• Title/Summary/Keyword: High-energy density

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High Energy Density Germanium Anodes for Next Generation Lithium Ion Batteries (다음세대 리튬이온 배터리용 고에너지 밀도 게르마늄 음극)

  • Ocon, Joey D.;Lee, Jae Kwang;Lee, Jaeyoung
    • Applied Chemistry for Engineering
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    • v.25 no.1
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    • pp.1-13
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    • 2014
  • Lithium ion batteries (LIBs) are the state-of-the-art technology among electrochemical energy storage and conversion cells, and are still considered the most attractive class of battery in the future due to their high specific energy density, high efficiency, and long cycle life. Rapid development of power-hungry commercial electronics and large-scale energy storage applications (e.g. off-peak electrical energy storage), however, requires novel anode materials that have higher energy densities to replace conventional graphite electrodes. Germanium (Ge) and silicon (Si) are thought to be ideal prospect candidates for next generation LIB anodes due to their extremely high theoretical energy capacities. For instance, Ge offers relatively lower volume change during cycling, better Li insertion/extraction kinetics, and higher electronic conductivity than Si. In this focused review, we briefly describe the basic concepts of LIBs and then look at the characteristics of ideal anode materials that can provide greatly improved electrochemical performance, including high capacity, better cycling behavior, and rate capability. We then discuss how, in the future, Ge anode materials (Ge and Ge oxides, Ge-carbon composites, and other Ge-based composites) could increase the capacity of today's Li batteries. In recent years, considerable efforts have been made to fulfill the requirements of excellent anode materials, especially using these materials at the nanoscale. This article shall serve as a handy reference, as well as starting point, for future research related to high capacity LIB anodes, especially based on semiconductor Ge and Si.

Influence of the density of states and overlap integral on impact ionization rate for silicon (상태밀도와 overlap integral이 실리콘내 전자의 임팩트이온화율에 미치는 영향)

  • 정학기;유창관;이종인
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 1999.05a
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    • pp.394-397
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    • 1999
  • Impact ionization, which is a kind of a carrier-carrier interaction process occurring in a semiconductor under the influence of a high electric field, is necessary to analyse carrier transport properties. Since the parabolic or nonparabolic E-k relation is different from real band structure in high energy range, exact model of impart ionization have been presented using full band I-k relation and Fermi's golden rule. We have investigated relation of density of states, energy band structure and overlap integral. We make use of empirical pseudopotential method in order to calculate energy band structure of silicon, tetrahedron method in order to calculate density of states. We know density of states very depends on energy band structure and overlap integral depends on the primary electron energy.

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Noise Analysis for Large Silencers of Ships and Off-shore Plants using Energy Flow Analysis

  • Kim, Tae-Gyoung;Song, Jee-Hun;Hong, Suk-Yoon
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.26 no.3
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    • pp.297-307
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    • 2020
  • In the study, energy flow analysis is performed to predict the performance of silencers. To date, deterministic approaches such as finite element method have been widely used for silencer analysis. However, they have limitations in analyzing large structures and mid-high frequency ranges due to unreasonable computational costs and errors. However, silencers used for ships and off-shore plants are much larger than those used in other engineering fields. Hence, energy governing equation, which is significantly efficient for systems with high modal density, is solved for silencers in ships and off-shore plants. The silencer is divided into two different acoustic media, air and absorption materials. The discontinuity of energy density at interfaces is solved via hypersingular integrals for the 3-D modified Helmholtz equation to analyze multi-domain problems with the energy flow boundary element method. The method is verified by comparing the measurements and analysis results for ship silencers over mid-high frequency ranges. The comparisons confirm good agreement between the measurement and analysis results. We confirm that the applied analysis method is useful for large silencers in mid-high frequency ranges. With the proven procedures, energy flow analysis can be performed for various types of silencer used in ships and off-shore plants in the first stage of the design.

Development of PFFEM, the new vibroacoustic analysis system in medium-to-high frequency ranges (중고주파에서의 새로운 진동해석시스템, PFFEM 개발연구)

  • Seo, Seong-Hoon;Hong, Suk-Yoon;Park, Do-Hyun;Kil, Hyun-Gwon
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2000.06a
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    • pp.325-333
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    • 2000
  • To predict vibrational energy density and intensity of partitioned complex system structures in medium-to-high frequency ranges, Power Flow Finite Element Method(PFFEM) programs for the plate elements are developed. The flexural, longitudinal and shear waves in plates are formulated and the joint element equations for multi-couped plates are fully developed. Also the wave transmission approach has been introduced to cover the energy transmission and reflection at the joint plate elements. Using the developed PFFEM program the energy density and intensity of the submarine and automobile shape structures are predicted with a harmonic point force at a single frequency.

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Acoustic Viscosity Characteristics of Oils with High Molecular Weight VI Improver Additives (고분자량 점도지수향상제가 첨가된 오일의 음향점도 특성)

  • Kong, H.;Ossia, C.V.;Han, H.G.
    • Tribology and Lubricants
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    • v.25 no.4
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    • pp.236-242
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    • 2009
  • Oil viscosity is one of the important parameters for machinery condition monitoring. Basically, it is expressed as kinematic viscosity measured by capillary flow and dynamic or absolute viscosity measured by rotary shear viscometry. Recently, acoustic wave techniques appear in the market, measuring viscosity as the product of dynamic viscosity and density. For Newtonian fluids, knowledge of density allows conversion from one viscosity parameter to the other at a specific shear rate and temperature. In this work, oil samples with different chain lengths of viscosity index (VI) improvers and concentrations were examined by different viscometric techniques. Results showed that acoustic viscosity measurements give misleading results for oil samples with high molecular weight VI improvers and at low temperatures ${\leq}40^{\circ}C$.

