• Journal of the Korean Institute of Gas
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• v.21 no.4
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• pp.21-29
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• 2017

Small and medium industry facility handling hazardous chemicals was inspected and summarized. The inspection results were summarized in four categories such as hazards to process, storage, workers, and the others. The result was applied to further improvement of the facility. In conclusion, the industry intented to satisfy minimum requirement of regulation and they do not pay attention to keep maintaining the facility in integrity condition.

• Fire Protection Technology
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• s.15
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• pp.22-27
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• 1993

The classification of hazardous area is a method of analysing and classifying the environment where explosive gas or vapour atmosphere may be expected to be present. The object of area classification is to enable the proper selection and installation of electical apparatus and other equipments. This report is intended to serve a general reference about the classification procedure of hazardous area with explanations of related Korean Standard.

• Analytical Science and Technology
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• v.34 no.5
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• pp.202-211
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• 2021

Volatile organic compounds (VOCs) in hazardous air pollutants (HAPs) have been regulated by the Air Pollution Control Act (1978) and their atmospheric concentrations have been monitored in 39 monitor sites in Korea. However, measurement standards of volatile organic compounds (VOCs) in HAPs at ambient levels have not been established in Korea. Primary reference gas mixtures (measurement standards) at ambient levels are required for accurately monitoring atmospheric VOCs in HAPs and managing their emissions. In this study, primary reference gas mixtures (PRMs) at 5 nmol/mol were developed in order to establish primary national standards of VOCs in HAPs at ambient levels. Primary reference gas mixtures (PRMs) were prepared in pressurized aluminum cylinders with special internal surface treatment using gravimetric method. Analytical methods using gas chromatography-flame ionization detector (GC-FID) coupled with a cryogenic preconcentrator were also developed to verify the consistency of gravimetrically prepared HAP VOCs PRMs. Three different columns installed in the GC-FID were evaluated and compared for the retention times and separation of eighteen target components in a chromatogram. Results show that the HAP VOCs PRMs at 5 nmol/mol were consistent within a relative expanded uncertainty (k=2) of less than 3 % except acrylonitrile (less than 6 %) and the 18 VOCs were stable for 1 year within their associated uncertainties.

• Journal of the Korean Institute of Gas
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• v.25 no.3
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• pp.39-45
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• 2021

Scrubbers that treat hazardous materials at workplaces have high treatment efficiency; however, the design is complex, and pumps need to be operated 24 hours a day, which can be costly. Therefore, to minimize the operating costs, small businesses do not install scrubbers, or operate them while circulation pumps are suspended. Hence, this study investigated the application of low-cost, high-performance scrubbers that can be used economically in small businesses. Low-cost, high-efficiency scrubbers are applied to bubble columns to utilize devices for hazardous chemical absorption treatment purposes, and for the development of these scrubbers, absorption performance was reviewed and the optimal application method was studied under certain conditions. The changes in the absorption performance of hazardous gas were studied in certain environments by varying the physical conditions, and the optimal application methods were analyzed. The results showed that, while it was possible to treat some of the gas flowing into the low cost, high performance scrubber, the treatment capacity was reduced. Performance degradation was prevented by supplying an absorption liquid, and a certain level of absorption was maintained depending on the amount of circulation. Based on this, three types of site application methods of low cost, high performance scrubbers were presented. In addition, the appropriate timing of circulation and anti freezing measures were also discussed.

• Journal of the Korean Institute of Gas
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• v.21 no.4
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• pp.62-69
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• 2017

Chemical accidents are systematically managed by the Chemicals Control Act. However, the definition and case studies of violent incidents by hazardous chemical substances need to be adequately organized. In this study, we focused on suggesting improvement directions of the legal and institutional system to prevent the violent incidents of hazardous chemical substances by studying the problems of current legislation and drawing up implications through domestic and foreign cases. The suggestions for improvement are as follows: 1) Strengthening prevention through amendment of laws (1) Selection of the competent department; 2) Enforcing regulations on online and offline commerce (1) Setting personal purchase amount; and 3) Increasing public awareness and public education (1) Improvement of the continuous system through the Chemical Evaluation Committee.

