• Title/Summary/Keyword: Heavy metal contaminated sediment

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폐금속광산 하류하천에서의 수변식물내 중금속의 축척에 관한 연구

  • 김주선;이재영;최상일
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.09a
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    • pp.235-240
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    • 2004
  • This study is to study accumulation of the heavy metals by riparian vegetation throughout analysis of the heavy metal concentration in riparian vegetation, water, and sediment near mine drainage. According to analyzing concentration of the heavy metals in riparian vegetation, water, and sediment, the heavy metal was indicated at the leaf significantly. Compared with the concentration of sediment soil, the maximum concentration of the As, Cd, CN, Pb, Zn was higher 2.6, 2.6, 2.5, non-detect, and 1.5 times in leaf, Also those concentration have 9.6, 16.6, 2.5, 1.6, and 2.5 times in root. As the results, the author can know the sediment has a very relative to vegetation in mine drainage, because the increasing of concentration of heavy metal in sediment gives the more accumulative concentration of heavy metal in vegetation. Compared with the concentration of contaminated site and non-contaminated site. As, Cd, CN, Pb, Zn the maximum concentration in sediment soil was higher 5.7, 258.1, 10.9, 370.0, and 298.3 times respectively. In case of vegetation, the maximum concentration of the As, Cd, CN, Pb, Zn was higher 5.6, 62.3, 5.0, non-detect, and 30.6 times in leaf. Also those concentration have 8.5, 63.3, 2.6, 60.7, and 62.1 times in root. In this study, the author can surmise that there indicated a lot of adsorption with the heavy metal concentration in contaminated mine drainage.

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Application of Red Mud and Oyster Shell for the Stabilization of Heavy Metals (Pb, Zn and Cu) in Marine Contaminated Sediment (적니와 굴패각을 이용한 해양오염퇴적물 내 중금속(Pb, Zn and Cu) 안정화 처리)

  • Shin, Woo-Seok;Kang, Ku;Park, Seong-Jik;Um, Byung-Hwan;Kim, Young-Kee
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.11
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    • pp.751-756
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    • 2012
  • In this study, a heavy-metal stabilization treatment using stabilizing agents derived from waste resources was utilized on Incheon North Port range sediment contaminated with Pb, Zn, and Cu. Both calcined red mud (5%, 10%, and 15% w/w) and oyster shell (5%, 10%, and 15% w/w) were applied for a wet-curing duration of 15 days. From the sequential extraction results, the oxide and organic fraction of heavy metals (Pb, Zn, and Cu) were observed strongly in the contaminated sediment. However, the fraction of heavy metal in the stabilized sediment was higher than the organic and residual fraction, in comparison to the contaminated sediment. Moreover, the leaching of heavy metals was reduced in the stabilized sediment, compared with the contaminated sediment. From these results, red mud and oyster shell were shown to be potential stabilizers of heavy metals in contaminated sediment.

Immobilization of Heavy metal mechanism in Contaminated Coastal Sediment using Biostimulant Ball (BSB) with Modified Zeolite

  • Subha, Bakthavachallam;Woo, Jung-Hui;Song, Young-Chae
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2016.05a
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    • pp.130-131
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    • 2016
  • Although many metals contaminated sediment from coastal area contain both anionic and cationic heavy metals, the current remediation technologies are not effective for stabilize heavy metals of both anionic and cationic elements from contaminated coastal region. the present work investigated the efficiency and mechanism of immobilization of Fe, Zn, Cr, Cu, Pb and Cd metal solutions in modified zeolite based biostimulant ball. Biostimulant ball containing acetate, nitrate and sulphate which are enhance the activity of marine microorganisms and it can act as electron donors and electron acceptors. Modified zeolite and chelating agent is greatly enhance the metal stabilization due to increased immobility of the analysed metals. The XRD, FT-IR and SEM of modified zeolite which cheating agents containing heavy metals were investigated. The results indicated that heavy metals could be effectively immobilized in modified zeolite and chelating agents in BSB added sediment. The immobilization of heavy metals in modified zeolite and chelating agents along with BSB could be due to stabilize of heavy metal cations. Immobilization of heavy metals using BSB with modified zeolite and chelating agent has lower cost effect and enhance the sediment quality.

