• 한국산학기술학회논문지
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• 제18권1호
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• pp.107-114
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• 2017

터보차저는 배기가스로 구동되는 엔진 과급기를 말하며, 배기에너지를 이용하여 배기통로에 연결된 터빈의 회전력을 변화시켜, 혼합 가스의 충전효율을 높여 출력과 연비를 향상 시키는 부품이다. 이러한 목적에 따라 과급을 조절해주는 것이 중요하며, 핵심 부품 중 노즐 슬라이드 조인트가 있다. 소재는 현재 오스테나이트 계 스테인리스강으로 높은 내열성과 내식성 등의 우수한 기계적 성질을 이용하고 있다. 그러나 절삭성이 나쁘기 때문에 절삭가공에 의해 복잡한 형상의 제품을 만드는데 어려운 점이 많다. 현재 노즐 슬라이드 조인트의 가공방법은 금속분말 사출성형후 치수정밀도를 위해 절삭가공을 행하고 있다. 따라서 본 연구에서는 Nitronic 60을 이용하여 터보차저 과급유량을 조절해주는 노즐 슬라이드 조인트의 제작 공정에서 절삭가공이 필요 없는 정형가공 공정을 제안하기 위하여, 기계적 특징에 영향과 연관이 있는 소결온도, 제품의 응력 및 변형률, 형상과 관련이 있는 모따기 펀치각도 및 펀치의 곡률반경을 설계변수로 선정하였다. 그에 따라 유한요소해석과 실험계획법인 다구찌법 및 SN비를 이용하여 가장 좋은 공정 조건을 제안하였다. 최종제품과 유한요소해석 결과의 상대밀도 및 정수압을 비교하여 경향이 일치함을 알 수 있었다. 따라서 다구찌법을 이용한 금속분말의 성형공정 설계에 유용하게 적용할 수 있을 것으로 판단된다.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2010년도 추계학술대회 초록집
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• pp.75.2-75.2
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• 2010

Polymer electrolyte fuel cells (PEFCs) have received a lot of attention as a power source for both stationary and mobile applications due to their attractive feature. In general, the performance of PEFCs is highly affected by the property of the electrodes. A PEFC electrode essentially consists of a gas diffusion layer and a catalyst layer. The gas difusion layer is highly porous and hydrophobicized with PTFE polymer. The catalyst layer usually contains electrocatalyst, proton conducting polymer, even PTFE as additive. Particularly, the proton conducting ionomer helps to increase the catalytic activity at three-phase boundary and catalyst utilization. Futhermore, it helps to retain moisture, resulting in preventing the electrodes from membrane dehydration. The most widely used proton conducting ionomer is perfluorinated sulfonic acid polymer, namely, Nafion from DuPont due to its high proton conductivity and good mechanical property. However, there are great demands for alternative ionomers based on non-fluorinated materials in terms of high temperature availability, environmental adaptability and production cost. In this study, the electrodes with the various content of the sulfonated poly(ether sulfone) ionomer in the catalyst layer were prepared. In addition, we evaluated electrochemical properties of the prepared electrodes containing the various amount of the ionomers by using the cyclic voltammetry and impedance spectroscopy to find an optimal ionomer composition in the catalyst layer.

• 한국세라믹학회지
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• 제39권10호
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• pp.948-954
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• 2002

차세대 발전 시스템에서 사용되는 고온 가스 필터용 지지층 소재를 제조하기 위하여 용융 Si 침윤 방법으로 기공율이 32∼36%, 주기공 크기가 37∼90 ${\mu}m$ 범위를 갖는 고강도 다공질 반응소결 탄화규소(RBSC)를 개발하였다. 반응소결 탄화규소 다공체의, 최대 파괴강도는 120MPa이었으며, 용융 Si 침윤 방법으로 제조된 반응소결 탄화규소 다공체에서는 SiC 입자 사이에 SiC/Si로 이루어진 기지상이 형성되어 있기 때문에 파괴 강도 및 열충격 특성이 점토 결합 탄화규소 다공체 보다 우수하였다. 반응소결 탄화규소 다공체의 기공율 및 기공 크기는 잔류 Si의 양 및 성형체에 사용한 SiC 입자 크기에 따라 다르게 나타났다.

