• 한국재료학회지
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• 제30권4호
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• pp.176-183
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• 2020

The high-temperature stability of YSZ specimens fabricated by die pressure and cold isostatic press (CIP) is investigated in CaCl₂-CaF₂-CaO molten salt at 1,150 ℃. The experimental results are as follows: green density 46.7 % and 50.9 %; sintering density 93.3 % and 99.3 % for die press and CIP, respectively. YSZ foremd by CIP exhibits higher stability than YSZ formed by die press due to denseness dependency after high-temperature stability test. YSZ shows peaks mainly attributed to CaZrO₃, with a small t-ZrO₂ peak, unlike the high-intensity tetragonal-ZrO₂ (t-ZrO₂) peak observed for the asreceived specimen. The t-ZrO₂ phase of YSZ is likely stabilized by Y₂O₃, and the leaching of Y₂O₃ results in phase transformation from t-ZrO₂ to m-ZrO₂. CaZrO₃ likely forms from the reaction between CaO and m-ZrO₂. As the exposure time increases, more CaZrO₃ is observed in the internal region of YSZ, which could be attributed to the inward diffusion of molten salt and outward diffusion of the stabilizer (Y₂O₃) through the pores. This results in greater susceptibility to phase transformation and CaZrO₃ formation. To use SOM anodes for the electroreduction of various metals, YSZ stability must be improved by adjusting the high-density in the forming process.

• 한국진공학회지
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• 제8권2호
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• pp.93-101
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• 1999

The purposed of this paper is to investigate the electrical and thermal stability of Polyvinylidene fluoride(PVDF) organic thin films prepared by the vapor deposition method. The differential scanning calorimetry curve of the PVDF organic thin films prepared by increasing substrate temperature showed that the melting curve increased from $128^{\circ}C$ to $142^{\circ}C$. This result implied that the PVDF organic thin film prepared by increasing substrate temperature increased intermolecular force in the crystalline region. The anomalous properties in dielectric constant and dielectric loss at low frequency and high temperature were described for PVDF organic thin film containing impurity carriers. It was confirmed that in view of electric conductive characteristics the ohm's law is satisfied in the range of lower electric field and ln J was proportional to the electric field ln E as like the conventional property of ionic conduction in the range of higher electric field. It was confirmed that major carrier of conductivity was ions. The electrical stability was improved according to an increase of the substrate temperature. On the basis of this experimental result, it could be observed that the optimum temperature of substrate for the electrical and thermal stability was at $105^{\circ}C$.

• 대기
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• 제23권1호
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• pp.13-21
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• 2013

In this study, the effects of atmospheric stability and surface temperature on the microscale local airflow are investigated in a hydrological suburban area using a computational fluid dynamics (CFD) model. The model domain includes the river and industrial complex for analyzing the effect of water system and topography on local airflow. The surface boundary condition is constructed using a geographic information system (GIS) data in order to more accurately build topography and buildings. In the control experiment, it is shown that the topography and buildings mainly determine the microscale airflow (wind speed and wind direction). The sensitivity experiments of atmospheric stability (neutral, stable, and unstable conditions) represent the slight changes in wind speed with the increase in vertical temperature gradient. The differential heating of ground and water surfaces influences on the local meteorological factors such as air temperature, heat flow, and airflow. These results consequentially suggest that the meteorological impact assessment is accompanied by the changes of background land and atmospheric conditions. It is also demonstrated that the numerical experiments with very high spatial resolution can be useful for understanding microscale local meteorology.

• 한국임상약학회지
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• 제8권1호
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• pp.54-58
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• 1998

The stability of ceftriaxone sodium 100 mg/ml in the water for injection was tested at two temperature conditions (refrigerator and room temperature) and two storage containers (vitro and syringe). The stability of each sample was determined by high-performance liquid chromatography while storing for 5 days at room temperature and 27 days at refrigerator. The concentration of ceftriaxone sodium was 100 mg/ml which the hospital usually use as a filling preparation for I.V. push or Y-site injection. There was no significant difference between the storage in vials and syringes. There was no significant difference in the change of concentration until storing the reconstituted ceftriaxone sodium injection for 2 days at room temperature and 14 days at refrigerator. In conclusion, the ceftriaxone sodium 100 mg/ml in the water for injection can be stored in vial or syringe for 2 days at room temperature and 14 days at refrigerator after preparation.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2001년도 하계학술대회 논문집
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• pp.1022-1025
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• 2001

This paper presents the characteristics of TaN thin-film as high-temperature strain gauges, which were deposited on Si substrate by DC reactive magnetron sputtering in an argon-nitrogen atmosphere(Ar-(4∼20%)N$_2$). The electrical and mechanical characteristics of these films investigated with the thickness range 1650∼1870${\AA}$ and room temperature resistivities in the range 178.3 ${\mu}$$\Omega$cm to 3175.7 ${\mu}$$\Omega$cm. The TaN thin-film strain gauge deposited in Ar-(20%)N$_2$atmosphere is obtained a temperature coefficient of resistance(TCR), 0∼-1357 ppm/$^{\circ}C$ in the temperature range 25∼275$^{\circ}C$ and a high temporal stability with a longitudinal gauge factor, 2.92∼3.47. Because of their high resistivity, low TCR and linear gauge factor, these cermet thin-film may allow high-temperature strain gauges miniaturization.

