• Title/Summary/Keyword: Hard template

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Fabrication of Mesoporous Carbon from Polyvinylidene Chloride(PVDC)-resin Precursor with Mg(OH)2 Template for Supercapacitor Electrode (슈퍼 커패시터용 전극을 위한 Polyvinylidene chloride(PVDC)-resin과 Mg(OH)2 템플릿으로부터 메조기공 탄소의 제조)

  • Hwang, Beodl;Chun, Sang-Eun
    • Journal of the Korean institute of surface engineering
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    • v.52 no.6
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    • pp.326-333
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    • 2019
  • The microporous carbon derived from PVDC-resin by a simple heat-treatment under an inert atmosphere exhibits a reasonable specific capacitance for a supercapacitor's electrode. However, the capacitance was rapidly decreased at high charge/discharge rate. The micropores present in an electrode surface hinder the entrance of an electrolyte ion onto the entire surface. To induce the meso-sized pores during the carbonization of PVDC-resin, Mg(OH)2 was utilized as a hard template. The porous carbon made from the mixture of PVD-Cresin and Mg(OH)2 include mesopores as well as micropores. The induced mesopores does not homogeneously distributed on the entire surface of the synthesized carbon. The PVDC-resin and Mg(OH)2 are dissolved in the dimethylformamide for the hard template to evolve the pores on the synthesized carbon uniformly. The carbon made from PVDC-resin with solvent and a hard template contains mostly mesopores resulting in the high power performance. The reduced amount of solvent in the precursor derives the carbon with high specific surface area and high power density.

Preparation of Micro-/Macroporous Carbons and Their Gas Sorption Properties

  • Hwang, Yong-Kyung;Shin, Hye-Seon;Hong, Jin-Yeon;Huh, Seong
    • Bulletin of the Korean Chemical Society
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    • v.35 no.2
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    • pp.377-382
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    • 2014
  • Micro-/macroporous carbons (MMCs) were prepared using a hollow mesoporous silica capsule (HMSC) as a sacrificial hard template. The carbonization process after the infiltration of furfuryl alcohol into the template-free HMSC material afforded MMC materials in high yield. The hard template HMSC could be removed by HF etching without deteriorating the structure of MMC. The MMC materials were fully characterized by SEM, TEM, PXRD, XPS, and Raman spectroscopy. The replication processes were so successful that MMCs exhibited a hollow capsular structure with multimodal microporosity. Detailed textural properties of MMC materials were investigated by volumetric $N_2$ adsorption-desorption analysis at 77 K. To explore the gas sorption abilities of MMCs for other gases, $H_2$ and $CO_2$ sorption analyses were also performed at various temperatures. The multimodal MMC materials were found to be good sorbents for both $H_2$ and $CO_2$ at low pressure.

An Approximation Algorithm based on First-fit Strategy for Template Packing Problem (First-fit 전략을 사용하는 템플럿 패킹 문제를 위한 근사 알고리즘)

  • Song, Ha-Joo;Kwon, Oh-Heum
    • Journal of Korea Multimedia Society
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    • v.19 no.2
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    • pp.443-450
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    • 2016
  • This paper deals with a kind of packing problem of which the goal is to compose one or more templates which will be used to produce the items of different types. Each template consists of a fixed number of slots which are assigned to the different types of items and the production of the items is accomplished by printing the template repeatedly. The objective is to minimize the total number of produced items. This problem is known to be NP-hard. We present a polynomial time approximation algorithm which has a constant approximation ratio. The proposed algorithm is based on the well-known first-fit strategy.

Versatile Strategies for Fabricating Polymer Nanomaterials with Controlled Size and Morphology

  • Yoon, Hyeon-Seok;Choi, Moon-Jung;Lee, Kyung-Jin;Jang, Jyong-Sik
    • Macromolecular Research
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    • v.16 no.2
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    • pp.85-102
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    • 2008
  • The development of reliable synthetic routes to polymer nanomaterials with well-defined size and morphology is a critical research topic in contemporary materials science. The ability to generate nanometer-sized polymer materials can offer unprecedented, interesting insights into the physical and chemical properties of the corresponding materials. In addition, control over shape and geometry of polymer nanoparticles affords versatile polymer nanostructures, encompassing nanospheres, core-shell nanoparticles, hollow nanoparticles, nanorods/fibers, nanotubes, and nanoporous materials. This review summarizes a diverse range of synthetic methods (broadly, hard template synthesis, soft template synthesis, and template-free synthesis) for fabricating polymer nanomaterials. The basic concepts and significant issues with respect to the synthetic strategies and tools are briefly introduced, and the examples of some of the outstanding research are highlighted. Our aim is to present a comprehensive review of research activities that concentrate on fabrication of various kinds of polymer nanoparticles.

