• Title/Summary/Keyword: Heat of reaction

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Conceptual Safety Design Analyses of Korea Advanced Liquid Metal Reactor

  • Suk, S.D.;Park, C.K.
    • Nuclear Engineering and Technology
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    • v.31 no.6
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    • pp.66-82
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    • 1999
  • The national long-term R&D program, updated in 1997, requires Korea Atomic Energy Research Institute(KAERI) to complete by the year 2006 the basic design of Korea Advanced Liquid Metal Reactor(KALIMER), along with supporting R&D work, with the capability of resolving the issue of spent fuel storage as well as with significantly enhanced safety. KALIMER is a 150 MWe pool-type sodium cooled prototype reactor that uses metallic fuel. The conceptual design is currently under way to establish a self-consistent design meeting a set of major safety design requirements for accident prevention. Some of the current emphasis includes those for inherent and passive means of negative reactivity insertion and decay heat removal, high shutdown reliability, prevention of and protection from sodium chemical reaction, and high seismic margin, among others. All of these requirements affect the reactor design significantly and involve extensive supporting R&D programs. This paper summarizes some of the results of conceptual engineering and design analyses performed for the safety of HAMMER in the area of inherent safety, passive decay heat removal, sodium water reaction, and seismic isolation.

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Expansion Characteristics of the Hydrated Sodium Silicate which Synthesized by Hydrothermal Reaction (열수반응으로 합성된 수화규산소다의 팽창 특성)

  • Cho, Ho-Yeon;Kong, Yang-Pyo;Suhr, Dong-Soo
    • Journal of the Korean Ceramic Society
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    • v.45 no.12
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    • pp.845-850
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    • 2008
  • Hydrated sodium silicate was synthesized by hydrothermal reaction using anhydrous sodium silicate. The optimum additions of water was 25wt% to make hydrated sodium silicate with homogeneous and purposed water contents. Porous ceramics with homogeneous microstructure and spherical closed pore can be fabricated by elimination of the large pores(a few mm in size) which was formed during first heat treatment through the decomposition of water. Spherical closed pore was formed above $600^{\circ}C$ and the pore size was increased with increasing second heat treatment temperature due to growth of pores. The size of spherical closed pore was varied from 35 to $233\;{\mu}m$ and specific gravity was varied from 0.2 to 1.02 depending on the combinations of the first and second heat treatment temperature.

Global analysis of heat transfer in Si CZ furnace with specular and diffuse surfaces

  • Hahn, S.H.;Tsukada, T.;Hozawa, M.;Maruyama, S.;Imaishi, N.
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1998.06a
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    • pp.45-48
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    • 1998
  • For the single crystal growth of silicon, a global analysis of heat transfer in a CZ furnace was carried out using the finite element method, where the radiative heat transfer between the surfaces that possess both specular and/or diffuse reflectance components was taken into account, and then the effect of the specular reflection of the crystal and/or melt on the CZ crystal growth was numerically investigated.

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SORET AND CHEMICAL REACTION EFFECTS ON THE RADIATIVE MHD FLOW FROM AN INFINITE VERTICAL POROUS PLATE

  • MALAPATI, VENKATESWARLU;DASARI, VENKATA LAKSHMI
    • Journal of the Korean Society for Industrial and Applied Mathematics
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    • v.21 no.1
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    • pp.39-61
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    • 2017
  • In this present article, we analyzed the heat and mass transfer characteristics of the nonlinear unsteady radiative MHD flow of a viscous, incompressible and electrically conducting fluid past an infinite vertical porous plate under the influence of Soret and chemical reaction effects. The effect of physical parameters are accounted for two distinct types of thermal boundary conditions namely prescribed uniform wall temperature thermal boundary condition and prescribed heat flux thermal boundary condition. Based on the flow nature, the dimensionless flow governing equations are resolved to harmonic and non harmonic parts. In particular skin friction coefficient, Nusselt number and Sherwood number are found to evolve into their steady state case in the large time limit. Parametric study of the solutions are conducted and discussed.

Prediction of MCFC Performance Using Three Dimensional Heat and fluid Flow Analysis with Electrochemical Reaction (전기 화학 반응을 포함한 3차원 열유동 해석을 이용한 용융탄산염 연료전지의 성능예측)

  • Cho H. M.;Lee K. W.;Choi D. H.
    • 한국전산유체공학회:학술대회논문집
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    • 2003.08a
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    • pp.219-224
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    • 2003
  • An analysis procedure for the MCFC channel flow has been developed to predict the fuel cell performance. As for the electrochemical reaction, among several chemical reaction models, one that fits the data best is adopted after a comprehensive comparative study. The Wavier-Stokes, energy, and species equations are solved to obtain the velocity, temperature and concentration fields for a specified average current density. The procedure is iterative as the local current density, or the reaction rate, is allowed to vary with the gas composition. A series of calculations are then carried out to examine the effects of gas flow rate, gas composition, gas usage rate, inlet gas temperature, and average current density on the fuel cell performance. The fuel cell characteristics, such as the temperature, current density distributions, and the concentration fields, for various operating conditions are presented and discussed.