• Journal of the Korean Society of Safety
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• v.12 no.4
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• pp.161-168
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• 1997

Most plants producing semiconductors use a lot of chemicals, hazardous materials, and explosive gases. Though those materials are hazardous too much, some works still have to be done manually by human workers. However, according to a historical survey, more than half industrial accidents of those plants resulted from human errors or malfunctions. Thus, this research aimed 1) to diagnose shifting hazardous materials of semiconductor plants, 2) to estimate failure probability of human workers through human reliability analysis, and 3) to find out the tasks on which educational emphasis should be put. Through personal interview and visiting working spots, shifting tasks were analyzed, and modelled into a 24-step work, and after that, THERP and ETA was applied. During the shifting work, estimated human failure probability under the assumption of independency, 2.3004E-05, underestimated that probability 8. l008E-05 which could be calculated under the assumption of dependency. And this analysis showed that gas leakage from an old cylinder occupies 78.27% in the case of independent failures whereas gas leakage from a new cylinder occupies 75.06% in the case of dependent failures. So it was concluded that dependency assumption may gloss real situations. In addition, confirming gauge of regulators and closing valves turned out to be the most important tasks than purge tasks.

• Journal of the Korean Society of Safety
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• v.29 no.6
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• pp.68-75
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• 2014

It is very important to classify explosion hazardous area (EHA) suitably and to use proper explosion-proof electric installations for facilities using flammable gases and liquids. In the past, various examples in the Notification of Ministry of Employment and Labor were referred to in classifying EHA. But, at present, many companies use the hypothetical volume in Korean Standards (KS). This study reviews the validity of EHA classification based on the hypothetical volume by comparing the calculated radii of EHA with those obtained by a consequence analysis program called PHAST and a mathematical approach in British Standards (BS). The radii of EHA by the hypothetical volume were found to be slightly larger than those by the other two methods. This was attributed to rather conservative uses of a safety factor(k) and a correction factor(f) for availability of ventilation in calculating the hypothetical volume. Since the differences are not so conspicuous, however, it is concluded that the hypothetical volume in KS is a valid means for the classification of EHA. This study also presents a table of the radii of EHA for easy reference by small-scale companies using city gas, C3-LPG and flammable liquid(toluene), respectively. The table consists of 25 leakage scenarios corresponding to combinations of 5 pipe(nozzle) sizes and 5 operating conditions for each flammable gas and liquid.

• Journal of Korean Society for Atmospheric Environment
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• v.29 no.6
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• pp.801-810
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• 2013

A field study was conducted to evaluate air quality from gas stations with and without Stage II vapor recovery systems that are currently used to reduce VOCs. The THC and VOCs levels were monitored for the test at three locations (inside office, around refueling area, site boundary) from a total of five gas stations. The results showed a considerable reduction in THC concentration which ranged from 48.7% to 81.8% with and without the operation of the Stage II VRS. Acoording to our comparative analysis, BTEX and other 19 VOCs levels were also significantly reduced with Stage II vapor recovery systems.

• Journal of the Korea Safety Management & Science
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• v.19 no.2
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• pp.31-39
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• 2017

Classify of explosion hazardous areas must be made at the site where flammable materials are used. This reason is that it is necessary to manage ignition sources in of explosion hazardous areas in order to reduce the risk of explosion. If such an explosion hazard area is widened, it becomes difficult to increase the number of ignition sources to be managed. The method using the virtual volume currently used is much wider than the result using CFD(Computational Fluid Dynamics). Therefore, we tried to improve the current method to compare with the new method using leakage characteristics. The result is a realistic explosion hazard if the light gas is calibrated to the mass and the heavy gas is calibrated to the lower explosion limit. However, it is considered that the safety factors should be taken into account in the calculated correction formula because such a problem should be considered as a buffer for safety.

• Journal of the Korean Institute of Gas
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• v.20 no.3
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• pp.59-65
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• 2016

It is imperative to use suitable explosion proof equipments to prevent explosion in different gas facilities. There is no technical standard for the classification of hazardous areas though standard of explosion proof is regulated. In this study, we have adopted Industrial Standard KS to develop the methodology for the prediction of the explosion risk in the natural gas facility with low pressure using the important factors including hole size, hypothetical volume, validation of ventilation effectiveness. The applicability of the developed methodology was evaluated by the comparison with the data obtained from experiments of natural gas explosion.