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The Basic Study on the Use of Sediment in the Contaminated Brook - The Applicability of Sediment as the Raw Material of Tile - (오염된 하천 저토의 활용 방안에 관한 기초적 연구 -하천 저토의 타일 원료로서의 적합성에 관하여-)

  • Park, Heung-Jai;Lee, Bong-Hun;Jeong, Seong-Ug
    • Journal of Environmental Science International
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    • v.5 no.6
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    • pp.771-778
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    • 1996
  • The sediment in the highly contaminated Gamjeon brook was collected, mixed with the raw material of the tile, and then the commercial tile was produced using the mixture. The concentrations of the heavy metals in the mixture-before and after the tile was produced-were analyzed and the effects of the acid solution on the produced tile were examined. The production of the tiles was successful and the result of heavy metal analysis showed that the concentration of Fe was the highest and that of Cd was the lowest The amount of heavy metal in the sediment - the raw material of the tile mixture was more than that of the produced tile. The elution concentration of the heavy metal by the acid solution(pH : 4 - 7) was low and the quality of the produced tile was better than the commercial tile. The result of this study suggested that the contaminated sediment was removed to produce good tiles, therefore the water pollution and soil pollution were reduced.

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Influence of Heavy Metal on Riparian Vegetation in Downstream Areas of Disused Metal Mines (폐금속광산지역의 하천퇴적물에서 중금속이 식물에 미치는 영향에 관한 연구)

  • Ahn, Tae Woong;Lee, Joung An;Oh, Jong Min
    • Journal of Environmental Impact Assessment
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    • v.18 no.4
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    • pp.209-218
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    • 2009
  • The purpose of this study was to accumulation of the heavy metals by riparian vegetation throughout analysis of the heavy metal concentration in riparian vegetation, water, and sediment near mine drainage. According to analyzing concentration of the heavy metals in riparian vegetation, water, and sediment the heavy metal was indicated at the leaf significantly. Compared with the concentration of sediment soil, the maximum concentration of the As, Cd, CN, Pb, Zn was higher 2.6, 2.6, 25, non-detect, and 15 times in leaf. Also those concentration have 9.6, 16.6, 25, 1.6, and 25 times in root. As the results, the author can know the sediment has a very relative to vegetation in mine drainage. because, the increasing of concentration of heavy metal in sediment gives the more accumulative concentration of heavy metal in vegetation. Compared with the concentration of conta minated site and non-contaminated site. As, Cd, CN, Pb, Zn the maximum concentration in sediment soil was higher 5.7, 258.1, 10.9, 370.0, and 298.3 times respectively. In case of vegetation, the maximum concentration of the As, Cd, CN, Pb, Zn was higher 5.6, 62.3, 5.0, non-detect, and 30.6 times in leaf. Also those concentration have 8.5, 63.3, 2.6, 60.7, and 62.1 times in root. In this study, the author can surmise that there indicated a lot of adsorption with the heavy metal concentration in contaminated mine drainage.

Remediation of Heavy Metal Contaminated Sediments (중금속 오염 퇴적저니의 복원방안)

  • 배우근;이창수;홍종철;장석규;김성진
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 1999.10a
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    • pp.34-38
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    • 1999
  • This paper investigated remediation options for contaminated sediments with heavy metals. Twenty three sediment samples were taken from three different depths of 0.5m, 1.5m and 2.5m. The concentration of Heavy metals Cu, Pb, and Hg were measured. The concentration of copper far exceeded the Sediment Quality Guideline in U.S.A and Interim Sediment Quality Guidelines in Canada. Therefore, remediation of the sediments is requried to protect the benthos. Two remediation options were suggested : dredging of the organic sediments as deep as about 85cm followed by surface covers with clean soil, and in-situ stabilization of tile sediments using lime or cement followed by surface cover with clean soil.

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A Study on Removal of Heavy Metal from Contaminated Sediment via Bioleaching (연안어장 준설 퇴적물내 함유된 중금속 처리에 관한 연구)

  • Ko Seong-Jung;Yun Jong-Hwui;Song Young-Chae;Kim Dong-Geun;Chung Ho-Soon
    • Proceedings of KOSOMES biannual meeting
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    • 2005.05a
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    • pp.119-122
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    • 2005
  • As it is known that the korean coastal fishing areas are getting contaminated by heavy metals from the sediment, the authors conducted the experiments to treat the heavy metals with bioleaching process. As a result, it is found that (1) acidification for the leaching of heavy metals is effectively processed when adding more than $0.3\%$ of sulfur and $0.1\%$ of ferrous sulfate. and (2) copper is rapidly solubilized irrespective of addition of sulfur, while solubilization is not processed even of FeS is added., and (3) bioleaching with sulfur and FeSO4 is possible method to effectively treat the heavy metals form the contaminated sediments.