• 한국화재소방학회논문지
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• 제28권2호
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• pp.76-81
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• 2014

화재와 같은 고온 시 구조부재의 붕괴를 방지함으로써 재실자와 소방관계자 그리고 재산을 보호할 수 있는 방법은 구조부재의 내화성능을 확보하는 것이며, 이는 시방적 내화설계방법인 내화시험을 통하여 확보되어 왔다. 그러나 내화시험에 수반되는 시험체 제작과 운반 그리고 막대한 시험 비용의 반복적 사용 등은 새로운 공법과 재료 개발의 문제점으로 대두되었다. 따라서 본 연구에서는 일반 등급(SS 400) 강재의 고온 시 항복강도, 탄성계수와 열전달 및 열응력 해석을 적용하여 H형강 보부재의 표면온도 상승 및 고온 시 내력 변화를 평가하였다. 또한 H형강 보부재의 길이 변화에 따른 고온 시의 보부재의 내력평가를 수행하여 각각의 길이변화에 따른 내력 변화의 차이를 평가하였다.

• Interaction and multiscale mechanics
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• 제5권1호
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• pp.1-12
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• 2012

Considerable longitudinal rail forces and displacements may develop in continuous welded rail (CWR) track on long-span bridges due to temperature variations. The track stability may be disturbed due to excessive relative displacements between the sleepers and ballast bed and the accompanied reduction in frictional resistance. For high-speed tracks, however, solving these problems by installing rail expansion devices in the track is not an attractive solution as these devices may cause a local disturbance of the vertical track stiffness and track geometry which will require intensive maintenance. With reference to temperature, two actions are considered by the bridge loading standards, the uniform variation in the rail and deck temperature and the temperature gradient in deck. Generally, the effect of temperature gradient has been disregarded in the interaction analysis. This paper mainly deals with the effect of temperature gradient on the track-bridge interaction with respect to the support reaction, rail stresses and stability. The study presented in this paper was not mentioned in the related codes so far.

• 한국세라믹학회지
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• 제47권3호
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• pp.223-231
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• 2010

The serious issue of tall building is to ensure the fire-resistance of high strength concrete. The fire resistant finishing method is necessarily essential in order to satisfy the fire resistance time of 3 h required by the law. The fire resistant finishing method is installed by applying a fire resistant material as a method of shotcrete or a fire resistant board to high strength concrete surface. This method can reduce the temperature increase of the reinforcement embedded in high strength concrete at high temperature due to the installation thickness control. This study is interested in identifying the effectiveness of inorganic alumino-silicate compounds including the inorganic admixture such as fly ash and meta-kaolin as the fire resistant finishing materials through the analysis of fire resistance and components properties at high temperature. The study results show that the fire resistant finishing material composed of fly ash and meta-kaolin has the thermal stability of the slight decrease of compressive strength at high temperature. These thermal stability is caused by the ceramic binding capacity induced by alkali activation reaction by the reason of the thermal analysis result not showing the decomposition of calcium hydrate. Inorganic compounds composed of fly ash and meta-kaolin is evaluated to be very effective as the fire resistance material for finishing to protect the concrete substrate by the reason of those simplicity in both application and manufacture. The additional study about the adhesion in the interface with concrete substrate is necessary for the purpose of the practical application.

• 동력기계공학회지
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• 제21권2호
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• pp.20-26
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• 2017

This study was carried out to investigate the effect of precipitate on the high temperature deformation stability of incoloy 825 alloy. $Cr_{23}C_6$ carbide was precipitated under $950^{\circ}C$, but was not detected over $1,000^{\circ}C$. Most of the precipitation consist of $Cr_{23}C_6$ carbide. Strain-rate sensitivity was the highest in 0.01/s and the lowest in 10/s. Strain-rate sensitivity was decreased sharply below $950^{\circ}C$. In the temperature between $850^{\circ}C{\sim}1,150^{\circ}C$, plastic instable area did not exist. It showed the lowest Ziegler Parameter value of 0.06 Ziegler Parameter was the lowest as 0.06 at $850^{\circ}C$ with 10s-1 of strain. The highest Ziegler Parameter value(0.43) was found in plastic deformation at $1,050^{\circ}C$ with 0.01s-1 of strain. It tends to have an higher resistance to the high temperature deformation under $950^{\circ}C$, due to the precipitation.

• 한국디지털건축인테리어학회논문집
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• 제12권4호
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• pp.59-66
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• 2012

This study is interested in identifying the effectiveness of alkali-activated fire protection material compounds including the alkali-activator such as potassium hydroxide, sodium silicate and fly ash as the fire resistant finishing materials. Also, this paper is concerned with change in compressive strength and pore structure of the alkali-activated fire protection material at high temperatures. The testing methods of fire protection materials in high temperature properties are make use of TG-DSC and mercury intrusion porosimetry measurements. This study results show that compressive strength is rapidly degraded depending on a rise of heating temperature. Porosity showed a tendency to increase irrespective of specimen types. This is due to both the outbreak of collapse of gel comprising the cement and a micro crack by heating. However, alkali-activated fire protection material composed of potassium hydroxide, sodium silicate and fly ash has the thermal stability of the slight decrease of compressive strength and porosity at high temperature. These thermal stability is caused by the ceramic binding capacity induced by alkali activation reaction by the reason of the thermal analysis result not showing the decomposition of calcium hydrate.