• Korean Journal of Food Science and Technology
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• v.43 no.2
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• pp.230-234
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• 2011

According to the Codex committee, the maximum allowable level for lead in fruits is 0.1 mg/kg. This survey was conducted as a surveillance program following the establishment of safety guideline for fruits in Korea. Concentrations of lead (Pb), cadmium (Cd), arsenic (As) and mercury (Hg) were measured in 927 samples using a ICP-MS and a mercury analyzer. The recoveries of microwave digestion method were 86.0-110.4% for Pb, 81.0-104.0% for Cd and 82.0-104.7% for As by standard addition method. The recovery of direct mercury analyzer was 106.5% for Hg. The average levels of Pb in ${\mu}g/kg$ were $10.0{\pm}12.8$ for apple, $8.8{\pm}10.9$ for pear, $4.1{\pm}4.4$ for persimmons, $14.9{\pm}12.3$ for mandarin, $7.1{\pm}6.5$ for orange, $3.1{\pm}3.3$ for banana, $8.8{\pm}8.9$ for kiwi, and $9.3{\pm}9.7$ for mango. The average levels of Cd in ${\mu}g/kg$ were $0.4{\pm}0.3$ for apple, $2.0{\pm}1.6$ for pear, $0.3{\pm}0.3$ for persimmon, $0.1{\pm}0.1$ for mandarin, $0.1{\pm}0.1$ for orange, $1.3{\pm}1.8$ for banana, $0.5{\pm}0.5$ for kiwi, and $0.7{\pm}0.6$ for mango. The average levels of As in ${\mu}g/kg$ were $2.0{\pm}2.1$ for apple, $1.2{\pm}1.3$ for pear, $1.5{\pm}1.2$ for persimmon, $0.8{\pm}0.3$ for mandarin, $1.5{\pm}0.5$ for orange, $1.8{\pm}1.2$ for banana, $1.6{\pm}1.5$ for kiwi, and $1.2{\pm}1.5$ for mango. The average levels of Hg in ${\mu}g/kg$ were $0.5{\pm}0.4$ for apple, $0.3{\pm}0.2$ for pear, $0.2{\pm}0.1$ for persimmon, $0.2{\pm}0.1$ for mandarin, $0.2{\pm}0.1$ for orange, $0.2{\pm}0.0$ for banana, $0.2{\pm}0.2$ for kiwi, and $0.6{\pm}0.2$ for mango. Based on the Korean public nutrition report 2005, these levels (or amounts) are calculated only at 0.17% for Pb, 0.013% for Cd and 0.006% for Hg of those presented in provisional tolerable weekly Intake (PTWI) which has been established by FAO/WHO. Therefore, the levels presented here are presumed to be adequately safe.

• Applied Biological Chemistry
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• v.23 no.3
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• pp.141-149
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• 1980

Contents of heavy metals in various bran layers of rice collected from Kyeong Nam province in 1978, were determined. The components of crude prote in, crude fat, crude cellulose, and ash in all the rice samples were found to be most concentrated in the rice of each layer of brown, 70% polished, and 90% polished, but the contents of crude protein (9.22%), crude fat (1.16%), crude cellulose (1.01%), and ash (0.38%) in polished rice decreased rapidly. On the other hand, the amounts of nitrogenfree extract in the rice were showed increasingly toward the inner layer and those of polished rice were 75.54%. The contents of lead, zinc, nickel, cadmium, and arsenic in bran layer of rice decreased in order of that of 90% polished, 70% polished, brown, and polished rice. Their amounts in polished rice were lead, $0.054{\sim}0.610ppm$; zinc, $9.830{\sim}19.093ppm$; nickel, trace-1.776ppm; cadmium, trace-0.039ppm; arsenic, ND-0.170ppm. It was shown that copper was more concentrated in the layer of 90% polished rice $(0.581{\sim}1.476ppm)$, and iron more in brown rice $(27.971{\sim}66.569ppm)$ than in any other portion, whereas mercury $(0.006{\sim}0.072ppm)$, chromium $(1.538{\sim}7.822ppm)$, and manganese $(57.371{\sim}179.252ppm)$ were much contained in the layer of 70% polished rice. Their amounts in polished rice were copper, $0.218{\sim}0.858ppm$; iron, $1.480{\sim}9.573ppm$; mercury, $0.006{\sim}0.027ppm$; chromium, ND-1.520ppm; and manganese, $6.730{\sim}11.562ppm$.

