustrate that only some testing procedures for the Muller integral equation yield a valid solution even at a frequency corresponding to an internal resonance of the structure. Numerical results for a dielectric sphere are presented and compared with solutions obtained using other formulations.

기계적 합금화 방법에 의한 $Nb_3Sn$합금 제조 (The synthesis of $Nb_3Sn$ alloy powders by mechanical alloying)

  • 이성만
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 1996년도 추계학술대회 논문집 학회본부
    • /
    • pp.464-467
    • /
    • 1996
  • The microstructural evolution during mechanical alloying of Nb and Sn powders, of average composition Nb3Sn, has been investigated by X-ray diffraction(XRD) and scanning electron microscopy(SEM). Observations by SEM showed a progressive change of milling time. From the XRD studies, the structural development with milling time depends on the ball size for a given powder/ball ratio. Using a larger ball of 9.5mm diameter, the elemental powders initially alloy mechanically to form an A15 structure phase, and then amorphised with continued milling. However, in case of milling with a smaller ball of 3.968mm diameter, an amorphous phase is first formed. These results can be understood by considering the dependence of the milling energy on the ball size. The homogeneous stoichiometric $Nb_3Sn$ phase could be easily obtained by heat treatment of a supersaturated solid solution produced by MA. Heat treatment of an amorphous phase formed by MA resulted in the mixture of the $Nb_3Sn$ and $Nb_6Sn_5$ phases.

  • PDF

A Solution for Diffusion Equations and the Distribution of Alloying Elements in Sintered Alloys

  • Wang, Chonglin
    • 한국분말야금학회:학술대회논문집
    • /
    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
    • /
    • pp.72-73
    • /
    • 2006
  • The error function can be calculated based on the Simpson method through a subroutine program. An integration program by FORTRAN language was made for diffusion equations of extended source with infinite extent and limited extent. The results on some alloying elements such as C, Co, Cr, Mn, Mo, Ni and V's diffusion in iron, showed the diffusion distance for Ni and Mo can only be $1{\sim}3\;{\mu}m$ and more distance for Co at common sintering temperature of $1120^{\circ}C$. To refine the particle size of the added elements down to a scale of micrometers is an effective way to get homogeneous distribution.

  • PDF

$^7Li$ NMR studies of LiMn$_2$O$_4$ prepared by eutectic self-mixing method without any mixing

  • Lee, Youngil;Kyooseung Han;Hyunkoo Kang;Jaebum Choo
    • 한국자기공명학회:학술대회논문집
    • /
    • 한국자기공명학회 2002년도 International Symposium on Magnetic Resonance
    • /
    • pp.85-85
    • /
    • 2002
  • Lithiated transition metal oxides such as LiMn2O4, Lil-xMnO$_2$, LiNiO$_2$, LiCoO$_2$, and their solid solution phases are used as cathode materials for lithium rechargeable batteries. We prepared the cathode materials using a novel eutectic self-mixing method without any artificial mixing procedures. This method provides an extraordinarily simple way to make the cathode materials, and it is possible to prepare at very low temperature such as 25$0^{\circ}C$. Furthermore, the cathode materials produced have discharge capacities that are much better than cathode materials prepared by previously reported synthetic methods. The spontaneous and homogeneous mixing is verified by $^{7}$ Li magic-angle-spinning (MAS) NMR spectroscopy.

  • PDF

전자유압식 분사계에 의한 초고압 디젤분무의 입경분포에 관한 연구 (A Study on the Droplet Size Distribution of Ultra High Pressure Diesel Spray on Electronic Hydraulic Fuel Injection System)

  • 장세호;안수길
    • 동력기계공학회지
    • /
    • 제2권1호
    • /
    • pp.25-30
    • /
    • 1998
  • In order to investigate the droplet size distribution and Sauter Mean Diameter in a ultra high pressure diesel spray, fuel was injected with ultra high pressure into the environments of high pressure and room temperature by an Electronic Hydraulic Fuel Injection System. Droplet size was measured with the immersion liquid sampling technique. The immersion liquid was used a mixture of water-methycellulose solution and ethanol. The Sauter Mean Diameter decreased with increasing injection pressure, with a decrease environmental pressure (back pressure) and nozzle diameter. Increasing the injection pressure makes the fuel density distribution of the spray more homogeneous. An empirical correlation was developed among injection pressure, air density, nozzle diameter and the Sauter Mean Diameter of spray droplets.

  • PDF

Synthesis and Reactions of Benzimidazoline-2-thione Derivatives

  • 이태룡;김경태
    • Bulletin of the Korean Chemical Society
    • /
    • 제10권1호
    • /
    • pp.80-84
    • /
    • 1989
  • Two properties of sodium naphthalenide (2), i.e. a strong base and a good electron donor were utilized for one pot synthesis: 2-alkylthiobenzimidazoles were synthesized in excellent yields from the reactions of benzimidazoline-2-thione (1) with an equimolar amount of alkyl halides in the presence of 2. Continuous addition of a different alkyl halide without the isolation of 2-alkylthiobenzimidazoles afforded 1-alkyl-2-alkylthiobenzimidazoles having different alkyl groups at N and S atoms in excellent yields. Further addition of 2 to 1-alkyl-2-alkylthiobenzimidazoles gave excellent yields of 1-alkylbenzimidazoline-2-thiones. When 2 in THF was added to a suspension of 1-alkyl-2-alkylthiobenzimidazoles in THF, a bond cleavage between N and C of alkyl group as well as S and C of alkyl group occurred. This is in contrast to the observation in which only cleavage between S and C of alkyl group takes place in the homogeneous solution.

Low-Temperature Processable Charge Transporting Materials for the Flexible Perovskite Solar Cells

  • Jo, Jea Woong;Yoo, Yongseok;Jeong, Taehee;Ahn, SeJin;Ko, Min Jae
    • Electronic Materials Letters
    • /
    • 제14권6호
    • /
    • pp.657-668
    • /
    • 2018
  • Organic-inorganic hybrid lead halide perovskites have been extensively investigated for various optoelectronic applications. Particularly, owing to their ability to form highly crystalline and homogeneous films utilizing low-temperature solution processes (< $150^{\circ}C$), perovskites have become promising photoactive materials for realizing high-performance flexible solar cells. However, the current use of mesoporous $TiO_2$ scaff olds, which require high-temperature sintering processes (> $400^{\circ}C$), has limited the fabrication of perovskite solar cells on flexible substrates. Therefore, the development of a low-temperature processable charge-transporting layer has emerged as an urgent task for achieving flexible perovskite solar cells. This review summarizes the recent progress in low-temperature processable electron- and hole-transporting layer materials, which contribute to improved device performance in flexible perovskite solar cells.