• Journal of ILASS-Korea
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• v.10 no.4
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• pp.8-15
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• 2005

The use of clean gaseous fuels for the purpose of high efficiency and low emission in automotive engines has tendency to increase in order to meet the reinforcing emission regulations and to efficiently utilize limited natural resources. Automotive companies developed and commercialized a LPG liquid injection system, which is mounted on LPLi(Liquid Phase LPG Injection) engines and vehicles based on this research trend. This research examines the biggest problem in LPLi engine, that is, the leakage characteristics of low viscosity LPG fuel according to the injector design variables. This study is also aimed to improve the performance of fuel-leakage in LPLi engine through the addition of a lubrication improver in HFRR(High Frequency Reciprocating Rig) facility. The needle displacement and the spring displacement of an LPLi injector are found to be already optimized. The possibility of a maximum of 70% leakage reduction compared to a conventional case, is verified when 1000ppm of a lubrication improvement material is added and 40% increase of a injector spring constant (K) is applied.

• Tribology and Lubricants
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• v.25 no.2
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• pp.125-131
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• 2009

Biodiesel produced from triglyceride which is main component of animal fats and vegetable oils by methanolysis was known for excellent lubricity. In this study, the lubricity of 12 kinds of biodiesel come from vegetable oils were analyzed using HFRR(High frequency reciprocating rig). The biodiesel synthesized from soybean oil has best lubricity by $153{\mu}m$ of wear scar in HFRR and used fried oil's biodiesel has slightly low lubricity by $299{\mu}m$. Also we have found that the lubricity of diesel was improved when mixing ratio of soybean biodiesel was increased in base diesel.

• Tribology and Lubricants
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• v.26 no.3
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• pp.190-198
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• 2010

GTL(gas-to-liquid) fuel produced by the Fischer-Tropsch process using carbon monoxide(CO) and hydrogen(H2) is expected to be one of the environmental friendly fuel for alternative and blended to petrodiesel. But GTL have poor lubricity due to paraffin as main component of GTL which is not involve polar materials. In this paper, we had investigated the lubricity improvement of GTL fuels with various lubricants using HFRR(high frequency reciprocating rig).

• Applied Chemistry for Engineering
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• v.23 no.4
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• pp.421-427
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• 2012

To improve the lubricity of ultra low sulfur diesel, vegetable oil-based alkanol amide derivatives were prepared and their lubricity properties were studied. To synthesize the alkanol amides, we conducted the amidation reaction of diethaolamine High Frequency Reciprocating Rig (HFRR) and the fatty acid methyl esters, obtained by the continuous transesterification of methanol and several vegetable oil, such as soybean oil, palm oil and coconut oil. The synthesized amides were soluble in ultra low sulfur diesel in the concentration range of ca. 1 wt%; the lubricating properties of ultra low sulfur diesel containing 120 ppm of amides were measured using an HFRR method. It was found that the wear scar diameter in the pure ultra low sulfur diesel decreased significantly from 581 ${\mu}m$ to 305~323 ${\mu}m$ upon the addition of the amides, indicating that lubricating properties of the diesel were improved. On the other hand, the types of vegetable oils did not affect the wear scar diameters, implying that lubricating properties of the diesel did not depend strongly on the structures of alkyl groups of alkanol amide derivatives. When we measured the lubricating properties of the one type of diesels containing various amounts of alkanol amide, we observed that the wear scar diameter decreased drastically with increasing the amide concentration, meaning that the lubricity improved with the amide concentration.

• Applied Chemistry for Engineering
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• v.21 no.6
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• pp.684-688
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• 2010

Biodiesel produced from the reaction of methanol and triglyceride which is the main component of animal fats and vegetable oils is known for remarkable lubricity. In this study, the lubricity of 3 kinds of biodiesel came from vegetable oils such as soybean oil, palm oil, and perilla oil and 2 kind of biodiesel which were produced from beef tallow and pork lard were analyzed using HFRR (High frequency reciprocating rig). In HFRR test result, the lubricity of perilla and soybean's biodiesel was higher than other biodiesels. After analysis of biodiesel components by GC-MS and determination of the lubricity of pure biodiesel components using HFRR, it was found that a higher olefin content and long alkyl chaining biodiesel had an excellent lubricity property.

