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Synthesis and Characterization of ZnS and ZnS/TiO2 Nanocomposites and Their Enhanced Photo-decolorization of MB and 1,5-Diphenyl Carbazide

  • Meng, Ze-Da;Ullah, Kefayat;Zhu, Lei;Ye, Shu;Oh, Won-Chun
    • Journal of the Korean Ceramic Society
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    • v.51 no.4
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    • pp.307-311
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    • 2014
  • ZnS and $ZnS/TiO_2$ were prepared by chemical deposition. The prepared photocatalysts were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray (EDX), and transmission electron microscopy (TEM). The generation of reactive oxygen species was detected by monitoring the oxidation reaction from 1,5-diphenyl carbazide (DPCI) to 1,5-diphenyl carbazone (DPCO). Excellent catalytic degradation of methylene blue (MB) solution was observed using the $ZnS/TiO_2$ composites during irradiation with visible light. The results show that the photocatalytic performance of $TiO_2$ nanoparticles is improved by loading with ZnS.

Synthesis and Characterization of a Ternary Nanocomposite Based on CdSe Decorated Graphene-TiO2 and its Application in the Quantitative Analysis of Alcohol with Reduction of CO2

  • Ali, Asghar;Biswas, Md Rokon Dowla;Areerob, Yonrapach;Nguyen, Dinh Cung Tien;Oh, Won-Chun
    • Journal of the Korean Ceramic Society
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    • v.55 no.4
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    • pp.381-391
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    • 2018
  • In this work, photocatalytic $CO_2$ reduction over a CdSe-graphene-$TiO_2$ nanocomposite has been studied. The obtained material was successfully fabricated via ultrasonic technique. The physical properties of the as-synthesized materials were characterized by some physical techniques. The $TiO_2$ and CdSe dispersed graphene nanocomposite showed excellent results of strong reduction rates of $CO_2$ compared to the results of bare $TiO_2$ and binary CdSe-graphene. An outstanding point of the combination of CdSe-$TiO_2$ and graphene appeared in the form of great photocatalytic reduction capability of $CO_2$. The photocatalytic activity of the asfabricated composite was tested by surveying for the photoreduction of $CO_2$ to alcohol under UV and visible light irradiation, and the obtained results imply that the as-prepared CdSe-graphene-$TiO_2$ nanocomposite is promising to become a potential candidate for the photocatalytic $CO_2$ reduction.

Visible Light Photoelectrocatalytic Properties of Novel Yttrium Treated Carbon Nanotube/Titania Composite Electrodes

  • Zhang, Feng-Jun;Chen, Ming-Liang;Zhang, Kan;Oh, Won-Chun
    • Bulletin of the Korean Chemical Society
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    • v.31 no.1
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    • pp.133-139
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    • 2010
  • Photoelectrocatalytic decolorization of methlene blue (MB) in the presence of two types of carbon nanotube/titania and yttrium-treated carbon nanotube/titania electrodes in aqueous solutions were studied under visible light. The prepared composite electrodes were characterized by X-ray diffraction, transmission and scanning electron microscopy, energy dispersive X-ray analysis, and photoelectrocatalytic activity. The photoelectrocatalytic performances of the supported catalysts were evaluated for the decolorization of MB solution under visible light irradiation. The results showed that yttrium incorporation enhanced the decolorization rate of MB. It was found that the photoelectrocatalytic degradation of a MB solution could be attributed to the combined effects caused by the photo-degradation of titania, the electron assistance of carbon nanotube network, the enhancement of yttrium and a function of the applied potential. The repeatability of photocatalytic activity was also tested. The presence of yttrium enhanced the hydrophillicity of yttrium-carbon nanotubes/titania electrode because more OH groups can be adsorbed on the surface.