• Journal of agricultural medicine and community health
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• v.22 no.2
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• pp.215-223
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• 1997

To estimate association of minerals relating to non-insulin dependent diabetes mellitus(NIDDM) the contents of essential minerals and toxic heavy metals in the scalp hair were measured during the period from March 1993 to June 1993. The cases were selected 69 (32 male, 37 female) from the patients who visited Kyungpook University Hospital during the period from March 1993 to June 1993 and 74 controls (47 male 27 female) from normal population. zinc, copper, manganese, lead, cadmium and aluminum were analyzed by atomic absorption spectrophotometer(IL. 551). The results were summarized as follows. In NIDDM group, mean contents of zinc and copper were $132.99{\pm}19.66$ ppm, $8.58{\pm}5.07$ ppm respectively; where as $152.51{\pm}46.15$ ppm, $12.48{\pm}6.56$ ppm in control group. The mean of above two mineral content showed significant difference statistically (p<0.01). But, in manganese the content of NIDDM group; $0.44{\pm}0.27$ ppm were significantly higher than the control group; $0.34{\pm}0.18$ ppm(p<0.05). A thesis submitted to the Council of the Graduate School of Kyungpook National University in partial fulfillment of the require ements for the degree of Ph.D. in Medical Science in June 1994. The mean contents of toxic metals - lead, cadmium, aluminum - in NIDDM group were $10.04{\pm}4.60$ ppm, $0.57{\pm}0.12$ ppm, $11.31{\pm}3.98$ ppm; whereas $8.10{\pm}2.45$ ppm, $0.41{\pm}0.23$ ppm, $7.61{\pm}4.16$ ppm in control group. The mean of above three mineral showed significant difference statistically(p<0.01). Cadmium, zinc and copper were selected statistically significant variables with presence of the NIDDM by multiple logistic regression analysis; copper, zinc and cadmium may be associated with NIDDM.

• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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• v.14 no.1
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• pp.35-42
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• 2008

Twenty eight gas impermeable plastic films for food-contact application were collected in the domestic market and material and/or migration tests for overall migration, antioxidants, potassium permanganate consumption, heavy metal, and plasticizers were carried out. The average overall migration values for NY/PE or NY/LLDPE, PETP/PE, and PVDC packaging films obtained by using n-heptane as fatty food simulant were 7.6, 6.9 and 14.1 mg/L, respectively. These values were much lower than the limit values of 150 and 30 mg/L for polyethylene and polyvinylidene chloride prescribed in the Korea Food Code. In almost of the packaging materials tested, the antioxidants such as Irganox 1010, Irganox 1076 and Irgafos 168 were found. The migration test result showed that almost of all samples except PVDC film contained Irganox 1076 and Irgafos 168, while the maximum migration value of Irganox 1076 into n-heptane was found in the Ny/PE/LLDPE(15/25/50 ${\mu}m$) sample at the concentration of 216.9 ${\mu}g/g$. From the plastic packaging samples tested, plasticizers such as DEP, DPRP, DBP, DPP, BBP, DCHP, DEHP, DEHA and observed above the detection limit. Consumption amount of potassium permanganate was much lower than the limit value of 10 mg/L. In the material test for heavy metals, cadmium and lead were determined at the concentrations far below the limit value of 100 mg/kg. The migration test for cadmium and lead showed a lower value than the detection limit. Therefore, it can be concluded that the safety status of the plastic films tested met the requirement of limit values as prescribed for the material and migration tests of food packaging utensils, containers and packages of the Korea Food Code.

