• Title/Summary/Keyword: Homogeneous Mixture

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Homogeneous Mixing of Si3N4 with Sintering Additives by Coprecipitation Method (질화규소의 소결첨가제의 공침법에 의한 균일혼합)

  • 김지순
    • Journal of the Korean Ceramic Society
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    • v.30 no.10
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    • pp.829-837
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    • 1993
  • Chemically and geometrically homogeneous mixing of Si3N4 powders with sintering additives(YAG, 3Y2O3$.$5Al2O3) was attempted via coprecipitation method. X-ray dot maps for the additive elements(Al and Y) showed that the additives are evenly distributed in the powder mixture prepared by coprecipitation method(CP). TEM observation of the coprecipittion-treated Si3N4 powders revealed that they are covered with extremely fine crystallites of additive. The shift in isoelectric point(IEP) of Si3N4 powders from pH 6.7 to pH 7.9 after coprecipitation mixing gave another evidence for coating of Si3N4 powders with YAG additives. SIMS analysis for composition on the surface and in the matrix of mixed powders showed that the YAG additives are highly enriched on the surface of coprecipitation-treated Si3N4 powders. Especially when a small amount of additive was used, the effect of homogeneous additive distribution on densification was preceptible: After pressureless-sintering of powder compacts containing 5 mol% YAG at 1800$^{\circ}C$ for 0.5h, a sintered density of 96.5% theoretical was obtained from the specimens prepared bycoprecipitation in comparison with 93.8% from the mechanically-mixed one.

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Start of Combustion Detection Method for Gasoline Homogeneous Charge Compression Ignition Engine (가솔린 균일 예혼합 압축착화 엔진의 착화시점 검출)

  • Choe, Doo-Won;Lee, Min-Kwang;SunWoo, Myoung-Ho
    • Transactions of the Korean Society of Automotive Engineers
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    • v.16 no.4
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    • pp.151-158
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    • 2008
  • Gasoline Homogeneous Charge Compression Ignition (HCCI) combustion is a new combustion concept. Unlike the conventional internal combustion engine, the premixed fuel mixture with high residual gas rate is auto-ignited and burned without flame propagation. There are several operating factors which affect HCCI combustion such as start of combustion (SOC), residual gas fraction, engine rpm, etc. Among these factors SOC is a critical factor in the combustion because it affects exhaust gas emissions, engine power, fuel economy and combustion characteristics. Therefore SOC of gasoline HCCI should be controlled precisely, and SOC detection should be preceded SOC control. This paper presents a control oriented SOC detection method using 50 percent normalized difference pressure. Normalized difference pressure is defined as the normalized value of difference pressure and difference pressure is difference between the in-cylinder firing pressure and the motoring pressure. These methods were verified through the HCCI combustion experiments. The SOC detection method using difference pressure provides a fast and precise SOC detection.

Effect of Inlet Temperature and CO2 Concentration in the Fresh Charge on Combustion in a Homogeneous Charge Compression Ignition Engine Fuelled with Dimethyl Ether (Dimethyl Ether 예혼합 압축 착화 엔진에서 흡기중 CO2 농도와 흡기온도 변화가 연소에 미치는 영향)

  • Bae, Choong-Sik;Jang, Jin-Young;Yeom, Ki-Tae
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.31 no.6 s.261
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    • pp.514-521
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    • 2007
  • This study focused on the effects of the $CO_2$ gas concentration in fresh charge and induction air temperature on the combustion characteristics of homogeneous charge compression ignition with dimethyl ether (DME) fuel, which was injected at the intake port. Because of adding $CO_2$ in fresh charge, start of auto-ignition was retarded and bum duration became longer. Indicated combustion efficiency and exhaust gas emission were found to be worse due to the incomplete combustion. Partial burn was observed at the high concentration of $CO_2$ in fresh charge with low temperature of induction air. However, indicated thermal efficiency was improved due to increased expansion work by late ignition and prolonged bum duration. Start of auto-ignition timing was advanced with negligible change of burn duration, as induction air temperature increased. Burn duration was mainly affected by oxygen mole concentration in induction mixture. Bum duration was increased, as oxygen mole concentration was decreased.

