• Membrane Journal
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• v.26 no.2
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• pp.126-134
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• 2016

To produce renewable biomethane from biogas, the properties of physical absorbents such as water, methanol, 1-methyl-2-pyrrolidone (NMP), poly(ethylene glycol) dimethylether (PEGDME), and propylene carbonate (PC) were studied, and PC was applied to membrane contactor systems. Among physical absorbents, PC exhibited a high contact angle of $58.3^{\circ}$ on polypropylene surface, and a PC/water mixture (5 wt%) increased the contact angle to $90^{\circ}$. Furthermore, the PC/water mixture presented higher $CO_2$ absorption capacities (0.148-0.157 mmol/g) than that of water (0.121 mmol/g), demonstrating a good property as an absorbent for membrane contactors. Actual operations in membrane contactors using the PC/water mixture resulted in $CO_2$ removal of 98.0-97.8% with biomethane purities of 98.5-98.3%, presenting a strong potential for biogas treatment. However, the PC/water mixture yielded moderate improved in $CO_2$ removal and methane recovery, as compared with water in the membrane contactor operation. This is originated from insufficient desorption processes to reuse absorbent and low $CO_2$ flux of the PC/water absorbent. Thus, it is requiring optimizations of membrane contactor technology including development of absorbent and improvement of operation process.

• Journal of Korean Society on Water Environment
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• v.22 no.2
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• pp.358-363
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• 2006

KSMBR process is dynamic state advanced wastewater treatment applied with Trisectional Aeration (TSA) mode combined with membrane. TSA was remodeled conventional intermittent aeration which was operated nonaeration-aeration. TSA operates nonaeration ($N_1$) - aeration (A) - nonaeration ($N_2$) in Trisectional Aeration Reactor (TAR). Organics of influent could be nearly consumed to denitrification without influence by remained DO in TAR and it could be operated about sludge return ratio of 1Q (influent base). The purpose of this study was to apply KSMBR to the full-scale plant and to evaluate efficiency of nitrogen and phosphorus removal and TSA operation. The result of this study, average CODcr/T-N and CODcr/T-P ratio were 7.8 and 59.6, respectively. BOD, TCODcr, SS, T-N, T-P, E-coli removal efficiency were 98.4, 95.2, 73.0, 69.6, 99.95 %, respectively. KSMBR obtained high removal efficiencies of C, N and P when it applied full-scale plant.

• Membrane Journal
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• v.20 no.3
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• pp.249-258
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• 2010

In this study, we tried to observe the permeation on the single $O_2$, $CF_4$ and $SF_6$ gas using a PSF (polysulfone), PC (tetra-bromo polycarbonate) and PI (polyimide) hollow fiber membranes. We also observed the permselectivity on the $O_2/SF_6$ and $CF_4/SF_6$. According to the results of single gases permeation for different pressures, PSF membrane has the highest $O_2$ permeation of 37.5 GPU and PC membrane has the highest $SF_6$ permeation of 2.7 GPU and the highest $CF_4$ permeation of 2.5 GPU at 1.1 MPa. According to the results of single gases permeation for different temperatures, PSF membrane has the highest permeation of $O_2$ at $45^{\circ}C$ and PC membrane has the highest permeation of $SF_6$ and $CF_4$ at $25^{\circ}C$. From the result of $O_2/SF_6$ and $CF_4/SF_6$ permselectivity for different pressures and temperature, the highest permeation and the lowest permselectivity were observed in the PSF and PC membrane. On the contrary, the lowest permeation and the highest permselectivity was observed in the PI membrane.

• Membrane Journal
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• v.27 no.4
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• pp.367-373
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• 2017

Pressurized membrane module systems, including hollow fiber type of Microfiltration (MF) and Ultrafiltration (UF) membranes are being increasingly used in drinking water treatment due to their high removal efficiency of pathogen. However, when fibers are damaged in pressurized membrane system, the pathogen will be able to penetrate the membrane. Therefore, it is essential to guarantee the regulatory requirements for water quality by an effective on-line or off-line condition integrity monitoring methods. Recently, pressure decay test (PDT) which is one of membrane integrity tests has been reflected to drinking water treatment plants using pressurized membrane module. In this paper, three different method were used to perform PDT and three different sensitivity values were analyzed through experiments. Three types of direct integrity test methods were applied to pressure feed side, filtrate side and bidirectional pressure decay test. The results of these experiments show that the sensitivity was increasing when the volume of pressurized gas was decreasing. The sensitivity is inversely proportional to the gas volume. Furthermore, it is desirable to increase pressure difference between feed side and permeate side in order to achieve higher sensitivity in the PDT by membrane damage.