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Conceptual design of a copper-bonded steam generator for SFR and the development of its thermal-hydraulic analyzing code

  • Im, Sunghyuk;Jung, Yohan;Hong, Jonggan;Choi, Sun Rock
    • Nuclear Engineering and Technology
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    • v.54 no.6
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    • pp.2262-2275
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    • 2022
  • The Korea Atomic Energy Research Institute (KAERI) studied the sodium-water reaction (SWR) minimized steam generator for the safety of the sodium-cooled fast reactor (SFR), and selected the copper bonded steam generator (CBSG) as the optimal concept. This paper introduces the conceptual design of the CBSG and the development of the CBSG sizing analyzer (CBSGSA). The CBSG consists of multiple heat transfer modules with a crossflow heat transfer configuration where sodium flows horizontally and water flows vertically. The heat transfer modules are stacked along a vertical direction to achieve the targeted large heat transfer capacity. The CBSGSA code was developed for the thermal-hydraulic analysis of the CBSG in a multi-pass crossflow heat transfer configuration. Finally, we conducted a preliminary sizing and rating analysis of the CBSG for the trans-uranium (TRU) core system using the CBSGSA code proposed by KAERI.

A Study on the Catalytic Ortho-Para Hydrogen Conversion in the Cryogenic Heat Exchanger Filled with Catalysts for Hydrogen Liquefaction (수소액화용 극저온 열교환기 내 촉매 수소 전환반응에 관한 연구)

  • SOHN, SANGHO;YOON, SEOK HO
    • Journal of Hydrogen and New Energy
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    • v.32 no.3
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    • pp.180-188
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    • 2021
  • This paper conducted a study on the ortho-para hydrogen conversion in the cryogenic heat exchanger filled with catalysts for hydrogen liquefaction by utilizing the numerical model of plate-fin heat exchanger considering catalytic reaction of ortho-para hydrogen conversion, heat and mass transfer phenomena and fluid dynamics in a porous medium. Various numerical analyzes were performed to investigate the characteristics of ortho-para hydrogen conversion, the effects of space velocity and activated catalyst performance.

Stabilizing Effect of Ginseng Saponin and Water Extract on Malate Dehydrogenase from Pigeon Breast Muscle (인삼사포닌 및 인삼수용성 추출물이 비둘기 가슴근육으로부터 분리된 Malate Dehydrogenase에 미치는 안정화효과)

  • Kim, Du-Ha;Sin, Mun-Hui;Hong, Sun-Geun
    • Journal of Ginseng Research
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    • v.7 no.1
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    • pp.88-93
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    • 1983
  • Studies were carried out to elucidate the protein stabilizing effect of ginseng. Malate dehydrogenase (EC 1.1.1.37) was used as a protein and the rate constant of the enzyme inactivation was determined under the heat denaturation condition. There was an optimum pH for the enzyme stability, the rate constant of the enzyme inactivation was minimum at BH 8.8. The rate constant was increased at lower and higher pH regions than the optimum pH. The inactivation reaction followed the Arrehnius law and the activation energy was measured as 36.8kcal/mole. The reaction rate was not affected by the enzyme concentration and thus it was assumed to be unimolecular first order reaction. The water extract of red ginseng decreased the rate constant of Malate dehydrogenate under heat inactivation condition to stabilize the enzyme activity. Purified ginseng saponin also stabilized the enzyme against heat inactivation.

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Evaluation of devolatilization models in CFD for high-pressure entrained flow coal gasifier (고압 석탄 분류층 가스화기 전산유동에서 탈휘발 모델의 영향 평가)

  • Ye, Insoo;Park, Sangbin;Ryu, Changkook;Park, Hoyoung;Kim, Bongkeun
    • 한국연소학회:학술대회논문집
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    • 2012.04a
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    • pp.37-40
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    • 2012
  • In an entrained flow coal gasifier, predicting the reaction behavior of pulverized coal particles requires detailed information on devolatilization, char gasification, gaseous reactions, turbulence and heat transfer. Among the input parameters, the rate of devolatilization and the composition of volatile species are difficult to determine by experiments due to a high pressure (~40 bar) and temperature (${\sim}1500^{\circ}C$). This study investigates the effect of devolatilization models on the reaction and heat transfer characteristics of a 300 MWe Shell coal gasifier. A simplified devolatilization model and advanced model based on Flashchain were evaluated, which had different volatiles composition and devolatilization rates. It was found that the tested models produce similar flow and reaction trends, but the simplified model slightly over-predict the temperature and wall heat flux near the coal inlets.

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GASIFICATION OF CARBONEOUS WASTES USING THE HIGH TEMPERATURE REFORMER

  • Lee, Dong-Jin
    • Environmental Engineering Research
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    • v.10 no.3
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    • pp.122-130
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    • 2005
  • Gasification of carbonaceous wastes such as shredded tire, waste lubricating oil, plastics, and powdered coal initiates a single-stage reforming reactor(reformer) Without catalyst and a syngas burner. Syngas is combusted with $O_2$ gas in the syngas burner to produce $H_2O\;{and}\;CO_2$ gas with exothermic heat. Reaction products are introduced into the reforming reactor, reaction heat from syngas burner elevates the temperature of reactor above $1,200^{\circ}C$, and hydrogen gas fraction reaches 65% of the product gas output. Reactants and heat necessary for the reaction are provided through the syngas burner only. Neither $O_2$ gas nor steam is injected into the reforming reactor. Multiple syngas burners may be connected to the reforming reactor in order to increase the syngas output, and the product syngas is recycled into syngas burner.