Numerical Studies on Combustion Characteristics of a Hybrid Catalytic Combustor (하이브리드 촉매 연소기의 연소특성에 관한 수치적 연구)

  • Hwang, Cheol-Hong;Jeong, Yeong-Sik;Lee, Chang-Eon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.25 no.4
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    • pp.583-592
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    • 2001
  • The combustion characteristics of the hybrid catalytic(catalytic+thermal) combustor with a lean methane-air mixture on platinum catalyst were investigated numerically using a 2-D boundary layer model with detailed homogeneous and heterogeneous chemistries. for the more accurate calculations, the actual surface site density of monolith coated with platinum was decided by the comparison with experimental data. It was found that the homogeneous reactions in the monolith had little effect on the change of temperature profile, methane conversion rate and light off location. However, the radicals such as OH and CO were produced rapidly at exit by homogeneous reactions. The effect of operation conditions such as equivalence ratio, temperature, velocity, pressure and diameter of the monolith channel at the entrance were studied. In thermal combustor, the production of N$_2$O was more dominant than that of NO due to the relative importance of the reaction N$_2$+O(+M)→N$_2$O(+M). Finally the productions of CO and NOx by amount of methane addition were studied.

Analysis of Heat Quantity in CNG Direct Injection Bomb(2) : Inhomogeneous Charge (CNG 직접분사식 연소기에서의 열량해석(2) : 비균질급기)

  • 최승환;전충환;장영준
    • Transactions of the Korean Society of Automotive Engineers
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    • v.12 no.2
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    • pp.24-31
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    • 2004
  • A cylindrical constant volume combustion bomb is used to investigate the combustion characteristics and to analyzer the heat quantity of inhomogeneous charge methane-air mixture. To analyze the heat quantity, some definitions including the CHR ratio, the UHC ratio and the HL ratio are needed and are calculated. It is shown that the effect of stratification is not significant in case of the overall excess air ratio of 1.1, mainly due to the higher heat loss and lower thermal efficiency compared to those of homogeneous condition. In the case of the overall excess air ratio of 1.4, as the initial charge pressure decreases, the CHR ratio has been decreased while the HL ratio has been increased, Generally, as the initial charge pressure increases, the amount of injection mixture has been decreased and has resulted in lower mean velocity and turbulence intensity for injection mixture. Also, the injected mixture is too rich to result in mixing deficiency in combustion chamber. From these results, it could be possible to acquire the improvement of thermal efficiency and the reduction of heat loss simultaneously through the 2-stage injection in CNG direct injection engine.

A Study on the Mixture Formation Process and Combustion Characteristics According to Injection Timing in Premixed Charge Compression Ignition (예혼합 압축착화 디젤엔진의 분사시기 변화에 따른 혼합기 형성 과정 및 연소 특성에 관한 연구)

  • Cho, Byung-Ho;Han, Yong-Tak;Lee, Ki-Hyung;Lee, Chang-Sik
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.26 no.12
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    • pp.1692-1698
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    • 2002
  • A diesel engine has various merits such as high thermal-efficiency, superior fuel consumption and durability. Therefore the number of diesel engine in the world is increasing. As the seriousness of environmental pollution increases in the world, the method to reduce the noxious materials of $CO_2$, NOx and P.M. is very important subject to correspond to exhaust gas regulations. A new concept, so called premixed charge diesel combustion(PCCI), is focused among the various corresponding manners. In this study, we investigated the mixture formation within the cylinder with injection timing using GTT simulation code and also compared combustion characteristics of PCCI engine with that of commercial diesel engine. From this experiments, it could be found that homogeneous mixture formation was observed according to advance of injection timing and simultaneous reduction of NOx and Soot in injection timing of BTDC 60$^{\circ}$.