Synthesis and Characterization of Calcium Derivative Combined with High-Surface-Area Activated Carbon Composites for Fine Toxic Gas Removal

  • Areerob, Yonrapach;Nguyen, Dinh Cung Tien;Dowla, Biswas Md Rokon;Kim, Hyuk;Cha, Je-Woo;Oh, Won-Chun
    • Journal of the Korean Ceramic Society
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    • v.55 no.5
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    • pp.473-479
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    • 2018
  • Highly toxic gases such as hydrogen sulfide ($H_2S$), carbon dioxide ($CO_2$), and ammonia ($NH_3$) are generated by both nature and human activities and affect human health. In this research, activated carbon combined with $Ca(OH)_2$ and $CaCO_3$ (AC-CO and AC-CC, respectively) were fabricated and applied in absorbing toxic gases from air pollutants. Activated charcoal powder was compressed in the form of pellets and used in the designated conditions. The optimum operating conditions and material properties, such as adsorption capacity, effect of weight ratio of the mixture, and hardness, have been investigated after combining with the calcium derivative. The good performance exhibited in this study suggests that this material is expected to be an effective and economically viable adsorbent for $NH_3$, $CO_2$, and $H_2S$ removal from the air system.

Feasibility Study for College of Medicine Establishment in Western Region of Chungcheongnam-do (충청남도 서부권 의과대학 설립에 대한 타당성 연구)

  • Kim, Jeong-Koo;Lee, Young-Shin;Kim, Woong-Yi;Yi, Jin-Bok
    • Journal of radiological science and technology
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    • v.43 no.4
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    • pp.289-295
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    • 2020
  • This study investigated the feasibility of establishing a college of medicine in the western region of Chungnam to fill the gap in the medical doctor in charge of essential medical care in the region. Currently, the level of medical services in Chungnam is low compared to provinces across the country and in particular, 7 cities and towns, which account for 760,000 people, one-third of Chungnam's population, are located in the western regions of Chungnam. Because of this, in the event of an emergency patients, it is necessary to travel to Cheonan, Daejeon, Seoul, etc. where the regional emergency medical center is located for more than 1 hour and 30 minutes. In the case of critically ill and emergency patients transfer, it is a situation that misses the golden time and causes valuable loss of life. In order to improve the medical environment in the western region of Chungnam and improve the lives of residents in vulnerable areas of medical services, it is believed that establishing a college of medicine in the western region of Chungnam is essential.

Preparation of CdS-AC/TiO2 Composites Designed for a High Photonic Effect and their Photocatalytic Activity Under Visible Light

  • Park, Chong-Yeon;Choi, Jong-Geun;Ghosh, Trisha;Oh, Won-Chun
    • Journal of the Korean Ceramic Society
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    • v.48 no.5
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    • pp.433-438
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    • 2011
  • In this study, CdS combined activated carbon/$TiO_2$ (CdS-AC/$TiO_2$) composites were prepared by a sol-gel method to improve the photocatalytic performance of $TiO_2$. These composites were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDX) and UV-vis analysis. The photocatalytic activities were examined by the degradation of methylene blue (MB) under visible light irradiation. The photodegradation rate of MB under visible light irradiation reached 90.1% in 120 min. The kinetics of MB degradation was plotted alongside the values calculated from the Langmuir-Hinshelwood equation. The 0.2 CAT sample showed the best photocatalytic activity, which might be due to an increase in the photo-absorption effect by activated carbon and the cooperative effect of CdS.

Two Cases of Patients with Migraine Recovered by Trigger Point Treatment (편두통(偏頭痛)에 아시혈요법(阿是穴療法)을 응용(應用)한 치험(治驗) 2례(例))

  • Han, Sung-Su;An, Chun-Jae;Seo, Jong-Eun;Lee, Geun-Dong
    • The Journal of Internal Korean Medicine
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    • v.22 no.3
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    • pp.443-452
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    • 2001
  • A migraine is a recurrent, throbbing headache generally felt on one side of the head. Migraines usually begin in early childhood, adolescence, or young adult life. Its accurate pathogenesis is still unknown but migraines are caused by a rapid widening and narrowing of blood vessel walls in the brain and head. The classic migraine and the common migraine are the two main types. The onset of classical migraine may be signalled by visual disturbances in what is called the 'aura' stage. Visual aura is most common among the auras of classical migraine. Common migraine (or migraine without aura) and classical migraine may be accompanied by various combinations of symptoms such as nausea, vomiting, and sensitivity to light and sound. Recently we have exprienced 2 cases of migraine patients and whose conditions were improved through trigger point needling and Oriental medical treatment.