• Journal of Chest Surgery
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• v.38 no.10 s.255
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• pp.661-668
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• 2005

Background: We have hypothesized that, if a low resistant gravity-flow membrane oxygenator is used, then the twin blood sacs of TPLS can be located at downstream of the membrane oxyenator, which may double the pulse rate at a given pump rate and increase the pump output. The purpose of this study was to determine the optimal configuration for the ECLS circuits by using the concept of pulse energy and pump output. Material and Method: Animals were randomly assigned to 2 groups in a total cardiopulmonary bypass model. In the serial group, a conventional membrane oxygenator was located between the twin blood sacs. In the parallel group, the twin blood sacs were placed downstream of the gravity-flow membrane oxygenator. Energy equivalent pressure (EEP) and pump output were collected at pump-setting rates of 30, 40, and 50 BPM. Result: At the given pump-setting rate, the pulse rate was doubled in the parallel group. Percent changes of mean arterial pressure to EEP were $13.0\pm1.7,\; 12.0\pm1.9\;and\;7.6\pm0.9\%$ in the parallel group, and $22.5\pm2.4,\; 23.2\pm1.9,\;and\;21.8\pm1.4\%$ in the serial group at 30, 40, and 50 BPM of pump-setting rates. Pump output was higher in the parallel circuit at 40 and 50 BPM of pump-setting rates $(3.1\pm0.2,\;3.7\pm0.2L/min\;vs.\;2.2\pm0.1\;and\;2.5\pm0.1L/min,\;respectively,\;p=0.01)$. Conclusion: Either parallel or serial circuit configuration of the ECLS generates effective pulsatility. As for the pump out, the parallel circuit configuration provides higher flow than the serial circuit configuration.

• Membrane Journal
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• v.24 no.5
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• pp.409-415
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• 2014

This study is aimed to separate propylene and propane using membrane process instead of NCC(Naphtha Cracking Center) $C_3$ splitter. Membrane process is a low energy consumption and eco-friendly process while $C_3$ splitter requires high energy consumption in petrochemical processes. In this study, high performance facilitated transport membrane (FTM) is used for propylene/propane separation. FTM module was prepared on top of porous polyetherimide hollow fiber using PVP/$AgBF_4$/TCNQ. We developed simulation program predicting the membrane separation properties under operation conditions. Separation properties of FTM module for propylene and propane were obtained from the simulation program based on the pure gas permeation data. Based on these results, it is predicted that an one-stage membrane process provides 99.5% of propylene at permeate side from a binary gas mixture of 95/5 vol% $C_3H_6$ / vol% $C_3H_8$ supplied as a feed gas.

• Applied Chemistry for Engineering
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• v.18 no.1
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• pp.10-16
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• 2007

In this study, we examined the preparation and hydrolysis property of immobilized urease membrane to decompose harmful urea in the body and remove ammonia which was produced by its decomposition. Urease immobilized membrane was prepared by introducing anion-exchange group DEA into porous hollow-fiber membrane by radiation graft polymerization method, and immobilization of urease. When urease was immobilized at membrane introduced with anion-exchange group, the more increasing grafting rate, the more increasing immobilization amount. The result originates from the fact that a greater amount of protein was immobilized by forming a multilayer on the longer grafted chain. Meanwhile, the addition of the cross-linker was possible not only to suppress separation phenomenon produced during a washing process of immobilized urease membrane but also to enable the recycling of membrane. Urease Immobilized membrane with no separation phenomenon was prepared by cross-linking reaction for 5 h, and the hydrolysis rate of prepared urease immobilized membrane was over 98% and 50%, respectively, in 1 mol and 4 mol urea solutions.