Pretilt Angle Properties of Mixture Nematic Liquid crystal for Mobile Information Device (휴대용 통신단말에 사용되는 혼합액정계에서의 프리틸트각 특성에 관한 연구)

  • Han, Jeongmin;Seo, Daeshik
    • Journal of Satellite, Information and Communications
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    • v.10 no.1
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    • pp.67-70
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    • 2015
  • We studied the state of the dual liquid crystal (LC) alignment which displays both homeotropic and homogeneous alignment on blended polyimide (PI) layer. The research was conducted using rubbing method at different imidizing temperatures and the blended PI was made using homeotropic PI having an alkyl side chain and homogeneous PI without the side chain. The uniform LC alignments were achieved, and have thermal stability. The results of contact angles were similar to that of pretilt angles.

Experimental and Theoretical Study on the Effect of Pressure on the Surface Reaction over Platinum Catalyst (백금촉매의 표면반응에 미치는 압력의 영향에 관한 실험 및 이론적 연구)

  • Kim, Hyung-Man
    • Journal of the Korean Society of Combustion
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    • v.5 no.1
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    • pp.1-6
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    • 2000
  • Surface reaction occurs at a certain surface temperature when a catalyst is heated up in a reactive mixture. If homogeneous ignition does not occur, a steady state is observed because the heat produced by the surface reaction is balanced with the heat loss caused by convection, conduction and radiation. The present paper treats the effects of pressure on the surface temperature at the steady state. Hydrogen and oxygen are used as reactants and nitrogen as an inert gas. A spherical platinum catalyst of 1.5 mm in diameter is sustained in the chamber with two wires of 0.1 mm in diameter. As results, there exists a maximum steady temperature at a certain relative hydrogen concentration which increases with total pressure. At the steady state, it can be approximated that the heat release is estimated by the mass transfer considering the effect of natural convection. The experimental results are explained qualitatively by the approximation.

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Numerical Analysis of Cavitation Flow Around Hydrofoils (3차원 수중익형 주위의 캐비테이션 유동 전산해석)

  • Kim, S.H.;Koo, T.K.;Park, W.G.;Kim, D.H.
    • The KSFM Journal of Fluid Machinery
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    • v.11 no.3
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    • pp.7-13
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    • 2008
  • The cavitating flow simulation is of practical importance for many engineering systems, such as pump, turbine, nozzle, Infector, etc. In the present work, a solver for two-phase flows has been developed and applied to simulate the cavitating flows past hydrofoils. The governing equation is the two-phase Navier-Stokes equation, comprised of the continuity equation of liquid and vapor phase. The momentum and energy equation is in the mixture phase. The solver employs an implicit, dual time, preconditioned algorithm using finite difference scheme in curvilinear coordinates. An experimental data and other numerical data were compared with the present results to validate the present solver. It is concluded that the present numerical code has successfully accounted for two-phase Navier-Stokes model of cavitation flow.

Characteristics of non-waxy rice starch/gum mixture gels (멥쌀 전분과 검물질 혼합물 겔의 특성)

  • Shin Malshick;Kwon Ji-Young;Song Ji-Young
    • Korean journal of food and cookery science
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    • v.21 no.6 s.90
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    • pp.942-949
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    • 2005
  • To improve the textural properties and stabilize the structure and gel matrix of non-waxy rice starch gels, non-waxy rice starch/gum mixture gels were prepared from various food gums, gum arabic, guar, algin, deacyl gellan, xanthan and gellan gums. The morphological and textural properties and freeze-thaw stability of their gels were compared. Rice starch/gum mixture gels with various gums formed a more homogeneous gel matrix with smaller particle size than rice starch gel without Em, but the trends differed depending on the gum types. The textural properties of rice starch/gum mixture gels were changed with the gum types. The shape of the rice starch/gum mixture gel matrix was desirable when mixed with gellan and algin. The textural properties of gels hardened in the rice starch/algin mixture gel and softened in the rice starch/algin mixture gel. The rice starch gels showed V-type crystallinity by x-ray diffractometer, but the peak at $2\theta$ = $20^{o}$ was decreased with increasing gum addition. The freeze-thaw stability increased with increasing gum addition. Gellan and algin were especially effective.