Fabrication of Nanopatterned PDMS Elastic Stamp Mold Using Surface Treatment of Nanotemplate (나노템플레이트 표면처리를 통한 나노패턴이 형성된 PDMS 탄성 스탬프 몰드 제작)

  • Park, Yong Min;Seo, Sang Hyun;Seo, Young Ho;Kim, Byeong Hee
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.24 no.1
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    • pp.38-42
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    • 2015
  • Polydimethylsiloxane (PDMS) is a widely used material for replicating micro-structures because of its transparency, deformability, and easy fabrication. At the nanoscale, however, it is hard to fill a nanohole template with uncured PDMS. This paper introduces several simple methods by changing the surface energy of a nanohole template and PDMS elastomer for replicating 100nm-scale structures. In the case of template, pristine anodic aluminum oxide (AAO), hydrophobically treated AAO, and hydrophillically treated AAO are used. For the surface energy change of the PDMS elastomer, a hydrophilic additive and dilution solvent are added in the PDMS prepolymer. During the molding process, a simple casting method is used for all combinations of the treated template and modified PDMS. The nanostructured PDMS surface was investigated with a scanning electron microscope after the molding process for verification.

Preparation of Mesoporous SiCBN Ceramic Templated by Mesoporous Carbon

  • Nghiem, Quoc Dat;Ryoo, Hyang-Im;Kim, Dong-Pyo
    • Journal of the Korean Ceramic Society
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    • v.44 no.7
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    • pp.358-361
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    • 2007
  • Well-ordered mesoporous SiCBN ceramics have been successfully synthesized by infiltrating a polymeric precursor, which was prepared from borazine and 2,4,6-trimethyl-2,4,6-trivinylcyclotrisilazane via a hydroboration reaction, into a mesoporous carbon (CMK-3) as a hard template. This was followed by pyrolysis at $1400^{\circ}C$ under nitrogen gas and subsequent oxidative removal of the carbon template without chemical etching. The prepared mesoporous SiCBN ceramic was characterized by a small-angle XRD, TEM, and BET surface area. The resulting mesoporous SiCBN ceramic revealed a BET surface area of $275 m^2g^{-1}$ and a pore volume of $0.8 cm^3 g$ with no crystallization.

A Secure Decentralized Storage Scheme of Private Information in Blockchain Environments

  • Han, Seungjin
    • Journal of the Korea Society of Computer and Information
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    • v.23 no.1
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    • pp.111-116
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    • 2018
  • Recently, IoT and Big Data dealing with voluminous and complex sensitive information is one of the key issues in the era of the 4th industrial revolution. There have been a lot of studies to store the collected and processed sensitive information safely in storage data. Especially biometric information, if it is leaked and becomes identity theft, is hard to be corrected and results in serious event. To fix the problem, methods such as FIDO or KFTC have been proposed. In this paper, we propose a modified method of TTAK.KO-12.0098 according to the environment of this paper and propose a method of safely storing the generated disposable template in a block chain. We show that our method is better by comparing the existing method and the security analysis.

A Template-based Interactive University Timetabling Support System (템플릿 기반의 상호대화형 전공강의시간표 작성지원시스템)