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Application of Limestone, Zeolite, and Crushed Concrete as Capping Material for Interrupting Heavy Metal Release from Marine Sediments and Reducing Sediment Oxygen Demand (해양퇴적물에서 중금속 용출 차단 및 퇴적물 산소 요구량 감소를 위한 석회석, 제올라이트 및 폐콘크리트의 피복 소재로서 적용)

  • Kang, Ku;Park, Seong-Jik
    • Journal of The Korean Society of Agricultural Engineers
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    • v.57 no.4
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    • pp.31-38
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    • 2015
  • This study aims to assess the effectiveness of limestone, zeolite, and crushed concrete as capping material to block the release of heavy metals (As, Cu, Cr, Ni, and Pb) and reduce the sediment oxygen demand. The efficiency of limestone, zeolite, and crushed concrete was evaluated in a reactor in which a 1-cm thick layer of capping materials was placed on the sediments collected from Inchon north harbor. Dissolved oxygen concentration and heavy metal concentration in seawater above the uncapped sediments and capping material were monitored for 17 days. The sediment oxygen demand was in the following increasing order: crushed concrete ($288.37mg/m^2{\cdot}d$) < zeolite ($428.96mg/m^2{\cdot}d$) < limestone ($904.53mg/m^2{\cdot}d$) < uncapped ($981.34mg/m^2{\cdot}d$). The capping materials could reduce the sediment oxygen demand by blocking the release of biochemical matters consuming dissolved oxygen in seawater. It was also shown that zeolite and crushed concrete could effectively block the release of Cu, Ni, and Pb but those were not effective for the interruption of As and Cr release from marine contaminated sediments.

Distribution Characteristics of Organic Matter and Heavy Metal of Sediment in Daecheon Port (대천항 퇴적물의 유기물 및 중금속 분포 특성)

  • Shin, Woo-Seok;Lim, Ji-Yoon;Yoon, Young-Gwan
    • Journal of Korean Society of Water Science and Technology
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    • v.26 no.6
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    • pp.43-51
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    • 2018
  • In order to systematically and scientifically manage the organic and heavy metals against sediment at Daecheon Port, this study conducted particle composition, organic materials and heavy metals irradiation studies of sediments. Analysis of the grain size composition of sediments in the target study area showed the distribution characteristics of the mix of sand, silt and clay. That is, Station C (Stn. C) showed superior by fine-grained sediment, Station A and B (Stn. A and B) showed superior by coarse-grained sediment. The organic matter(COD, TOC, and IL) of Stn. C was appeared to be heavily polluted more than Stn. A and B. These data for the spatial properties in sediment showed that organic matter was related positively to the sediment silt-clay content. Also, in the case of heavy metals contamination in surface sediments, Stn. C was higher than Stn. A and B. Particularly, at the Stn. C, high organic matter concentration and C/N ratio value( >10) indicated that the sediment was composed highly of land-derived organic matter. From these results, it considered that the correlation analysis among to silt-clay, organic matter and heavy metal was found to have a good interrelationship.

Feasibility of Present Soil Remediation Technologies in KOREA for the Control of Contaminated Marine Sediment: Heavy Metals (우리나라 현존 토양정화 기술의 해양오염퇴적물 정화사업 적용 가능성 검토: 중금속)

  • Kim, Kyoung-Rean;Choi, Ki-Young;Kim, Suk-Hyun;Hong, Gi-Hoon
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.12
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    • pp.1076-1086
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    • 2010
  • Soil remediation technologies were experimented to evaluate whether the technologies could be used to apply remediation of contaminated marine sediment. In this research, marine sediments were sampled at "Ulsan" and "Jinhae" where remediation projects are considered, and then the possibility of heavy metal removal was evaluated throughout the technologies. Heavy metal concentration of silt and clay fraction was higher than that of sand fraction at "Ulsan". Heavy metal removal of the silt and clay fraction was arsenic (As) 81.5%, mercury (Hg) 93.8% by particle separation, cadmium (Cd) 72.2%, mercury (Hg) 93.8% by soil washing technology, cadmium (Cd) 70.8%, lead (Pb) 65.6% by another soil washing technology. Based on experimental results, tested particle separation and soil washing technologies could be used to remove heavy metals of sand fraction and silt and clay fraction. Heavy metal removal by soil washing technology which was composed of separation, washing and physical or chemical reaction by additives such as acid, organic solvents was more effective comparing to that of particle separation. Since heavy metal concentration of all treated samples was suitable for national soil standards, all the tested technologies were could be used not only to remove heavy metals of marine contaminated sediment but also to reuse treated samples in land.