• Journal of Food Hygiene and Safety
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• v.33 no.2
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• pp.102-109
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• 2018

In the present study, a variety of polylactide (PLA) articles (n = 211) were tested for migration of lead (Pb), cadmium (Cd) and arsenic (As) into the food simulant (4% v/v acetic acid). Pb, Cd, and As were analyzed by inductively coupled plasma mass spectrometry (ICP-MS). Migration tests were performed at $70^{\circ}C$ and $100^{\circ}C$ for 30 min. The amounts of Pb, Cd, and As increased at $100^{\circ}C$ for 30 min compared with levels at $70^{\circ}C$. However, the migration at both conditions was very low. The maximum level of Pb at $100^{\circ}C$ for 30 min corresponded to 1% of the migration limit. The estimated daily intakes (EDI) based on safety evaluation ranged from $2.5{\times}10^{-5}$ to $2.0{\times}10^{-3}{\mu}g/kg\;bw/day$ for Pb, Cd, and As. The EDI calculated from migration of Pb at $100^{\circ}C$ for 30 min in PLA was the maximum value, $2.0{\times}10^{-3}{\mu}g/kg\;bw/day$, which corresponded to 0.055% of provisional tolerable weekly intake (PTWI, $25{\mu}g/kg\;bw/week$). The data from this study represent a valuable source for science-based safety control and management of hazardous heavy metals migrating from polylactide food contact materials.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.7 no.3
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• pp.169-178
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• 1974

Concentrations of mercury, cadmium, lead and copper are determined in the surrounding seawater and in seaweeds, Undarta pinnatifida and Sargassun fulvellum, from Suyeong Bay in Busan in the spring tide and neap tide from January to April 1974. The range and mean of the heavy metal concentrations in the surrounding seawater are as follows : mercury 0.00-0.39 ppb, 0. 16ppb; cadmium 0.00-0.46 ppb, 0.18 ppb, lead 0.00-0.94 ppb, 0.26 ppb : copper 0.00-0.86 ppb, 0.25 ppb respectively, and the concentrations varied slightly according to the tide. The mean values of concentration rate of Hg, Cd, Pb and Cu in air dry base were $0.42\times10^3(0.13\times10^3\~1.0\times10^3)$, $2.1\times10^3(0.8\times10^3\~4.9\times10^3)$, $8.9\times10^3(3.1\times10^3\~19\times10^3)$ and $15\times10^3(6.0\times10^3\~28\times10^3)$ in the Undaria pinnatifida, and $0.25\times10^3($0.06\times10^3\~0.56\times10^3)$, $1.0\times10^3(0.61\times10^3\~1.7\times10^3)$, $5.4\times10^3(3.1\times10^3\~8.5\times10^3)$ and $22.8\times10^3(14.4\times10^3\~52.4\times10^3)$ in the Sargassun fulvellum. The concentration rate of Hg, Cd and Pb of the Undaria pinnatifida was almost twice as much as that of the Sargassun fulvellum but the concentration rate of copper of the former was slightly smaller than of the latter.

• Journal of Preventive Medicine and Public Health
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• v.27 no.1 s.45
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• pp.25-43
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• 1994

To estimate the factors to the inclination of the criminal violence, the content of trace minerals and toxic metals in the scalp hair were measured during the period from May 1992 to October 1992. One hundred eleven violent and 89 nonviolent criminal inmates of Taegu Correctional Institute were selected. The inmates of violent criminals were imprisoned by murder, robber, rape, injury and violent acts. Those of nonviolent criminals were swindle, larceny, and adultery and had no history of institutional violence. The contents of two toxic metals (cadmium, lead) and five trace minerals (Cu, Fe, Zn, Mg, Na) were determined by an atomic absorption spectrophotometer (IL. 551). The contents of cadmium and lead in hair of violent criminals were significantly higher as $0.56{\pm}0.14ppm,\;11.53{\pm}3.32ppm$, respectively, than $0.42{\pm}0.20ppm,\;9.63{\pm}4.31ppm$ of nonviolent group (p<0.01). But the level of copper was significantly lower than nonviolent group (p<0.05). The factors that had a significant correlation with the inclination of violence in multiple logistic regression analysis were cadmium (odds ratio=98.09), unmarried (odds ratio=0.39), many times of criminal history(odds ratio=1.57) and residence of rural area (odds ratio=0.44). The results suggest that the sub-toxic contents of cadmium and lead in the hair may be of potential effect on behavior, and the mineral analysis may be an important adjunctive diagnostic procedure. Further studies into this problem are necessary.

