• Title/Summary/Keyword: Heavy water

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Exfoliated Graphite for Spilled Heavy Oil Recovery

  • Inagaki, Michio;Toyoda, Masahiro;Iwashita, Norio;Nishi, Yoko;Konno, Hidetaka
    • Carbon letters
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    • v.2 no.1
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    • pp.1-8
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    • 2001
  • Exfoliated graphite was found to sorb selectively a large amount of heavy oil, about 80 g of heavy oil floating on water per 1 g of exfoliated graphite, which is highly possible to be applied to recovering spilled heavy oil. Sorption capacity, selectivity and kinetics of exfoliated graphite were reviewed. The possibility of recovery of heavy oil from exfoliated graphite and recycling of both recovered heavy oil and exfoliated graphite was also discussed. Its sorption performance was compared with other materials which were reported to show sorption of heavy oil.

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Risk Assessment for Heavy Metals in Soil, Ground Water, Rice Grain nearby Abandoned Mine Areas (국내 폐금속 광산지역에서의 토양, 지하수, 쌀의 중금속 노출에 따른 인체 위해성평가)

  • Na, Eun-Shik;Lee, Yong-Jae;Ko, Kwang-Yong;Chung, Doug-Young;Lee, Kyu-Seung
    • Korean Journal of Environmental Agriculture
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    • v.32 no.4
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    • pp.245-251
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    • 2013
  • BACKGROUND: The objectives of this study are to investigate the contamination levels of heavy metals in soil, ground water, and agricultural product near the abandoned Boeun and Sanggok mine areas in Korea and to assess the health risk for these local residents exposed to the toxic heavy metals based on analytical data. METHODS AND RESULTS: By the results of human health risk assessment for local residents around Boeun and Sanggok, human exposure to cadmium, copper, arsenic from soil and to lead, cadmium, and arsenic from rice grain were higher in Sanggok, but human exposure to zinc and arsenic from ground water was higher in Boeun. By the results of hazard index (HI) evaluation for arsenic, cadmium, copper, lead, and zinc, HI values in both areas were higher than 1.0. This result indicated that the toxicity hazard through the continuous exposure to lead, cadmium, arsenic from rice, ground water, and soil would be likely to occur to the residents in the areas. Cancer risk assessment for arsenic, risks from the rice were exposed to one to two out of 10,000 people in Boeun and one of 1,000 people in Sanggok. These results showed that the cancer risks of arsenic in both areas were 10~100 times greater than the acceptable cancer risk range of US EPA ($1{\times}10^{-6}{\sim}1{\times}10^{-5}$). CONCLUSION(S): Therefore, if these two local residents consume continuously with arsenic contaminated soil, ground water, and rice, the adverse health effects (carcinogenic potential) would be more increased.

Quantitative Risk Assessment Method for Metals in Water Body using WASP (WASP 모의를 이용한 하천 수계 중금속 위해성평가 방법)

  • Shin, Yu-Ri;Yoon, Chun-Gyeong;Jeon, Na-Jeong;Rhee, Han-Pil
    • Journal of Korean Society on Water Environment
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    • v.26 no.4
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    • pp.629-636
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    • 2010
  • According to the spatial movements of the Nak-dong river watershed, the changes in heavy metal concentrations were simulated by WASP7.3. The risk assessment was performed using the predicted data of WASP7.3. The target heavy metal was manganese (Mn). In the simulated manganese data of WASP7.3, the average concentration by regions was from 0.03 mg/L to 0.07 mg/L. It is lower than drinking water standard in korea. The risk assessment was presented that it was high at the junction of Nak-dong river and Kumho river. It was influenced by the discharge of industrial complexes and large cities which were located in the junction. In comparison of drinking water standard and predicted data of WASP7.3 risk assessment, whole watershed was also low level at predicted data. However, to keep the similar risk value ($10^{-7}$) in adults and children anywhere, it requires the additional treatment of the point source discharges. It was also reflected by regions. Through this study, it was possible to evaluate heavy metal influence in unattainable monitoring regions and to estimate heavy metal addition and reduction by locations. Therefore, the outcomes of WASP7.3 can connect with the risk assessment and it can evaluate the safety of human by regions.