  • Chang, Yong-Sik;Jeong, Ye-Won
    • Journal of Intelligence and Information Systems
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    • v.16 no.3
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    • pp.121-145
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    • 2010
  • University timetabling depending on the educational environments of universities is an NP-hard problem that the amount of computation required to find solutions increases exponentially with the problem size. For many years, there have been lots of studies on university timetabling from the necessity of automatic timetable generation for students' convenience and effective lesson, and for the effective allocation of subjects, lecturers, and classrooms. Timetables are classified into a course timetable and an examination timetable. This study focuses on the former. In general, a course timetable for liberal arts is scheduled by the office of academic affairs and a course timetable for major subjects is scheduled by each department of a university. We found several problems from the analysis of current course timetabling in departments. First, it is time-consuming and inefficient for each department to do the routine and repetitive timetabling work manually. Second, many classes are concentrated into several time slots in a timetable. This tendency decreases the effectiveness of students' classes. Third, several major subjects might overlap some required subjects in liberal arts at the same time slots in the timetable. In this case, it is required that students should choose only one from the overlapped subjects. Fourth, many subjects are lectured by same lecturers every year and most of lecturers prefer the same time slots for the subjects compared with last year. This means that it will be helpful if departments reuse the previous timetables. To solve such problems and support the effective course timetabling in each department, this study proposes a university timetabling support system based on two phases. In the first phase, each department generates a timetable template from the most similar timetable case, which is based on case-based reasoning. In the second phase, the department schedules a timetable with the help of interactive user interface under the timetabling criteria, which is based on rule-based approach. This study provides the illustrations of Hanshin University. We classified timetabling criteria into intrinsic and extrinsic criteria. In intrinsic criteria, there are three criteria related to lecturer, class, and classroom which are all hard constraints. In extrinsic criteria, there are four criteria related to 'the numbers of lesson hours' by the lecturer, 'prohibition of lecture allocation to specific day-hours' for committee members, 'the number of subjects in the same day-hour,' and 'the use of common classrooms.' In 'the numbers of lesson hours' by the lecturer, there are three kinds of criteria : 'minimum number of lesson hours per week,' 'maximum number of lesson hours per week,' 'maximum number of lesson hours per day.' Extrinsic criteria are also all hard constraints except for 'minimum number of lesson hours per week' considered as a soft constraint. In addition, we proposed two indices for measuring similarities between subjects of current semester and subjects of the previous timetables, and for evaluating distribution degrees of a scheduled timetable. Similarity is measured by comparison of two attributes-subject name and its lecturer-between current semester and a previous semester. The index of distribution degree, based on information entropy, indicates a distribution of subjects in the timetable. To show this study's viability, we implemented a prototype system and performed experiments with the real data of Hanshin University. Average similarity from the most similar cases of all departments was estimated as 41.72%. It means that a timetable template generated from the most similar case will be helpful. Through sensitivity analysis, the result shows that distribution degree will increase if we set 'the number of subjects in the same day-hour' to more than 90%.

Modal Parameter Extraction Using a Digital Camera (디지털 카메라를 이용한 구조물의 동특성 추출)

  • Kim, Byeong-Hwa
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2008.11a
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    • pp.61-68
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    • 2008
  • A set of modal parameters of a stay-cable have been extracted from a moving picture captured by a digital camera supported by shaking hands. It is hard to identify the center of targets attached on the cable surface from the blurred cable motion image, because of the high speed motion of cable, low sampling frequency of camera, and the shaking effect of camera. This study proposes a multi-template matching algorithm to resolve such difficulties. In addition, a sensitivity-based system identification algorithm is introduced to extract the natural frequencies and damping ratios from the ambient cable vibration data. Three sets of vibration tests are conducted to examine the validity of the proposed algorithms. The results show that the proposed technique is pretty feasible for extracting modal parameters from the severely shaking motion pictures.

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Fabrication of Hollow Metal Microcapsules with Mesoporous Shell Structure: Application as Efficient Catalysts Recyclable by Simple Magnetic Separation

  • Jang, Da-Young;Jang, Hyung-Gyu;Kim, Gye-Ryung;Kim, Geon-Joong
    • Bulletin of the Korean Chemical Society
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    • v.32 no.9
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    • pp.3274-3280
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    • 2011
  • Monodispersed porous NiO and $Co_3O_4$ microcapsules with a hollow core were synthesized using SBA-16 silica sol and PS as a hard template. The porous hollow microcapsules were characterized by XRD, TEM and $N_2$ adsorption/desorption analysis. After $H_2$ reduction of metal oxide microspheres, they were conducted as an active catalyst in the reduction of chiral butylronitrile and cyanobenzene. The mesoporous metals having a hollow structure showed a higher activity than a nonporous metal powder and an impregnated metal on the carbon support.