Browse > Article
http://dx.doi.org/10.4191/kcers.2011.48.5.433

Preparation of CdS-AC/TiO2 Composites Designed for a High Photonic Effect and their Photocatalytic Activity Under Visible Light  

Park, Chong-Yeon (Department of Advanced Materials & Science Engineering, Hanseo University)
Choi, Jong-Geun (Department of Advanced Materials & Science Engineering, Hanseo University)
Ghosh, Trisha (Department of Advanced Materials & Science Engineering, Hanseo University)
Oh, Won-Chun (Department of Advanced Materials & Science Engineering, Hanseo University)
Publication Information
Abstract
In this study, CdS combined activated carbon/$TiO_2$ (CdS-AC/$TiO_2$) composites were prepared by a sol-gel method to improve the photocatalytic performance of $TiO_2$. These composites were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDX) and UV-vis analysis. The photocatalytic activities were examined by the degradation of methylene blue (MB) under visible light irradiation. The photodegradation rate of MB under visible light irradiation reached 90.1% in 120 min. The kinetics of MB degradation was plotted alongside the values calculated from the Langmuir-Hinshelwood equation. The 0.2 CAT sample showed the best photocatalytic activity, which might be due to an increase in the photo-absorption effect by activated carbon and the cooperative effect of CdS.
Keywords
Activated carbon photocatalysis; $TiO_2$; CdS; Methylene blue; Visible light;
Citations & Related Records