Vibration Power Flow Analysis of Submarine-shaped Structures using Developed Software

  • Seo, Seong-Hoon;Hong, Suk-Yoon
    • Journal of Ship and Ocean Technology
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    • v.6 no.2
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    • pp.1-11
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    • 2002
  • For the analysis of vibrational energy density and intensity of partitioned complex system structures in medium-to-high frequency ranges, A software based on the Power Flow Analysis(PFA) has been developed for the plate elements. The flexural, longitudinal and shear waves in plates are formulated and the joint element equations for multi-coupled plates are fully developed. Also, the wave transmission approach has been introduced to cover the energy transmission and reflection at the joint plate elements. To confirm the validity of the developed PFA software, the submarine-shaped complex structures are used for the analysis of vibration intensity and energy density.

Vibration analysis of 2300 TEU container ship using power flow analysis program in medium-to-high frequency ranges (파워흐름해석 프로그램을 이용한 2300 TEU 컨테이너선의 중고주파 대역 진동해석)

  • 서성훈;박영호;홍석윤;길현권
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2001.11b
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    • pp.1061-1066
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    • 2001
  • To predict vibrational energy density and intensity of beam-plate coupled complex structures in medium-to-high frequency ranges, Power Flow Finite Element Method(PFFEM) programs for plate, beam and some coupled structural elements are developed. The flexural, longitudinal and shear waves in plates are formulated and the joint element equations for multi-couped plates are fully developed. Also the wave transmission approach has been introduced to cover the energy transmission and reflection at the joint elements. Using the developed PFFEM program, vibration analysis for 2300TEU container ship model is performed and here the model data for this program are obtained by converting fonner FE model for structural analysis. This program predicts successfully the vibrational energy density and intensity upto 8,000 Hz for the ship model with over 50,000 DOF.

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Dislocation Analysis of CVD Single Crystal Diamond Using Synchrotron White Beam X-Ray Topography (가속기 백색광 X-Ray Topography를 이용한 CVD 단결정 다이아몬드 내부 전위 분석)

  • Yu, Yeong-Jae;Jeong, Seong-Min;Bae, Si-Young
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.32 no.3
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    • pp.192-195
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    • 2019
  • Single-crystal diamond obtained by chemical vapor deposition (CVD) exhibits great potential for use in next-generation power devices. Low defect density is required for the use of such power devices in high-power operations; however, plastic deformation and lattice strain increase the dislocation density during diamond growth by CVD. Therefore, characterization of the dislocations in CVD diamond is essential to ensure the growth of high-quality diamond. In this work, we analyze the characteristics of the dislocations in CVD diamond through synchrotron white beam X-ray topography. In estimate, many threading edge dislocations and five mixed dislocations were identified over the whole surface.

A Study on Photoresist Stripping Using High Density Oxygen Plasma (고밀도 산소 플라즈마를 이용한 감광제 제거공정에 관한 연구)

  • Jung, Hyoung-Sup;Lee, Jong-Geun;Park, Se-Geun;Yang, Jae-Kyun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.2
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    • pp.95-100
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    • 1998
  • A helical inductively coupled plasma asher, which produces low energy and high density plasma, has been built and investigated for photoresist stripping process. Oxygen ion density in the order of $10^{11}/cm^3$ is measured by Langmuir probe, and higher oxygen radical density is observed by Optical Emission Spectrometer. As RF source power is increased, the plasma density and thus photoresist stripping rate are increased. Independent RF bias power to the wafer stage provides a dc bias to the wafer and an ability to add the ion assisted reaction. At 1 KW of the source power, the coupling mechanism of the RF power to the plasma is changed from the inductive mode to the capacitive one at about 1 Torr. This change causes the plasma density and ashing rate decreases abruptly. The critical pressure of the mode change becomes larger with larger RF power.

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CS-PDM Series Resonant High Frequency Inverter for Copy Machine

  • Sugimura, Hisayuki;Eid, Ahmad Mohamad;Hiraki, Eiji;Kim, Sung-Jung;Lee, Hyun-Woo;Nakaoka, Mutsuo
    • 제어로봇시스템학회:학술대회논문집
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    • 2005.06a
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    • pp.1066-1071
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    • 2005
  • This paper presents the two lossless auxiliary inductors-assisted voltage source type half bridge (single ended push pull: SEPP) series resonant high frequency inverter for induction heated fixing roller in copy and printing machines. The simple high-frequency inverter treated here can completely achieve stable zero current soft switching (ZCS) commutation for wide its output power regulation ranges and load variations under its constant high frequency pulse density modulation (PDM) scheme. Its transient and steady state operating principle is originally described and discussed for a constant high-frequency PDM control strategy under a stable ZCS operation commutation, together with its output effective power regulation characteristics-based on the high frequency PDM strategy. The experimental operating performances of this voltage source SEPP ZCS-PDM series resonant high frequency inverter using IGBTs are illustrated as compared with computer simulation results and experimental ones. Its power losses analysis and actual efficiency are evaluated and discussed on the basis of simulation and experimental results. The feasible effectiveness of this high frequency inverter appliance implemented here is proved from the practical point of view.

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