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Influence of Electrolyte on the Shape and Characteristics of TiO2 during Anodic Oxidation of Titanium (Titanium 양극산화시 TiO2 의 형상 및 특성에 미치는 전해질의 영향)

  • Yeji Choi;Chanyoung Jeong
    • Corrosion Science and Technology
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    • v.22 no.3
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    • pp.193-200
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    • 2023
  • Titanium alloy (grade-4) is commonly used in industrial and medical applications. To improve its corrosion resistance and biocompatibility for medical use, it is necessary to form a titanium oxide film. In this study, the morphology of the oxide film formed by anodizing Ti-grade 4 using different electrolytes was analyzed. Wetting properties before and after surface modification with SAM coating were also observed. Electrolytes used were categorized as A, B, and C. Electrolyte A consisted of 0.3 M oxalic acid and ethylene glycol. Electrolyte B consisted of 0.1 M NH4F and 0.1 M H2O in ethylene glycol. Electrolyte C consisted of 0.07 M NH4F and 1 M H2O in ethylene glycol. Samples B and C exhibited a porous structure, while sample A formed a thickest oxide film with a droplet-like structure. AFM analysis and contact angle measurements showed that sample A with the highest roughness exhibited the best hydrophilicity. After surface modification with SAM coating, it displayed superior hydrophobicity. Despite having the thickest oxide film, sample A showed the lowest insulation resistance due to its irregular structure. On the other hand, sample C with a thick and regular porous oxide film demonstrated the highest insulation resistance.

Process Optimization of Nypa fruticans Wurmb Extract using Mixed Solvent and its Functional Component Analysis

  • Kim, Jin;Kim, Han Sung;Son, Jang Wan;Moon, Seong Yong;Lee, Sook-Young
    • Biomedical Science Letters
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    • v.28 no.1
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    • pp.34-41
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    • 2022
  • In this study, conditions for extraction of functional component from Nypa fruticans wurmb was optimized. The yield by extraction with 30% ethanol (LE30, 42.12%) was higher than those hot water extraction (LDW 33.32%), 50% ethanol (LE50, 40.12%) and 70% ethanol (LE70, 34.5%). The extract was purified and analyzed by GC MS. The prevailing compounds found in extract were Cyclodecasiloxane-, pentadecanoic acid, -eicosane, undecanal and tridecanoic acid. The presence of saturated and unsaturated fatty acids in ethanolic extract vindicate the use of this plant to treat many diseases in traditional medicine. The total phenolic contents in the LDW, LE30, LE50, LE70 extract were 128±1.65 mg/g, 205±2.3 mg/g, 210±4.23 mg/g and 180±5.6 mg/g, respectively. The DPPH was highest in LE70 extract (1,000 ㎍/mL, 81.14%), ABTS was highest in LE50 extract (1,000 ㎍/mL, 84.14%). The protective effects against oxidative stress in raw 264.7 cell imparted by the LE50 extract was better than those imparted by the other extracts. The findings of the present study suggest that 50% ethanol is best solvent for extraction of Nypa fruticans Wurmb, considering yield, polyphenol content, and antioxidant activities with extraction cost.

Factors influencing efficiency of somatic embryogenesis of Gentiana kurroo (Royle) cell suspension

  • Fiuk, Agnieszka;Rybczynski, Jan J.
    • Plant Biotechnology Reports
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    • v.2 no.1
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    • pp.33-39
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    • 2008
  • In this paper, we would like to show unexpected morphogenic potential of cell suspensions derived from seedling explants of Gentiana kurroo (Royle). Suspension cultures were established with the use of embryogenic callus derived from seedling explants (root, hypocotyl and cotyledons). Proembryogenic mass proliferated in liquid MS medium supplemented with $0.5mg\;l^{-1}$ 2,4-D and $1.0mg\;l^{-1}$ Kin. The highest growth coefficient was achieved for root derived cell suspensions. The microscopic analysis showed differences in aggregate structure depending on their size. To assess the embryogenic capability of the particular culture, 100 mg of cell aggregates was implanted on MS agar medium supplemented with Kin ($0.0-2.0mg\;l^{-1}$), $GA_3$ ($0.0-2.0mg\;l^{-1}$) and AS ($80.0mg\;l^{-1}$). The highest number of somatic embryos was obtained for cotyledon-derived cell suspension on $GA_3$-free medium, but the best morphological quality of embryos was observed in the presence of $0.5-1.0mg\;l^{-1}$ Kin, $0.5mg\;l^{-1}$ $GA_3$ and $80.0mg\;l^{-1}$ AS. The morphogenic competence of cultures also depended on the size of the aggregate fraction and was lower when size of aggregates decreased. Flow cytometry analysis reveled luck of uniformity of regenerants derived from hypocotyl suspension and 100% of uniformity for cotyledon suspension.