• 폴리머
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• 제31권1호
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• pp.8-13
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• 2007

나일론 6/poly(acrylonitrile-co-butadiene-co--styrene) (ABS) 블렌드의 단점을 해결하기 위해 ABS의 고무상인 폴리부타디엔 대신 폴리(부틸 아크릴레이트)를 고무상으로 포함하고 있는 poly(acrylonitrile-co-styrene-co-acrylic rubber) (ASA)를 사용하여 새로운 나일론/ASA 블렌드를 실험하였다. 고충격성을 갖는 블렌드 제조를 위하여 상용화제로 무수 말레산을 25 wt% 포함한 poly(styrene-co-maleic anhydride) (SMA)와 이를 3 wt% 이하 포함한 poly(styrene-co-acrylonitrile-co-maleic anhydride) (SANMA)를 사용하여 블렌드를 제조하였다. 나일론/ASA 블렌드에서 상용화제의 함량에 따른 물성 변화는 나일론/ABS 블렌드와 유사한 경향을 나타내었다. 블렌드 내의 고무 함량이 20 wt% 이상일 때 안정된 물성의 고충격 블렌드가 제조되었다. 블렌드를 사출 성형 온도에서 사출 성형기 내에 체류시킨 후 제조한 시편의 충격 강도를 시험한 결과 SMA를 상용화제로 사용한 경우 충격 강도의 감소가 관찰된 반면 SANMA를 상용화제로 사용한 블렌드에서는 충격 강도의 변화가 거의 없었다.

• 한국주조공학회지
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• 제31권2호
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• pp.66-70
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• 2011

Hot dip aluminizing (HDA) is widely used in industry for improving corrosion resistance of material. The formation of intermetallic compound layers during the contact between dissimilar materials at high temperature is common phenomenon. Generally, intermetallic compound layers of $Fe_2Al_5$ and $FeAl_3$ are formed at the Al alloy and Fe substrate interface. In case of cast iron, high contact angle of graphite existed in the matrix inhibits the formation of intermetallic compound layer, which carry with it the disadvantage of a reduced reaction area and mechanical properties. In present work, the process for the removal of graphite existed on the surface of specimen has been investigated. And also HDA was proceeded at $800^{\circ}C$ for 3 minutes in aluminum alloy melt. The efficiency of graphite removal was increased with the reduction of particle size in sanding process. Graphite appears to be present both in the region of melting followed by re-solidification and in the intermetallic compound layer, which could be attributed to the fact that the surface of cast iron is melted down by the formation of low melting point phase with the diffusion of Al and Si to the cast iron. Intermetallic compound layer consisted of $Fe(Al,Si)_3$ and $Fe_2Al_5Si$, the layer formed at cast iron side contained lower amount of Si.

• Restorative Dentistry and Endodontics
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• 제16권2호
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• pp.18-32
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• 1991

The purpose of this study was to observe characteristic properties of amalgam through the polarization curves and SEM images from 4 type amalgams (Amalcap, Shofu spherical. Dispersalloy and Tytin) with 3 different surface finish procedures (polishing, burnishing and carving) by using the potentiostats (EG & GPARC) and SEM (Jeol JSM-35). After each amalgam alloy and Hg was triturated as the direction of the manufacturer by means of mechanical amalgamator (Samki), the triturated mass was inserted into the cylndrical metal mold which was 12 mm in diameter and 10 mm in height and was pressed with $100kg/cm^2$. 4 specimens of each type amalgam were burnished with egg burnisher and another 4 specimens of each type amalgam were carved with Hollenback carver. Above 8 specimens and remaining untreated 4 specimens were stored at room temperature for about 7 days. Untreated 4 specimens of each type amalgam were polished with abrasive papers (Deer) from #400 to #1200 and finally on the polishing cloth with $0.5{\mu}m$ and $0.06{\mu}m$ $Al_2O_3 $ powder suspended water. Anodic polarization measurements was employed to compare the corrosion behaviours of the amalgams in 0.9% saline solution at $37^{\circ}C$. The open circuit potential was determined after 30 minutes immersion of specimen in electrolyte. The scan rate was 1 mV/sec and the surface area of amalgam exposed to the solution was $0.64cm^2$ for each specimen. All the potentials reported are with respect to a saturated calomel electrode (SCE). SEM images of each specimen were taken after + 800 mV (SCE) polarization. The results were as follows: 1. The corrosion potential of high copper amalgam was more anodic than that of low copper amalgam. 2. The polished amalgam were more resistant to corrosion than any other burnished and carved amalgam. 3. In the case of polishing, current density of high copper amalgam was lower than that of low copper amalgam.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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• pp.283-283
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• 2013