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Optimization of synthesis conditions and $CO_2$ capture capability of Cu-BTC Metal-Organic Framework (이산화탄소 흡착용 Cu-BTC MOF 합성 최적화)

  • Peng, Mei Mei;Hemalatha, Pushparaj;Ganesh, Mani;Jang, Hyun-Tae
    • Proceedings of the KAIS Fall Conference
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    • 2011.12a
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    • pp.200-203
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    • 2011
  • A copper-based metal organic framework (MOF) named Cu-BTC, also known as HKUST-1, was synthesized by using a solvothermal method at various synthesis temperature, time and pressure. The obtained samples were characterized with Powder X-ray diffraction (XRD) for phase structure, scanning electron microscopy (SEM) for crystal structure, and nitrogen adsorption-desorption for pore textural structure. The Cu-BTC sample was also studied for $CO_2$ adsorption. The analysis results displayed that the sample synthesized at the condition of temperature: $120^{\circ}C$, synthesis time: 12 hours, pressure: 1 bar exhibited a good crystal structure with uniform size of octahedral particles. The BET data revealed a high surface area of 1741.7 $m^2g^{-1}$ and a pore volume of 0.7137 $cm^3g^{-1}$and exhibiteda maximum $CO_2$ adsorption capacity of 170 mg/g of the sorbent at $25^{\circ}C$.

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The effect of dental treatment using conscious sedation therapy on patient satisfaction (의식하진정요법을 이용한 치과치료가 치과치료 만족도에 미치는 영향)

  • Eun-Hye Kim;Sung-Suk Bae;Mi-Ra Lee;Soo-Kyung Jun;Min-Kyung Kang
    • Journal of Korean society of Dental Hygiene
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    • v.24 no.4
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    • pp.353-360
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    • 2024
  • Objectives: This study aimed to investigate the effects of conscious sedation on patient satisfaction with dental treatment. Methods: The survey included questions on the patients' general characteristics, dental treatment fear, anxiety, and satisfaction, and patient evaluation by an observer. Statistical analyses were performed using SPSS 20.0 ver. and data were analyzed using frequency analysis, independent t-test, Pearson's correlation coefficient, and multilinear regression analysis. Results: Patients who received conscious sedation therapy showed significantly lower levels of dental fear and anxiety, whereas their dental treatment satisfaction was significantly higher than that of patients who received regular dental treatment (p<0.05). Dental treatment fear, anxiety, satisfaction, and conscious sedation depth were significantly correlated in patients who received conscious sedation therapy (p<0.05). Factors influencing dental treatment satisfaction included age, weight, use of medication, smoking habits, use of conscious sedation therapy, dental treatment fear and anxiety, and conscious sedation depth (p<0.05). Conclusions: Conscious sedation therapy can be an effective method to reduce dental treatment fear and anxiety and improve patient satisfaction.

Influence of SiO2 Content on Wet-foam Stability for Creation of Porous Ceramics

  • Bhaskar, Subhasree;Park, Jung Gyu;Cho, Gae Hyung;Seo, Dong Nam;Kim, Ik Jin
    • Journal of the Korean Ceramic Society
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    • v.51 no.5
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    • pp.511-515
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    • 2014
  • The thermodynamic instability of bubbles in wet-foam colloidal suspension is due to the substantial area of their gas/liquid interface. Several physical processes lead to gas diffusion from smaller to larger bubbles, resulting in a coarsening and Ostwald ripening of wet foam. This includes a narrowing of the bubble size distribution. The distribution and microstructure of porous ceramics, the adsorption free energy and Laplace pressure of $Al_2O_3$ particle-stabilized colloidal suspension, and $SiO_2$ content were investigated for tailoring the bubble size. Wet-foam stability of more than 80% is related to the degree of hydrophobicity with contact angles of $62-70^{\circ}$ achieved from the surfactant. The contact angle replaces part of the highly energetic interface and lowers the free energy of the system. This leads to an apparent increase in the surface tension (26-33 mN/m) of the colloidal suspension.