Analysis of Mission, Vision and Core values in Korean Tertiary General Hospitals Through Text Mining (텍스트 마이닝을 통한 상급종합병원의 미션, 비전, 핵심가치 분석 연구)

  • Ji-Hoon Lee
    • Korea Journal of Hospital Management
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    • v.28 no.2
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    • pp.32-43
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    • 2023
  • Purposes: This research is conducted to identify main features and trends of mission, vision and core values in Korean tertiary general hospitals by using text-mining. Methodology: For the study, 45 mission, 112 vision and 190 core values are collected from 45 tertiary general hospitals' homepages in 2022 and use word frequency analysis and Leyword co-occurrence analysis. Findings: In the tertiary general hospitals' mission, there are high frequency words such as 'health', 'humanity', 'medical treatment', 'education', 'research', 'happiness', 'love', 'best', 'spirit', and mission mainly includes the content of contributing humanity's health and happiness with these words. In case of vision, high frequency words are 'hospital', 'medical treatment', 'research', 'lead', 'trust', 'centered', 'patient', 'best', 'future'. By using these words in vision, it represents the definition and characteristics of vision such as ideal organizations in the future, goals and targets. As a result of the Leyword co-occurrence analysis, vision includes the content of 'high-tech medical treatment', 'special care for patients', 'leading education and research', 'the highest trust with customer', 'creative talents training'. -astly, the high frequency word-pairs in core values are 'social distribution', 'innovation pursuit', 'cooperation and harmony', and it defines standards of behavior for organizations. Practical Implication: To correct the problems of vision, mission and core values from findings, firstly, it needs for Korean tertiary general hospitals to use the words that can explain organization's identity and differentiate others in their mission. Secondly, considering strengthening the role of hospitals in their community and the importance of members in organizations, it is necessary to establish vision with considering community and members to activate vision effectively. Thirdly, because there are no specific guidelines of establishing mission, vision and core values for healthcare organizations, this research concepts and results could be utilized when other organizations establish mission, vision and core values.

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Thermomechanical Properties and Shape Memory Effect of PET-PEG Copolymers Cross-linked with Pentaerythritol

  • Shim, Yong-Shik;Chun, Byoung-Chul;Chung, Yong-Chan
    • Fibers and Polymers
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    • v.7 no.4
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    • pp.328-332
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    • 2006
  • Poly(ethylene terephthalate) (PET) and poly(ethylene glycol) (PEG) copolymers cross-linked with pentaerythritol, a four-way cross-linker, are prepared to compare their mechanical and shape memory properties with the one cross-linked by glycerol. Composition of PEG and pentaerythritol is varied to search for the one with the best mechanical and shape memory properties. The highest shape recovery rate is observed for the copolymer composed of 30 mol% PEG-200 and 2.5 mol% pentaerythritol. Four-way cross-linking by pentaerythritol significantly improves shape recovery rate and retention of high shape recovery rate after repeated use compared to the one cross-linked by glycerol, a three-way cross-linker, and difference and advantage of additional cross-linking point are discussed.

Effects of Fillers on Mixing and Mechanical Properties of Polymer Concrete (충진재가 폴리머 콘크리트의 배합과 역학적 성질에 미치는 영향)

  • 연규석;김광우;김기성;김관호
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.35 no.2
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    • pp.81-91
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    • 1993
  • This study was performed to evalute effects of fillers on the mixing characteristics and mechanical properties of polymer concrete. Two types of unsaturated polyester polymer and two types of epoxy resin were used as binder material, and the portland cement, a fly ash and heavy calcium carbonate were used as filler. Following conclusions were drawn from the research results. 1. Working life of polymer concrete was not affected by filler types, but affected significantly by polymer types and quantities of hardener and catalysts. 2. Without concerning polymer types, use of heavy calcuim carbonate as filler was the best in improving workability.3. The highest strength was achieved by heavy calcium carbonate in using unsaturated polyester resin and by fly ash in using epoxy resin type.4. Elastic modulus was in the range of 2.05X 10-5~2.6X 10-5gf/cm$^2$, which was approximatly 60% of that of cement concrete. Heavy calcium carbonate with unsaturated polyester resin and fly ash with epoxy resin showed relatively higher elastic modulus.

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A Study on the Relationship between the Traffic Signal System and the Air Pollutants emitted by the Motor Vehicles at Intersection

  • Hong, Min-Sun;Woo, Wan-Gi;Park, Jong-In
    • Journal of Korean Society for Atmospheric Environment
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    • v.9 no.E
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    • pp.364-372
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    • 1993
  • The purpose of this study is to analyze traffic patterns by use of TRANSYT-7F Model, and to choose the optimum traffic-light cycle length and cycle splite to improve traffic flow and air quality at Samsung Intersection in Seoul. Emission rates of air pollutants are calculated for three time segments 0700-0900, 0900-1800 and 1800-2000. The traffic volume correlated reasonably well with air pollutants emitted ; however, the phasing and timing of traffic signals was found to equally be important. The results of performance with optimal setting indicate that the best cycle length were 80sec(0700-0900), 95sec(0900-1800) and 90sec(1800-2000), res-pectively. As expected the highest emissions of air pollutants were observed during the evening rush hours (1800-2000). A properly designed signalized intersection can help reduce traffic delay, driver discomfort, fuel consumption, and air pollution by efficiently the capacity of existing intersection.

