• Title/Summary/Keyword: High-concentration ammonia wastewater

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Effect of high free ammonia concentration on microalgal growth and substrate uptake (폐수 내 고농도 free ammonia(FA)가 미세조류의 성장 및 기질제거에 미치는 영향 평가)

  • Kim, Eun-Ji;Cho, Jae Hyung;Noh, Kyung Ho;Nam, guisook;Hwang, Sun-Jin
    • Journal of Korean Society of Water and Wastewater
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    • v.30 no.6
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    • pp.715-723
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    • 2016
  • This study investigated the effect of high concentration of free ammonia on microalgal growth and substrate removal by applying real wastewater nitrogen ratio. To test of this, the conditions of free ammonia 1, 3, 6, 9, 12, 15 mg-N/L are compared. After 3 days of incubation, algal growth of Chlorella vulgaris and carbon removal rate are respectively lower in the reactors of FA 12, 15 mg-N/L compared to the others. This indicates that the high concentration of free ammonia, in this case, above 12 mg-N/L, has negative effect on algal growth and metabolic activity. Also, high concentration of free ammonia causes the proton imbalance, ammonium accumulation in algae and has toxicity for these reasons. So, we have to consider free ammonia in applying the microalgae to wastewater treatment system by the way of diluting wastewater or controlling pH and temperature.

Estimation of influening factors for efficient anaerobic digestion of high strength ammonia-nitrogen wastewater (고농도 암모니아성 질소 폐수의 효과적인 혐기성 처리를 위한 영향 인자 평가)

  • Park, Seyong;Park, Junghoon;Na, Hoysung;Kim, Moonil
    • Journal of Korean Society of Water and Wastewater
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    • v.26 no.5
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    • pp.649-658
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    • 2012
  • In this study, the influencing factors for efficient anaerobic digestion of high strength ammonia-nitrogen wastewater removal were investigated by testing biochemical methane potential test. In the influencing factors, the trace metals which could increase activity of anaerobic microorganisms, microbial concentration and types were evaluated. In the results, trace metals supplementation showed gas production amount higher than those without addition of trace metals. Among the tested trace metals, B, Ni, and Se were preferable to gas production. In the result of gas production according to the microbial concentration, the amount of gas production was proportional to the microbial concentration. In addition, the shortest lag time and the fastest gas production rate were achieved when the highest microbial concentration was tested. granule-type microorganism produced more gas than suspended-type microorganism. In conclusion, the efficient anaerobic digestion for high strength ammonia-nitrogen wastewater removal could be achieved by applying necessary trace metals injection and high concentration granule type microorganism.

A Study on the Chemical Treatment Techniques of High Concentration Ammonia Nitrogen in Food Wastewater

  • Tae-Hwan JEONG;Su-Hye KIM;Woo-Taeg KWON
    • Journal of Wellbeing Management and Applied Psychology
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    • v.6 no.3
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    • pp.33-36
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    • 2023
  • Purpose: Since the food wastewater contains a high concentration of nitrogen, it is very important to find a way to efficiently remove it. Research design, data and methodology: A total of four experiments were conducted under different conditions to remove ammonia nitrogen present in the food wastewater. The experiment was designed by adding sodium hypochlorite to the raw food wastewater and varying conditions such as pH control, aeration/precipitation, and stirring. Results: The ammonia nitrogen removal rate in Experiment 1 was about 12% (sodium hypochlorite added), ammonia nitrogen increased about 4.7% in Experiment 2 (sodium hypochlorite added after aeration/precipitation in a bioreaction tank, stirring), and decreased about 52.5% (sodium hypochlorite added after controlling and stirring). Conclusions: When the concentration of sodium hypochlorite was high, ammonia nitrogen was best removed, and the pH was adjusted to 12, and sodium hypochlorite was added after stirring, and the removal was the second best. If the method of this study is further studied and developed, it can be basic data for ammonia nitrogen removal in the future.

Demonstration Study on Ammonia Stripping in Electronic Industry Wastewater with High Concentrations of Ammonia Nitrogen (고농도 암모니아를 함유한 전자 폐수의 암모니아 탈기 실증 연구)