• Tribology and Lubricants
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• v.32 no.3
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• pp.95-100
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• 2016

As an alternative fuel, biodiesel has excellent lubricating property. Previously, our research group reported that the properties of biodiesels depended on their composed molecular structure. In this study, we investigate lubricity and the mechanism of lubricity improvement of synthesized biodiesel molecules. We synthesize four types of biodiesel components from fatty acid via fisher esterification and soybean biodiesel from soybean oil via transesterification in high yield (92-96%). We analyze the lubricity of the five 5 types of biodiesel using HFRR (high frequency reciprocating rig). We estimate that the mechanism of lubricity is relevant to the molecular structure and structure conversion of biodiesel. The test results indicate that the longer the length of molecules and the higher the content of olefin, the better the lubricity of the biodiesel molecules. However, the wear scar size of the first test samples’ do not show a regular pattern with the wear scar size of the second test samples’. Moreover, we investigated the structure conversion of the biodiesels by using GC-MS for the recovered biodiesel samples from the HFRR test. However, we do not detect structure conversion. Thus, we conclude that the lubricity of biodiesel depends on how effectively solid adsorption and boundary lubrication occurs based on the size of the molecule and the content of olefin in the molecule. In addition, HFRR test condition in not sufficient for Diels-Alder cyclization of biodiesel components.

• Journal of Institute of Convergence Technology
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• v.3 no.1
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• pp.15-18
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• 2013

The next generation alternative fuel of diesel, DME (Dimethyl Ether) discharges particulate matter hardly due to chemical structural as oxygen-fuel so it has the eco-friendly property. Despite these advantages, the DME has the technical difficulties to apply to the diesel engine because of a low calorific value, viscosity and compressibility effects. From this point of view, we performed experimental studies on improved reliability of DME common-rail vehicle and lubricity enhancement of DME fuel for empirical distribution of eco-friendly DME fuel. Also we analyzed solubility of lubrication enhancer according to a drop in temperature, try to secure reliability about core parts of DME vehicle by applying lubrication enhancer in the DME common-rail vehicle.

• Tribology and Lubricants
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• v.36 no.6
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• pp.385-390
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• 2020

It rains heavily, such as long rain and typhoons, during a typical rainy season in Korea. In this season, several fuel contamination accidents by water and vehicular problems caused by water contaminated fuel occur. Many research groups have studied the effects of water contaminated fuel on vehicles and environment. However the characteristics of water contaminated fuel have not been studied. In this study, we prepared diesel samples with a constant ratio of water (0~30 volume %) using an emulsifier. Then, we analyzed these diesel samples for their representative fuel properties. In the analytical results, diesel with 30% water showed an increase in fuel properties such as density (823→883 kg/㎥), kinematic viscosity (2.601→6.345 ㎟/s), flash point (47→56℃), pour point (-22→2℃), CFPP (cold filter plugging point) (-17→20℃) and copper corrosion number (1a→2a). The low temperature characteristics, such as low pour point and CFPP, blocks the fuel filter in the cold season. In addition, water contaminated diesel decreases lubricity (190→410 ㎛) under high frequency reciprocating rig (HFRR) and derived cetane number (54.81→34.25). The low lubricity of fuel causes vehicle problem such as pump and injector damage owing to severe friction. In addition, the low cetane diesel fuel increases exhaust gases such as NOx and particulate matters (PM) owing to incomplete combustion. This study can be used to identify the problems caused by water contamination to vehicle and fuel facilities.

• Tribology and Lubricants
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• v.16 no.5
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• pp.332-340
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• 2000

The reduction of sulfur content in the diesel fuel has caused the poor lubricity of diesel fuel in the distributor type injection pumps of diesel engines that use the diesel for lubrication of their moving parts. To investigate the reason for poor lubricity of low sulfur diesel fuels, the wear scar diameters by HFRR (High Frequency Reciprocating Rig) were measured on the diesel fuels from Korean markets and the results were compared with their physical and chemical properties. Also, the lubricity change and the improvement effects on lubricity additives for the ultra low sulfur diesel fuel, were made experimentally, that will be regulated to a maximum of 0.005 wt% from about 2005 were evaluated. As a result, a good correlation was found between the wear scar diameter and the polyaromatic compound which includes heterocyclic compound in the diesel fuel. It was also found that the content of polyaromatic compound including heterocyclic compound was affected by the amount of desulfurization treatment fraction. And the lubricity additives with ester base were more effective than that with acid base on the ultra low sulfur diesel fuel. Therefore, it is suggested that the factors affecting the lubricity stated above should be taken into account to improve the lubricity property of the diesel fuel in the refining process.