Preparations and characteristics of the ceramic balls for heavy metals absorption and antibacterial activities in the drinking water (음용수중의 중금속흡착과 항균성용 세라믹 볼의 제조 및 특성평가)

  • Park, Chun-Won;Park, Ra-Young;Park, Sun-Min
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.15 no.6
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    • pp.263-268
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    • 2005
  • The ceramic balls impregnated with $20{\sim}40nm$ sized Ag colloid were examined for heavy metals absorption and antibacterial activities in the drinking water. The preparation conditions of ceramic ball that the porosity was excellent were as follows: starting material: 85 wt% $Ca_{10}(PO_4)_6(OH)_2$, binder: 5 wt% PVA and 15 wt% ${\alpha}-Ca_3(PO_4)_2$, heating temperature: $1000^{\circ}C$, duration: 3 hrs. The ceramic balls obtained under these conditions showed specific surface area of $110m^2/g$, pore size of $120{\mu}m$ and porosity of 80%. Also, as the results of a performance test on a rate of adsorbing and removing heavy metals in the drinking water by using the.AAS, heavy metals such as Zn, Mn, Fe and Cu were removed to the extent that their content became 0.03mg/l or lower after 1 day and they showed an excellent bactericidal activity that all coliforms were killed after 3 hrs.

Risk Evaluation of Monopotassium Phosphate (MKP) and Bentonite Application via the Mobility Reduction of Soil TNT and Heavy Metals (제일인산칼륨과 벤토나이트 처리를 통한 토양 내 TNT와 중금속 이동성 및 인체위해도 저감 기술)

  • Jung, Jae-Woong;Yu, Gihyeon;Nam, Kyoungphile
    • Journal of Soil and Groundwater Environment
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    • v.20 no.6
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    • pp.28-36
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    • 2015
  • Simultaneous mobility reduction of explosives and heavy metals in an operational range by monopotassium phosphate (MKP) and bentonite spreading technology was investigated. Potassium ion and phosphate ion in MKP act as explosives sorption enhancer and insoluble heavy metal phosphate formation, respectively, while bentonite acts as the explosives adsorbent. Then, the decrease in surface water concentration of the pollutants and resulting risk reduction for local residents of the operational range, by MKP/bentonite application was estimated. Under untreated scenario, the noncancer hazard index (HI) exceeded unity on February, July and August, mainly due to 2,4,6-trinitrotoluene (TNT); however, MKP/bentonite treatment was expected to lower the noncancer hazard index by decreasing the surface water concentration of explosives and heavy metals (especially TNT). For example, on July, estimated surface water concentration and HI of TNT were 0.01 mg/L and 1.1, respectively, meanwhile the sorption coefficient of TNT was 3.9 mg1−nkg−1Ln. However, by MKP/bentonite treatment, the TNT sorption coefficient increased to 113.8 mg1−nkg−1Ln and the surface water concentration and HI decreased to about 0.002 mg/L and 0.2, respectively. Based on the result, it can be concluded that MKP/bentonite spreading is a benign technology that can mitigate the risk posed by the pollutants migration from operational ranges.

Study on Heavy Metal Desorption and Recovery of the Carbon Foam used in Industrial Plating Wastewater Treatment as Adsorbent (산업도금폐수 처리에 사용된 탄소폼 흡착소재의 중금속 탈착 및 회수에 관한 연구)

  • Lee, Da-Young;Lee, Chang-Gu;Kim, Dae-Woon;Park, Sang-Hyen;Kweon, Ji-Hyang;Lee, Sang-Hyup
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.11
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    • pp.627-634
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    • 2016
  • We investigated the characteristics of heavy metal desorption and recovery from carbon foam after plating wastewater treatment. The heavy metal desorption depends on solution chemistry because desorption occurred in HCl and $H_2SO_4 $ solution but did not occur in distilled water. Heavy metal desorption efficiency was increased using ultrasonication with desorption solution. The higher ultrasonic power and the longer reaction time improve efficiency. The copper plating rinse solution was treated reliably by carbon foam adsorbent during 200 bed volume. The adsorbed copper was dissolved using desorption solution and recovered by DC power supply. After copper recovery, the reuse efficiency of desorption solution was 84.2%.

ACCUMULATION OF HEAVY METAL IN SHELLFISH 1. On the Copper Content in Green Oysters (패류의 중금속 축적에 관한 연구 1. 녹색 굴의 동함유량에 관하여)