  • Jae Hyun Son;Younghee Kim
    • Clean Technology
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    • v.29 no.4
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    • pp.297-304
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    • 2023
  • The rapid advancement of the high-tech electronics industry has led to a significant increase in high-concentration ammonia wastewater. Various methods have been attempted to reliably treat wastewater containing high concentrations of ammonia, but no successful technology has yet been developed and applied. In this study, the removal efficiency and characteristics of ammonia nitrogen was evaluated according to changes in temperature, air loading rate, and liquid loading rate using a closed circulation countercurrent packed tower type demonstration facility for wastewater containing high concentrations of ammonia generated in the high-tech electronics industry. The temperature was varied while maintaining operating conditions of a wastewater flowrate of 20.8 m3 h-1 and an air flow rate of 18,000 Nm3 h-1. The results showed that at temperatures of 45,50,55, and 60℃, the removal efficiencies of ammonia nitrogen (NH3-N) were 87.5%, 93.4%, 96.8%, and 98.7%, respectively. It was observed that temperature had the most significant impact on the removal efficiency of NH3-N under these conditions. As the air loading rate increases, the removal rate also increases, but the increase in removal efficiency is not significant because droplets from the absorption tower flow into the stripping tower. Even if the liquid loading rate was changed by ±30%, the removal rate did not change significantly. This does not mean that the removal rate was unaffected, but was believed to be due to the relatively high air load rate. Through demonstration research, it was confirmed that ammonia stripping is a reliable technology that can stably treat high-concentration ammonia wastewater generated in the high-tech electronics industry.

Factors Influencing Nitrite Build-up Nitrification of High Strength Ammonia Wastewater (고농도 암모니아성 폐수의 질산화과정에서 아질산염 축적의 영향인자)

  • 한동준;강성환;임재명
    • Journal of environmental and Sanitary engineering
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    • v.13 no.2
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    • pp.128-138
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    • 1998
  • This study was focused to find how each factors effect on the biological nitrification in wastewater treatment under high ammonia nitrogen concentration. Batch reactors in aerobic conditions were used to test the treatment efficiency of mixed liquor, nightsoil and piggery wastewater. The results are summeried as follows; Initial ammonia nitrogen concentration and pH were the direct influencing factors of nitrite build-up. More than 250 mg NH$_{4}$$^{+}$ - N/L in initial concentration built up nitrite and then the inhibition rate to Nitrobacter was above 70 percentage. And maximum nitritation rate was showed at pH 8.3 and nitrification could be completely achieved by pH control. Temperature and dissolved oxygen were the indirect influencing factors of nitrite build-up. These were a great effect on the activity of nitrifying microbes and ammonia nitrogen removal. Maximum nitritation rate was showed at 30 $\circ $C. The effect of DO concentration was negligible at more than 3 mg/L.

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A Survey of Water Quality and Improvement Measure of Imjin-River (임진강수계의 수질조사 및 개선방안)

  • 김형진;백영석;이준석
    • Journal of environmental and Sanitary engineering
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    • v.10 no.1
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    • pp.66-75
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    • 1995
  • This survey is executed about the water quality and improvement measure of Imjin- river. The results are summarized as follows; 1 ) Ammonia nitrogen concentration in tap water was two times higher than drinking water standard. 2) The concentration of BOD in textile wastewater was 235ppm which is higher than wastewater distribution standard and leather wastewater showed high nitrogen concentration. 3) Water quality of the Imjin- river upstream was not in problem but that of Shin- stream showed somewhat high concentration in BOD, COD, and ammonia nitrogen. Especially the detected Cynide compound on the lower of Shin- stream implied seriously polluted condition. 4) The heavy metal in soil of the river bed was not detected but iron, zinc was detected to high concentration. 5) It Is urgently suggested to build more municipal sewage and sanitary treatment plants, and run dredging and river bed rearrangement project. 6) The Construction of the wastewater treatment complexes of relevant industries shall be propelled as soon as possible.

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Effect of Operating Condition of Stripping Process on Ammonia Removal for Pre-treatment of Swine Wastewater (축산폐수 전처리를 위한 암모니아 탈기공정의 운전조건이 암모니아 제거에 미치는 영향)

  • Whang, Gye-Dae;Cho, Young-Moo
    • Journal of Korean Society on Water Environment
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    • v.20 no.1
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    • pp.86-92
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    • 2004
  • Lab-scale experiments have been carried out to investigate ammonia stripping with a modified spray tower for removing ammonia nitrogen from swine wastewater. The operating conditions such as initial pH, temperature, air flow, hole size of distributor determining the diameter of water drops, and influent solids concentration were closely examined focusing on removal efficiency of ammonia. As a result of the experiment, in order to achieve high rate of ammonia removal by the air stripping system, the air flow rate must be supplied at high rate with sufficiently high initial pH, temperature. The optimum operating condition to meet the residual ammonia concentration of 300 mg/L was the initial pH of 11.0 at $35^{\circ}C$ with the air flow rate of 20 L/min. It also showed that the smaller hole size is, the higher removal rate of ammonia is expected. However, when used a small sized distributor (2 mm), the flooding problem at the upper column occurred due to clogging of the hole. With regard to the influent solids concentration, it was showed that the lower concentration of solids, the higher removal rate of ammonia. The removal of particulate materials in influent led to improve the removal efficiency of ammonia, rather than to control the operating condition including initial pH, temperature, and air flow. The empirical correlation between KLa and operating parameters would be driven as, $K_{La}=(0.0003T-0.0047){\cdot}G^{0.3926}{\cdot}L^{-0.5169}{\cdot}C^{-0. 1849}$. The calculated $K_{La}$ from proposed formula can be used effectively to estimate the optimum reaction time and to calculate the volume of modified spray tower system.