Because of beautiful glossy and color, the value of gold leverage is very high in Europe. To improve the quality of gold alloys, we performed heat treatment on 14 K white gold alloys by variously changing age-hardening conditions. Age-hardening behavior and the related phase transformation changes were studied to elucidate the hardening mechanism of 14 K white gold alloy. For solid solution treatment [ST], casted gold alloy specimens were treated at high temperature ($750^{\circ}C$) for 30 minutes, and the specimens dropped to water to quench them. For Age-hardening treatment [AT], the specimens were treated at various temperatures ($250{\sim}300^{\circ}C$). After the heat treatment, we observed the phenomenon to increase hardness from 126 Hv to 166 Hv by Vicker's hardness tester. Through electron probe micro-analysis (EPMA) mapping analysis, we investigated that irregular particles were changed uniformly. In the SEM and OM images, two phases of matrix and particle-likestructures were observed, and the precipitation of these elements from the matrix progressed during age-hardening. By transmission electron microscope and X-ray diffraction observation, it was revealed that the formation of the Au3Cu superstructure contributed to the age-hardening at $270^{\circ}C$ in the gold alloy. After the heat treatment, this analysis shows that casted gold alloys were to improve hardness and to moderate surface defects at specific temperatures and duration.

• 한국분말재료학회지
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• 제10권6호
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• pp.406-414
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• 2003

In order to produce good wear resistance powder metallurgy Al-Si alloys with high strength, addition of glass forming elements of Ni and Ce in $Al_{81}$Si$_{19}$ alloy was examined using SEM, TEM, tensile strength and wear testing. The solubility of Si in aluminum increased with increasing Ni and Ce contents for rapidly solidified powders. These bulk alloys consist of a mixed structure in which fine Si particles with a particle size below 500 nm and very fine A1$_3$Ni, A1$_3$Ce compounds with a particle size below 200 nm are homogeneously dispersed in aluminum matrix with a grain size below 600 nm. The tensile strength at room temperature for $Al_{81}$Si$_{19}$, $Al_{78}$Si$_{19}$Ni$_2$Ce$_{0.5}$, and $Al_{76}$Si$_{19}$Ni$_4$Ce$_1$ bulk alloys extruded at 674 K and ratio of 10 : 1 is 281,521, and 668 ㎫ respectively. Especially, $Al_{73}$Si$_{19}$Ni$_{7}$Ce$_1$ bulk alloy had a high tensile strength of 730 ㎫. These bulk alloys are good wear-resistance bel ter than commercial I/M 390-T6. Specially, attactability for counterpart is very little, about 15 times less than that of the I/M 390-T6. The structural refinement by adding glass forming elements such as Ni and Ce to hyper eutectic $Al_{81}$Si$_{19}$ alloy is concluded to be effective as a structural modification method.d.tion method.

• 한국분말재료학회지
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• 제24권4호
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• pp.308-314
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• 2017

$Fe_3O_4$/Fe/graphene nanocomposite powder is synthesized by electrical wire explosion of Fe wire and dispersed graphene in deionized water at room temperature. The structural and electrochemical characteristics of the powder are characterized by the field-emission scanning electron microscopy, X-ray diffraction, Raman spectroscopy, field-emission transmission electron microscopy, cyclic voltammetry, and galvanometric discharge-charge method. For comparison, $Fe_3O_4$/Fe nanocomposites are fabricated under the same conditions. The $Fe_3O_4$/Fe nanocomposite particles, around 15-30 nm in size, are highly encapsulated in a graphene matrix. The $Fe_3O_4$/Fe/graphene nanocomposite powder exhibits a high initial charge specific capacity of 878 mA/g and a high capacity retention of 91% (798 mA/g) after 50 cycles. The good electrochemical performance of the $Fe_3O_4$/Fe/graphene nanocomposite powder is clearly established by comparison of the results with those obtained for $Fe_3O_4$/Fe nanocomposite powder and is attributed to alleviation of volume change, good distribution of electrode active materials, and improved electrical conductivity upon the addition of graphene.

• 한국산학기술학회논문지
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• 제7권6호
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• pp.1302-1307
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• 2006

본 연구는 고효율의 광촉매 제조와 그것의 환경적 응용에 관한 것이다. 가시광 영역에서도 $TiO_2$와 유사한 빛 흡수와 광분해속도를 갖는 나노 광촉매를 제조하였고, 낮은 온도에서도 활성 높은 rutile상이 형성하는 $TiO_2$ 광촉매를 제조하여 $SiO_2$위에 분산시켰다 또한, 광촉매에 적용 가능한 바인더와 안정한 $TiO_2$ 광촉매 졸을 제조하였다. 이와같은 물질들은 자외선/가시광선 분광광도계, X선 회절분석기, SEM, 광촉매활성 측정과 $TiO_2$ 코팅 표면의 물성으로 평가하였다. 이 결과들은 공기정화를 위하여 POF나 금속판을 이용하는 효율적인 광촉매 시스템에 적용 할 수 있다.