  • CHO Yong-Kae;KIM Choon-Kwon
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.4 no.2
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    • pp.61-65
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    • 1971
  • It is well known that shellfish absorb and accumulate heavy metals in the water environment. When the concentration of the heavy metals in the water is above guideline, we find abnormal accumulation of them in the body of shellfish. This study on green oysters is an instance showing the relationship between the abnormal accumulation of heavy metal and industrial wastewaters containing it. The influence of the industrial wastewaters upon shellfish has been discussed from the statistical, physiological, and saprobiensystematic points of view, and the author wants to make clear of the absorption and accumulation mechanism of the heavy metals and physiological situation. This paper deals with the copper-contents in the meat of oysters which were collected in Changhang Bay and Daechun area, the latter being not supposed to be influenced by the water of the Kum River during the period from October 1970 to february 1971. The mean value of the copper contents in oysters caught at the sampling station in the Changhang Bay area is ranged from 851.5 to 143.1mg Cu/kg wet base, and that of Daechun area varied from 13.0 to 27.4mg Cu/kg wet base, so an evident difference is seen at a significance of $0.1\%$. It appears that one of the environmental factors making copper concentrated in the oysters of the Changhang area is due to the copper-contaning slug being discharged into the sea water by the Changhang Ore Refinery.

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Problems of Water Resources with New Measures for Conservation in Italy (이탈리아 수자원의 당면문제와 새로운 보전방안)

  • 조윤승
    • Journal of environmental and Sanitary engineering
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    • v.10 no.3
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    • pp.115-123
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    • 1995
  • Most countries have problems regarding the quantity and quality of their fresh water resources, and many countries are suffering from the e(feces of pollution of their inland and coastal waters. Italy is one of the country in which water supply is extremely uneven, and there are wide areas where it represents a real emergencies during periods of drought. All the watershed's water resources, however, are subjected to considerable anthropogenic pressure such as organic load with heavy metals. The high values of organic materials are accounted for mainly by runoff and percolation waste water from urban and agricultural land extensively ma- nured with effluents (rom livestock farming, while high concentration of heavy metals are found in watersheds of national and interregional significance. More than 35% of the underground water bearing strata of certain basins are already contaminated by pollution boih industrial and agricultural pollutants. In these connection, the problems and new measures of water resources in Italy are overviewed.

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Operational Improvement of Small Urban Storm Water Pumping Station (1) - Simulation of Flood Hydrograph using GIS-based Hydrologic Model (도시 소유역 배수펌프장 운영개선 방안 연구 (1) - GIS 기반 수문모형에 의한 홍수유출수문곡선의 재현)

  • Gil, Kyung-Ik;Han, Jong-Ok;Kim, Goo-Hyun
    • Journal of Korean Society on Water Environment
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    • v.21 no.6
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    • pp.682-686
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    • 2005
  • Recently some urban areas have been flooded due to heavy storm rainfalls. Though major causes of these floodings may be attributed to localized heavy rainfalls, other factors are related to urban flooding including deficiency of storm sewer network capacity, change of surface runoff due to covered open channels, and operational problems of storm drainage pump stations. In this study, hydrologic and hydraulic analysis of Sutak basin in Guri city were carried out to evaluate flooding problems occurred during the heavy storm in July, 2001. ArcView, a world most widely used GIS tool, was used to extract required data for the hydrologic analysis including basin characteristics data, concentration times, channel routing data, land use data, soil distribution data and SCS runoff curve number generation from digital maps. HEC-HMS, a GIS-based runoff simulation model, was successfully used to simulate the flood inflow hydrograph to Sutak pumping station.

Environmental Source of Arsenic Exposure

  • Chung, Jin-Yong;Yu, Seung-Do;Hong, Young-Seoub
    • Journal of Preventive Medicine and Public Health
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    • v.47 no.5
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    • pp.253-257
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    • 2014
  • Arsenic is a ubiquitous, naturally occurring metalloid that may be a significant risk factor for cancer after exposure to contaminated drinking water, cigarettes, foods, industry, occupational environment, and air. Among the various routes of arsenic exposure, drinking water is the largest source of arsenic poisoning worldwide. Arsenic exposure from ingested foods usually comes from food crops grown in arsenic-contaminated soil and/or irrigated with arsenic-contaminated water. According to a recent World Health Organization report, arsenic from contaminated water can be quickly and easily absorbed and depending on its metabolic form, may adversely affect human health. Recently, the US Food and Drug Administration regulations for metals found in cosmetics to protect consumers against contaminations deemed deleterious to health; some cosmetics were found to contain a variety of chemicals including heavy metals, which are sometimes used as preservatives. Moreover, developing countries tend to have a growing number of industrial factories that unfortunately, harm the environment, especially in cities where industrial and vehicle emissions, as well as household activities, cause serious air pollution. Air is also an important source of arsenic exposure in areas with industrial activity. The presence of arsenic in airborne particulate matter is considered a risk for certain diseases. Taken together, various potential pathways of arsenic exposure seem to affect humans adversely, and future efforts to reduce arsenic exposure caused by environmental factors should be made.