• Journal of the Korea Organic Resources Recycling Association
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• v.26 no.2
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• pp.33-41
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• 2018

Large amounts of leaves from street trees fall onto the streets annually and need to be cleaned and treated. Cherry trees are common street trees in Korea. The adsorption characteristics of Pb(II) by cherry leaf (CL) and cherry leaf-derived biochar (CB) were studied through a series of batch experiments. CB was produced through the carbonization of CL at $800^{\circ}C$ for 90 min. Carbonization increased the C content and pH value, while decreased H and O contents. Well developed pore structure was observed at the surface of CB. The pseudo-second order model better described the kinetics of Pb(II) adsorption onto CL and CB, indicating that the rate-limiting step of the heavy metal sorption is chemical sorption. Fast adsorption rates and high adsorption capacities were obtained by the carbonization from CL to CB. Langmuir models better adequately described the Pb(II) adsorption onto CL and CB. Maximum adsorption capacities of Pb(II) expressed by Langmuir constant, $Q^0$ were 37.31 mg/g and 94.34 mg/g, when CL and CB were used as adsorbents, respectively.

• Journal of the Korean GEO-environmental Society
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• v.17 no.11
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• pp.35-43
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• 2016

In this study, by using a Effective Microorganisms Brewing Cycle, it confirmed the purification effect of pollutants that are adsorbed on the basins stench removal and retarding soil. On the basis of on-site application test, a soil decontamination system will be suggested. Using a Effective Microorganisms Brewing Cycle, the odor concentration is reduced 2.5 times than that of natural purification treatment method. It was measured and found that the quality of the pore water discharged from the soil is improved. In addition, it was found that a composite of copper and lead with the fermentation microorganisms adsorbed on soil particles from the surface of the stirred experiments lagoon mixed soil is reduced to 65% and 66%, respectively, The TPH organic component was confirmed that the reduction effect of 85%. Restoration of reservoir contaminated soils using the effective microorganism brewing cycle needs to be more developed and implemented as a long-term purification system. This study may be a good reference of developing more complete microorganism brewing system which will efficiently reduce the odor and soil contamination based on optimal stirring and mixing ratio of the compound solutions and contaminated soils in reservoir.

• Resources Recycling
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• v.9 no.1
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• pp.52-62
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• 2000

In order to maximize the recycling of converter slag to the more valuable fields, such as high quality aggregates for construction, cement industry and flux for ion making. It will be very important to control the compositions and properties of converter slag to suit the purpose of utilizastion. In this study, converter slag (STELCO, CANADA) was mixed with 5%~30% $SiO_2$and 7% carbon, and then reduced at $1650^{\circ}C$. After the reduction was completed, the reformed slags were cooled to room temperature in the furnace. All of the slags were then characterized using SEM-EDX, XRD and chemical analysis. Also the compressive strengths and densities of the reformed slags were measured to compare with natural aggregates. XRD analysis shows that th phases of reformed slags are changed from bredigite+merwinite mixed phases of 10% $SiO_2$added reduction to akermanite phases of 20% and 30% $SiO_2$ added reduction. But the SEM-EDX analysis revealed that the phase distribution of the reformed slags was changed very sensitively and complicately depends on the change of slag compositions. And also the properties of reformed slags are changed very much depend on the phase distribution. About one third of Cadmium and on fifth of Vanadium are remained in reduction reformed converter slag. Another heavy metal elements such as cobalt, zinc, lead are removed up to more than 90-95% of original slag. The compressive strength and density of 25% $SiO_2$ added and reformed slag is very near to natural granite. This is superior more than 10% to Thyssen's $SiO_2$ added and oxidized converter slag aggregates.