Browse > Article
http://dx.doi.org/10.4491/KSEE.2016.38.11.627

Study on Heavy Metal Desorption and Recovery of the Carbon Foam used in Industrial Plating Wastewater Treatment as Adsorbent  

Lee, Da-Young (Center for Water Resource Cycle Research, Korea Institute of Science and Technology)
Lee, Chang-Gu (Center for Water Resource Cycle Research, Korea Institute of Science and Technology)
Kim, Dae-Woon (R&D Center, Smithers-Oasis Korea)
Park, Sang-Hyen (R&D Center, Smithers-Oasis Korea)
Kweon, Ji-Hyang (Department of Environmental Engineering, Konkuk University)
Lee, Sang-Hyup (Center for Water Resource Cycle Research, Korea Institute of Science and Technology)
Publication Information
Abstract
We investigated the characteristics of heavy metal desorption and recovery from carbon foam after plating wastewater treatment. The heavy metal desorption depends on solution chemistry because desorption occurred in HCl and $H_2SO_4 $ solution but did not occur in distilled water. Heavy metal desorption efficiency was increased using ultrasonication with desorption solution. The higher ultrasonic power and the longer reaction time improve efficiency. The copper plating rinse solution was treated reliably by carbon foam adsorbent during 200 bed volume. The adsorbed copper was dissolved using desorption solution and recovered by DC power supply. After copper recovery, the reuse efficiency of desorption solution was 84.2%.
Keywords
Carbon Foam; Heavy Metal; Desorption; Recovery; Plating Wastewater;
Citations & Related Records
Times Cited By KSCI : 1  (Citation Analysis)
연도 인용수 순위
1 Mishra, S. P., "Adsorption-desorption of heavy metal ions," Cur. Sci., 107, 601-612(2014).
2 Malamis, S., Katsou, E., Kosanovic, T. and Haralambous, K. J., "Combined adsorption and ultrafiltration processes employed for the removal of pollutants from metal plating wastewater," Sep. Sci. Technol., 47, 983-996(2012).   DOI
3 Lee, C. G., Park, J. A., Choi, J. W., Ko, S. O. and Lee, S. H., "Removal and recovery of Cr(VI) from industrial plating wastewater using fibrous anion exchanger," Water Air Soil Pollut., 227, 287-11(2016).   DOI
4 Gautam, R. K., Mudhoo, A., Lofrano, G. and Chattopadhyaya, M. C., "Biomass-derived biosorbents for metal ions sequestration: adsorbent modification and activation methods and adsorbent regeneration," J. Environ. Chem. Eng., 2, 239-259(2014).   DOI
5 Lata, S., Singh, P. K. and Samadder, S. R., "Regeneration of adsorbents and recovery of heavy metals: a review," Int. J. Environ. Sci. Technol., 12, 1461-1478(2015).   DOI
6 Tondi, G., Pizzi, A., Delmotte, L., Parmentier, J. and Gadiou, R., "Chemical activation of tanninefuranic carbon foams," Ind. Crop. Prod., 31, 327-334(2010).   DOI
7 Liu, S., Huang, Z. and Wang, R., "A carbon foam with a bimodal microemesoporous structure prepared from larch sawdust for the gas-phase toluene adsorption," Mater. Res. Bull., 48, 2437-2441(2013).   DOI
8 Chen, F., Yang, B., Ma, J., Qu, J. and Liu, G., "Decontamination of electronic waste-polluted soil by ultrasound-assisted soil washing," Environ. Sci. Pollut. Res., Published online (2016).
9 Ye, M., Sun, M., Liu, Z., Ni, N., Chen, Y., Gu, C., Kengara, F. O., Li, H. and Jiang, X., "Evaluation of enhanced soil washing process and phytoremediation with maize oil, carboxymethyl-b-cyclodextrin, and vetiver grass for the recovery of organochlorine pesticides and heavy metals from a pesticide factory site," J. Environ. Manage., 141, 161-168(2014).   DOI
10 Li, G., Zhao, Z., Liu, J. and Jiang, G., "Effective heavy metal removal from aqueous systems by thiol functionalized magnetic mesoporous silica," J. Hazard. Mater., 192, 277-283(2011).
11 Zou, Z., Qiu, R., Zhang, W., Dong, H., Zhao, Z., Zhang, T., Wei, X. and Cai, X., "The study of operating variables in soil washing with EDTA," Environ. Pollut., 157, 229-236 (2009).   DOI
12 Korkut, O., Sayan, E., Lacin, O. and Bayrak, B., "Investigation of adsorption and ultrasound assisted desorption of lead (II) and copper (II) on local bentonite: a modelling study," Desalination, 259, 243-248(2010).   DOI
13 Lacin, O., Bayrak, B., Korkut, O. and Sayan, E., "Modeling of adsorption and ultrasonic desorption of cadmium(II) and zinc(II) on local bentonite," J. Colloid Interface Sci., 292, 330-335(2005).   DOI
14 Meng, R. and Yu, X., "Investigation of ultrasound assisted regeneration of Ni. bentonite with response surface methodology (RSM)," Appl. Clay Sci., 54, 112-117(2011).   DOI
15 Zhang, W., Li, X., Yang, Z., Tang, X., Ma, Y., Li, M., Hu, N., Wei, H. and Zhang, Y., "In situ preparation of cubic $Cu_2O$-RGO nanocomposites for enhanced visible-light degradation of methyl orange," Nanotechnology, 27, 265703 (2016).   DOI
16 Webb, P. A., "Introduction to chemical adsorption analytical techniques and their applications to catalysis," MIC Technical Publications, Micromeritics Instrument Corp. (2003).
17 Burke, D. M., Morris, M. A. and Holmes, J. D., "Chemical oxidation of mesoporous carbon foams for lead ion adsorption," Sep. Purif. Technol., 104, 150-159(2013).   DOI
18 Lee, C. G., Jeon, J. W., Hwang, M. J., Ahn, K. H., Park, C., Choi, J. W. and Lee, S. H., "Lead and copper removal from aqueous solutions using carbon foam derived from phenol resin," Chemosphere, 130, 59-65(2015).   DOI
19 Lee, C. G., Song, M. K., Ryu, J. C., Park, C., Choi, J. W. and Lee, S. H., "Application of carbon foam for heavy metal removal from industrial plating wastewater and toxicity evaluation of the adsorbent," Chemosphere, 153, 1-9(2016).   DOI
20 Sar, P., Kazy, S. K., Asthana, P. K. and Singh, S. P., "Metal adsorption and desorption by lyophilized Pseudomonas aeruginosa," Int. Biodeterior. Biodegrad., 44, 101-110(1999).   DOI
21 Gupta, V. K. and Rastogi, A., "Biosorption of lead(II) from aqueous solutions by non-living algal biomass Oedogonium sp. and Nostoc sp. - a comparative study," Colloid Surf. B-Biointerfaces, 64, 170-178(2008).   DOI
22 Choi, W.-J., Park, K.-M., Yoon, B.-G., Kim, M.-C. and Oh, K.-J., "Recovery of Presource from Sewage Sludge by a Struvite-forming Method," Korean Soc. Environ. Eng., 31(7), 557-564(2009).
23 Chen, F., Tan, M., Ma, J., Li, G. and Qu, J., "Restoration of manufactured gas plant site soil through combined ultrasoundassisted soil washing and bioaugmentation," Chemosphere, 146, 289-299(2016).   DOI