• 한국생물공학회:학술대회논문집
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• 2000.11a
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• pp.256-259
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• 2000

Ethanol fermentration of glucose by a strain of Zymomonas mobilis KCTC 1535 was studied in membrane recycle bioreactor, which was coupled with closs flow hollow fiber membrane. The maximum values of product yields and productivity are 0.4685g total ethanol/ g glucose, 14.05g total ethanol/ L/h, respectively The pervaporation performance of the PDMS menbrane has been investigated for the separation of binary mixtures of EtOH/water at $50^{\circ}C{\sim}70^{\circ}C$. The optimum conditions of feed concentration, temperature, feed solution flow rates is determined to be 8%, $70^{\circ}C$, 492ml/min, respectively. An ethanol permselectivity of 7.5 and flux of $0.04kg/m^2/hr$ were obtained with these membrane

• Transactions of the Korean hydrogen and new energy society
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• v.18 no.3
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• pp.223-229
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• 2007

여과막 생물반응기를 이용하여 $60^{\circ}C$에서 혐기 세균 복합체가 포도당으로부터 수소를 생산할 수 있는 최적조건을 연구하였다. 여과막 생물반응기는 연속교반 탱크반응기와 외부에 장착된 PVDF (polyvinylidene fluoride) 중공사막 여과장치로 구성되었다. 접종슬러지는 하수처리장 소화 슬러지조에서 얻었고, 포자형성 수소생산 미생물을 얻기 위해 $90^{\circ}C$에서 20분 간 열처리하였다. 16S rRNA PCR-DGGE(polymer chain reaction-denaturing gradient gel electrophoresis) 분석을 통해 열처리 전후의 미생물상 변화를 조사하였다. 열처리 후 DGGE 밴드의 수는 감소하였고, 주요 밴드는 Clostridium perfringens와 유사한 염기서열을 나타내었다. 운전 기간 동안 바이오가스 내 수소함량은 60%(v/v)를 유지하였고, 메탄은 검출되지 않았다. 연속교반 탱크반응기를 여과막 없이 수력학적 체류 4시간에서 운전하였을 때 공급된 포도당의 95.0%가 제거되었고, 이때 균체농도 및 수소생산속도는 각각 1.35 g cell/L 및 7.4 L $H_2$/L/day이었다. 동일한 체류시간에서 PVDF중공사막 여과장치를 장착하여 연속교반 탱크반응기를 운전하였을 때, 균체농도는 1.62 g cel/L로 증가하였고 높은 포도당 제거율(99.5%) 및 수소생산속도(8.8 L $H_2$/L/day)가 관찰되었다. 40 nm 및 100 nm의 공극크기를 가진 여과막은 균체농도 및 수소생산 측면에서 유사한 성능을 나타내었다. 여과막 생물반응기는 여과막의 반복적인 세척을 통해 30일 이상 안정적으로 운전될 수 있었다.

• Journal of Korean Society on Water Environment
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• v.26 no.1
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• pp.81-88
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• 2010

This study was conducted to find the capability of comparison of overall oxygen transfer coefficient in the membrane coupled high performance reactor (MPHCR) in treating high organic loading wastewater. Effluent quality had been analyzed while the influent organic loading rate was changed from 2 to $7kg\;COD/m^3{\cdot}day$. The oxygen transfer coefficients had been investigated using two-phase nozzle for operating variables which were internal circulation flowrate (5~8 L/min), air flow rate (0.0125~0.2 L/min), liquid temperature ($10{\sim}20^{\circ}C$), and pure-oxygen flow rate (0.0125~0.2 L/min). The overall oxygen transfer coefficient was increased with flowrate of internal circulation and air and high temperature. Especially, internal circulation flow rate showed distinct effect on overall oxygen transfer coefficient due to an increase of gas holdup and air-liquid contract area by two-phase nozzle. In the high range of organic loading rate from 4 to $7kg\;COD/m^3{\cdot}day$, the removable efficiency of COD was 91%. Conventional activated sludge process usually treat organic loading from 0.32 to $0.64kg\;COD/m^3{\cdot}day$ however, the MPHCR can treat 10 to 20 times higher if it would be compared to the conventional activated sludge process. Foaming problem often happened and caused biomass wash out of the reactor, therefore, the foaming should be controlled for the enhanced operation.