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Growth and Cultural Characteristics of Cordyceps cardinalis Collected from Korea

  • Sung, Gi-Ho;Shrestha, Bhushan;Han, Sang-Kuk;Kim, Soo-Young;Sung, Jae-Mo
    • Mycobiology
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    • v.38 no.4
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    • pp.274-281
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    • 2010
  • Cordyceps cardinalis was reported in Japan and the USA in 2004, and its fruiting bodies have recently been cultured in Korea. Herbarium specimens preserved at the Cordyceps Research Institute, Mushtech, Korea were revised and identified as C. cardinalis, based on morphological characters and conidial structures. Most of the C. cardinalis specimens were collected from Mt. Halla in Jeju-do. The effects of various nutritional sources and environmental conditions such as temperature and pH on mycelial growth of C. cardinalis were studied. Oatmeal agar, Martin's peptone dextrose agar, and Schizophyllum (mushroom) genetics complete medium plus yeast extract resulted in the best mycelial growth. Among carbon sources, cereals, and nitrogen sources, maltose, oatmeal, and peptone resulted in the best mycelial growth respectively. Mineral salts helped to increase growth rate but only resulted in thin mycelial density, similar to water agar. A temperature of $25^{\circ}C$ and a pH of 7 resulted in the highest mycelial growth. Based on these results, a Cordyceps cardinalis composite medium (CCM) was formulated with 1% maltose, 2% oatmeal, 1% peptone, and 2% agar. Use of the CCM resulted in slightly better mycelial growth than that of other commonly used agar media. Only organic nitrogen sources imparted a reddish pigmentation to the agar media, but this character diminished after several subcultures. A 7 day culture duration resulted in the best mycelial growth.

Studies on the Quality Improvement of Printing Paper by Process Controlling of DIP and TMP (탈묵펄프 및 열기계펄프의 공정 조절을 통한 인쇄용지의 품질향상 연구)

  • Hwang, Sung-Jun;Lim, Jong-Keun;Kim, Hyoung-Jin;Chung, Sung-Hyun
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.5
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    • pp.5-14
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    • 2015
  • Recently, the use of wood resources has been limited due to global environmental change, like global warming and desertification. It is very critical in Korea's paper industries because lots of virgin pulp are dependant on direct import from abroad for printing grade of paper. In this work, the alternatively best available technique for reducing the import amounts of BKP (bleached Kraft pulp) was considered by mixing DIP (deinked pulp) and TMP (thermomechanical pulp) for the manufacture of high quality paper. Generally known, the sheet prepared from fibrous raw materials of DIP and TMP has lower strength and optical properties than that prepared from BKP. This study was aimed to improve the sheet quality by using DIP and TMP. 4 kinds of polyelectrolytes were approached to find out the best effects on physical strength and optical brightness improvements, and high retention behaviors with GCC (ground calcium carbonate). In conclusion, amphoteric PAM with 1,000,000 molecular weight (g/mol) and 0.5 charge density (meq/g) was best for the improvement of strength properties with the mixture of DIP and TMP. GCC retention rate was also the highest with cationic-PAM of above 2,000,000 molecular weight (g/mol) and about 2.0-3.0 charge density (meq/g) of strengthening agent.

The effect of using nanoparticles in bioactive glass on its antimicrobial properties

  • Maram Farouk Obeid;Kareim Moustafa El-Batouty;Mohammed Aslam
    • Restorative Dentistry and Endodontics
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    • v.46 no.4
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    • pp.58.1-58.8
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    • 2021
  • Objectives: This study addresses the effect of using nanoparticles (np) on the antimicrobial properties of bioactive glass (BAG) when used in intracanal medicaments against Enterococcus faecalis (E. faecalis) biofilms. Materials and Methods: E. faecalis biofilms, grown inside 90 root canals for 21 days, were randomly divided into 4 groups according to the antimicrobial regimen followed (n = 20; BAG-np, BAG, calcium hydroxide [CaOH], and saline). After 1 week, residual live bacteria were quantified in terms of colony-forming units (CFU), while dead bacteria were assessed with a confocal laser scanning microscope. Results: Although there was a statistically significant decrease in the mean CFU value among all groups, the nano-group performed the best. The highest percentage of dead bacteria was detected in the BAG-np group, with a significant difference from the BAG group. Conclusions: The reduction of particle size and use of a nano-form of BAG improved the antimicrobial properties of the intracanal treatment of E. faecalis biofilms