Ammonia Nitrogen Removal and Recovery from Swine Wastewater by Microwave Radiation

  • La, Joohee;Kim, Taeyoung;Jang, Jae Kyung;Chang, In Seop
    • Environmental Engineering Research
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    • v.19 no.4
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    • pp.381-385
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    • 2014
  • Microwave (MW) radiation was developed to remove and recover ammonia nitrogen in the real swine wastewater. The effect of operating parameters of MW radiation such as initial pH, power, radiation time, aeration, and stirring for removal ammonia nitrogen in swine wastewater was determined. The pH, radiation time, and power were significantly influenced on the removal of ammonia nitrogen, and aeration and stirring showed relatively minor effect on the removal of ammonia nitrogen. Optimum condition was achieved to retrieve the nitrogen efficiently at pH 11, 700 W for 5 min in MW radiation process. Through this process, 83.1% of ammonia nitrogen concentration was reduced in swine wastewater and also 82.6% of ammonia nitrogen was recovered as ammonium sulfate at the optimized condition. The high ammonia removal and recovery efficiency of the MW radiation method indicated that MW radiation was an effective technique to remove and recover ammonia nitrogen in the swine wastewater.

Effects of phosphorus concentration and nitrogen sources on photoautotrophic microalgae Scenedesmus dimorphus applied wastewater treatment (인 농도 및 질소원이 광합성 미세조류인 Scenedesmus dimorphus를 이용한 하수고도처리에 미치는 영향)

  • Kim, Tae-Hyeong;Cho, Yong-Beom;Park, Jeong-Eun;Hwang, Sun-Jin
    • Journal of Korean Society of Water and Wastewater
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    • v.27 no.3
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    • pp.325-329
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    • 2013
  • A result of estimating the effects of initial phosphorus concentration and nitrogen sources on removal of nitrogen and phosphorus in wastewater treatment using Scenedesmus dimorphus shows that there was no difference in microalgae growth amount and nitrogen removal amount by phosphorus concentration(5 ~ 60 mg/L). On the other hand, as initial phosphorus concentration increased, phosphorus removal amount was increased by luxury uptake of microalgae. Scenedesmus dimorphus preferred to ammonia when ammonia(40 mg/L) and nitrate(40 mg/L) are simultaneously presented and nitrogen removal rate of ammonia was high at approximately 20 mg/L/day.

Application of Ferrate (VI) for Selective Removal of Cyanide from Plated Wastewater (도금폐수 중 시안(CN)의 선택적 제거를 위한 Ferrate (VI) 적용)

  • Yang, Seung-Hyun;Kim, Younghee
    • Clean Technology
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    • v.27 no.2
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    • pp.168-173
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    • 2021
  • The treatment of plated wastewater is subject to various and complex processes depending on the pH, heavy metal, and cyanide content of the wastewater. Alkali chlorine treatment using NaOCl is commonly used for cyanide treatment. However, if ammonia and cyanide are present simultaneously, NaOCl is consumed excessively to treat ammonia. To solve this problem, this study investigated 1) the consumption of NaOCl according to ammonia concentration in the alkaline chlorine method and 2) whether ferrate (VI) could selectively treat the cyanide. Experiments using simulated wastewater showed that the higher the ammonia concentration, the lower the cyanide removal rate, and the linear increase in NaOCl consumption according to the ammonia concentration. Removal of cyanide using ferrate (VI) confirmed the removal of cyanide regardless of ammonia concentration. Moreover, the removal rate of ammonia was low, so it was confirmed that the ferrate (VI) selectively eliminated the cyanide. The cyanide removal efficiency of ferrate (VI) was higher with lower pH and showed more than 99% regardless of the ferrate (VI) injection amount. The actual application to plated wastewater showed a high removal ratio of over 99% when the input mole ratio of ferrate (VI) and cyanide was 1:1, consistent with the molarity of the stoichiometry reaction method, which selectively removes cyanide from actual wastewater containing ammonia and other pollutants like the result of simulated wastewater.