Times Cited By SCOPUS : 0
연도 인용수 순위
  • Reference
1 H. L. Su, Y. Xie, P. Gao, Y. J. Xiong, and Y. T. Qian, "Synthesis of $MS/TiO_2$(M = Pb, Zn, Cd) Nanocomposites Through a Mild Sol-gel Process," Mater. Chem., 11 684 (2001).   DOI
2 K. H. Yoon, J. Cho, and D. H. Kang, "Physical and Photoelectrochemical Properties of the $TiO_2-ZnO$ System," Mater. Res. Bull., 34 1451 (1999).   DOI
3 V. Stengl, S. Bakardjieva, N. Murafa, V. Hou kova, and K. Lang, "Visible-light Photocatalytic Activity of $TiO_2/ZnS$ Nanocomposites Prepared by Homogeneous Hydrolysis," Micropor. Mesopor. Mater., 110 370 (2008).   DOI   ScienceOn
4 M. Romero, J. Blanco, B. Sanchez, A. Vidal, S. Malato, A.I. Cardona, and E. Garcia, "Solar Photocatalytic Degradation of Water and Air Pollutants : Challenges and Perspectives," Solar Energy, 66 169 (1999).   DOI
5 J. H. Liu, R. Yang, and S. M. Li, "Preparation and Application of Efficient $TiO_2$ /ACFs Photocatalyst," J. Environ. Sci., 18 979 (2006).   DOI
6 A. H. El-Sheikh, A. P. Newman, H. Al-Daffaee, S. Phull, N. Cresswell, and S. York, "Deposition of Anatase on the Surface of Activated Carbon," Surf. Coat. Technol., 187 284 (2004).   DOI
7 J. Arana, E. Tello Rendon, J.M. Dona Rodriguez, C. Garriga i Cabo, O. Gonzalez Diaz, J.A. Herrera Melian, and J. Perez Pena. "$TiO_2$ Activation by Using Activated Carbon as a Support Part I. Surface Characterisation and Decantability Study,"Appl. Catal. B Environ., 44 161 (2003).   DOI
8 P. Dwivedi, V. Gaur, A. Sharma, and N. Verma, "Comparative Study of Removal of Volatile Organic Compounds by Cryogenic Condensation and Adsorption by Activated Carbon Fiber," Sep. Purif. Technol., 39 23 (2004).   DOI   ScienceOn
9 T. Guo, Z. P. Bai, C. Wu, and T. Zhu, "Influence of Relative Humidity on the Photocatalytic oxidation (PCO) of Toluene by $TiO_2$ Loaded on Activated Carbon Fibers: PCO Rate and Intermediates Accumulation," Appl. Catal. B: Environ., 79 171 (2008).   DOI
10 R. S. Yuan, J. T. Zheng, R. B. Guan, and Y. C. Zhao, "Surface Characteristics and Photocatalytic Activity of $TiO_2$ Loaded on Activated Carbon Fibers," Colloids Surf. A, 254 131 (2005).   DOI
11 H. Yamashita, M. Harada, A. Tanii, and M. Honda, "Preparation of Efficient Titanium Oxide Photocatalysts by an Ionized Cluster Beam (ICB) Method and their Photocatalytic Reactivities for the Purification of Water," Catal. Today, 63 63 (2000).   DOI
12 W. W. So, K. J. Kim, and S. J. Moon, "Photo-production of Hydrogen Over the $CdS-TiO_2$ Nano-composite Particulate $^{\ast}Lms$ Treated with TiCl4," Int. J. Hydrogen Energy, 29 229 (2004).   DOI
13 K. R. Zhu, M. S. Zhang, J. M. Hong, and Z. Yin, "Size Effect on Phase Transition Sequence of $TiO_2$ Nanocrystal," Mater. Sci. Eng. A: Struct., 403 87 (2005).   DOI
14 R. S. Yuan, R. B. Guan, and J. T. Zheng, "Effect of the Pore Size of $TiO_2-loaded$ Activated Carbon Fiber on its Photocatalytic Activity," Scripta Mater., 52 1329 (2005).   DOI
15 Y. Zhang, J. C. Crittenden, D. W. Hand, and D. L. Perram, "Fixed-bed Photocatalysts for Solar Decontamination of Water," Environ. Sci. Technol., 28 435 (1994).   DOI
16 Y. Bessekhouad, N. Chaoui, M. Trzpit, N. Ghazzal, D. Robert, and J.V. Weber, J. "UV-vis Versus Visible Degradation of Acid Orange II in a Coupled $CdS/TiO_2$ Semiconductors Suspension," Photochem. Photobiol., A183 218 (2006).
17 K. Demeestere, J. Dewulf, T. Ohno, P. H. Salgado, and H. V. Langenhove, "Visible Light Mediated Photocatalytic Degradation of Gaseous Trichloroethylene and Dimethyl Sulfide on Modified Titanium Dioxide," Appl. Catal. B: Environ., 61 140 (2005).   DOI
18 J.C. Tristao, F. Magalhaes, P. Corio, M.T.C. Sansiviero, "Electronic Characterization and Photocatalytic Properties of $CdS/TiO_2$ Semiconductor Composite," J. Photochem. Photobiol., A, 181 152 (2006).   DOI
19 L. Wu, J. C. Yu, and X. Z. Fu, "Characterization and Photocatalytic Mechanism of Nanosized CdS Coupled $TiO_2$ Nanocrystals under Visible Light Irradiation," J. Mol. Catal. A: Chem., 244 25 (2006).   DOI   ScienceOn
20 Z. Ding, X. J. Hu, P. L. Yue, G. Q. Lua, and P. F. Greenfield, "Synthesis of Anatase $TiO_2$ Supported on Porous Solids by Chemical Vapor Deposition," Catal. Today, 68 173 (2001).   DOI   ScienceOn
21 Y. M. Xu, W. Zheng, and W. P. Liu, "Enhanced pHotocatalytic Activity of Supported $TiO_2$ : Dispersing Effect of $SiO_2$," J. Photochem. Photobiol. A: Chem., 122 57 (1999).   DOI   ScienceOn
22 A. Bhattacharyya, S. Kawi, and M. B. Ray, "Photocatalytic Degradation of Orange II by $TiO_2$ Catalysts Supported on Adsorbents," Catal. Today, 98 431 (2004).   DOI   ScienceOn
23 W.C. Oh, M.L. Chen, and F.J Zhang, "Photocatalytic Degradation of Methylene Blue by CNT/ TiO2 Composites Prepared from MWCNT and Titanium(IV) Isopropoxide in Tetrahydrofuran," J. Photocatal. Sci., 1 [2] 19-28 (2010).
24 W.C. Oh, "Review of Carbon Based Titania Photocatalysts," J. Photocatal. Sci., 1 [2] 29-34 (2010).
25 L. Zhu, Z.D. Meng, M. L..Chen, F.J. Zhang, J.G.Choi, J.Y. Park, and W.C. Oh, "Photodegradation of MB Solution by the Metal (Fe, Ni and Co) Containing $AC/TiO_2$ Photocatalyst under the UV Irradiation," Phys J. Photocatal. Sci., 1 [2] 69-76 (2010).
26 W.C. Oh and F.J Zhang "A Review-Antibacterial Activity of CNT/ $TiO_2$, Ag-CNT/ $TiO_2$, and C60/ $TiO_2$," J. Photocatal. Sci., 1 [2] 63-67 (2010).
27 D. Chatterjee and A. Mahata, "Visible Light Induced Photodegradation of Organic Pollutantson Dye Adsorbed $TiO_2$ Surface," J. Photochem. Photobiol., A153 199 (2002).
28 Y. M. Cho and W. Y. Choi, "Visible Light-Induced Degradation of Carbon Tetrachloride on Dye-Sensitized $TiO_2$," Environ. Sci. Technol., 35 966 (2001).   DOI