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http://dx.doi.org/10.5012/bkcs.2014.35.2.377

Preparation of Micro-/Macroporous Carbons and Their Gas Sorption Properties  

Hwang, Yong-Kyung (Department of Chemistry and Protein Research Center for Bio-Industry, Hankuk University of Foreign Studies)
Shin, Hye-Seon (Department of Chemistry and Protein Research Center for Bio-Industry, Hankuk University of Foreign Studies)
Hong, Jin-Yeon (Department of Chemistry and Protein Research Center for Bio-Industry, Hankuk University of Foreign Studies)
Huh, Seong (Department of Chemistry and Protein Research Center for Bio-Industry, Hankuk University of Foreign Studies)
Publication Information
Bulletin of the Korean Chemical Society / v.35, no.2, 2014 , pp. 377-382 More about this Journal
Abstract
Micro-/macroporous carbons (MMCs) were prepared using a hollow mesoporous silica capsule (HMSC) as a sacrificial hard template. The carbonization process after the infiltration of furfuryl alcohol into the template-free HMSC material afforded MMC materials in high yield. The hard template HMSC could be removed by HF etching without deteriorating the structure of MMC. The MMC materials were fully characterized by SEM, TEM, PXRD, XPS, and Raman spectroscopy. The replication processes were so successful that MMCs exhibited a hollow capsular structure with multimodal microporosity. Detailed textural properties of MMC materials were investigated by volumetric $N_2$ adsorption-desorption analysis at 77 K. To explore the gas sorption abilities of MMCs for other gases, $H_2$ and $CO_2$ sorption analyses were also performed at various temperatures. The multimodal MMC materials were found to be good sorbents for both $H_2$ and $CO_2$ at low pressure.
Keywords
Porous materials; Microporous carbon; Macroporous carbon; Hydrogen adsorption; Carbon dioxide adsorption;
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1 Brun, N.; Prabaharan, S. R. S.; Surcin, C.; Morcrette, M.; Deleuze, H.; Birot, M.; Babot, O.; Achard, M.-F.; Backov, R. J. Phys. Chem. C 2012, 116, 1408.   DOI
2 Dresselhaus, M. S.; Jorio, A.; Hofmann, M.; Dresselhaus, G.; Saito, R. Nano Lett. 2010, 10, 751.   DOI   ScienceOn
3 Gu, J.-M.; Kim, W.-S.; Hwang, Y.-K.; Huh, S. Carbon 2013, 56,208.   DOI
4 Gu, J.-M.; Kwon, T.-H.; Park, J.-H.; Huh, S. Dalton Trans. 2010,39, 5608.   DOI
5 Tamai, H.; Kakii, T.; Hirota, Y.; Kumamoto, T.; Yasuda, H. Chem. Mater. 1996, 8, 454.   DOI   ScienceOn
6 Sumida, K.; Rogow, D. L.; Mason, J. A.; McDonald, T. M.; Bloch, E. D.; Herm, Z. R.; Bae, T. H.; Long, J. R. Chem. Rev. 2012, 112,724.   DOI   ScienceOn
7 Zhao, Z.; Li, Z.; Lin, Y. S. Ind. Eng. Chem. Res. 2009, 48, 10015.   DOI   ScienceOn
8 Stein, A.; Wang, Z.; Fierke, M. A. Adv. Mater. 2009, 21, 265.   DOI
9 Ramasamy, E.; Lee, J. Chem. Commun. 2010, 46, 2136.   DOI
10 Hao, G.-P.; Li, W.-C.; Qian, D.; Wang, G.-H.; Zhang, W.-P.; Zhang, T.; Wang, A.-Q.; Schuth, F.; Bongard, H.-J.; Lu, A.-H. J. Am. Chem. Soc. 2011, 133, 11378.   DOI
11 Wang, Z.; Zhang, X.; Liu, X.; Lv, M.; Yang, K.; Meng, J. Carbon 2011, 49, 161.   DOI
12 Yoon, S. B.; Sohn, K.; Kim, J. Y.; Shin, C.-H.; Yu, J.-S.; Hyeon, T. Adv. Mater. 2002, 14, 19.   DOI   ScienceOn
13 Fuertes, A. B.; Valle-Vigon, P.; Sevilla, M. Chem. Commun. 2012,48, 6124.   DOI
14 Lu, A.-H.; Hao, G.-P.; Sun, Q. Angew. Chem. Int. Ed. 2011, 50,9023.   DOI
15 Lu, A.-H.; Sun, T.; Li, W.-C.; Sun, Q.; Han, F.; Liu, D.-H.; Guo, Y. Angew. Chem. Int. Ed. 2011, 50, 11765.   DOI
16 Lim, J.-S.; Lee, K.; Choi, J.-N.; Hwang, Y.-K.; Yun, M.-Y.; Kim, H.-J.; Won, Y. S.; Kim, S.-J.; Kwon, H.; Huh, S. Nanotechnology 2012, 23, 085101.   DOI
17 Hwang, Y.-K.; Choi, J.-N.; Cho, J.-H.; Kwon, H.; Huh, S. Eur. J. Inorg. Chem. 2012, 3379.
18 Ryoo, R.; Joo, S. H.; Jun, S. J. Phys. Chem. B 1999, 103, 7743.   DOI   ScienceOn
19 Texier-Mandoki, N.; Dentzer, J.; Piquero, T.; Saadallah, S.; David, P.; Vix-Guterl, C. Carbon 2004, 42, 2735.   DOI   ScienceOn
20 Brun, N.; Prabaharan, S. R. S.; Morcrette, M.; Sanchez, C.; Pecastaings, G.; Derre, A.; Soum, A.; Deleuze, H.; Birot, M.; Backov, R. Adv. Funct. Mater. 2009, 19, 3136.   DOI   ScienceOn
21 Kwon, T.-H.; Jung, S.; Kim, H.-J.; Park, S.; Kim, S.-J.; Huh, S. Eur. J. Inorg. Chem. 2009, 2811.
22 Joo, S. H.; Choi, S. J.; Oh, I.; Kwak, J.; Liu, Z.; Terasaki, O.; Ryoo, R. Nature 2001, 412, 169.   DOI   ScienceOn
23 Liu, L.; Deng, Q.-F.; Hou, X.-X.; Yuan, Z.-Y. J. Mater. Chem. 2012, 22, 15540.   DOI