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Optimized for Low-temperature Sintering of TiO2 Paste with TTIP (TTIP를 이용한 저온소성용 TiO2 페이스트 최적화)

  • Jung, You-Ra;Jin, En Mei;Gu, Hal-Bon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.8
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    • pp.608-613
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    • 2013
  • In this paper, the low-temperature sintering of $TiO_2$ is approached to solve the problem of high temperature sintering which decreases the interconnection between particles or between substrate and particle. $TiO_2$ paste is prepared with Titanium (IV) isopropoxide as the precursor material and calcinate at different conditions (low temperature). In the results, since the changing of temperature and time of sintering, crystalline phase do not change and the intensities of anatase, rutile phase are higher. At $110^{\circ}C$, 7 h sintering condition, crystalline size of anatase and rutile phase are the smallest which are 13.07 and 17.47 nm, respectively. In addition, the highest zeta potential is about 32.77 mV and the repulsive force increases thus leading to the best of the dispersion characteristics between $TiO_2$ particles. Futhermore, DSSCs at that condition exhibits the highest efficiency with the values of $V_{oc}$, $J_{sc}$, FF and ${\eta}$ are 0.69 V, $8.60mA\;cm^{-2}$, 67.93% and 4.06%, respectively.

Secondary Transition Characteristics of Induced Displacement Current (유기된 변위전류의 2차 전이특성)

  • Kim, Sung-Jin;Chang, Hun;Kim, Young-Heun;Choi, Young-I1;Gu, Hal-Bon;Chung, Hun-Sang;Lee, Kyung-Sup
    • Proceedings of the KIEE Conference
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    • 2000.07c
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    • pp.1693-1695
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    • 2000
  • In this paper with deposition 8A5H induce monolayers which has photoisomerization response displacement current was detected by photoisomerization and the amplifier was designed in order to amplify detected displacement current and then secondary current characteristic was measured. The experimental results are as following: In case of ultraviolet(${\lambda}_1$) and visible(${\lambda}_2$) irradiation on 8A5H induce monolayers depositioned on board the peak of current was detected about 9[fA]. Displacement current amplified as secondary transition form was measured but there was any particular reaction for detailed and accurate measurement restruction of the circuit is required.

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Effect of Performance in Dye-sensitized Solar Cells by PEG Contents (PEG 함량변화가 염료감응형 태양전지의 효율에 미치는 영향)

  • Baek, Hyoung-Youl;Han, Zhen-Ji;Li, Hu;Gu, Hal-Bon;Park, Kyung-Hee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.2
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    • pp.178-181
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    • 2008
  • A solar cell based on dye-sensitized photoelectric conversion was studied by investigating the effects of the amount of polyethylene glycol(PEG), added to the $TiO_2$ paste, on surface morphology of the $TiO_2$ films and on the solar cell performance. Energy conversion efficiency was found to increase with PEG addition up to 20 % by weight of $TiO_2$ and then decrease with further addition due to the aggregation of $TiO_2$ nano particles in the $TiO_2$ film. In this study, the best result of dye-sensitized solar cell was the short circuit current(Isc) of $22.6mAcm^{-2}$, the open circuit voltage (Voc) of 0.73 V, the fill factor (ff) of 0.55 and the overall energy conversion efficiency (${\eta}$) of 9.1 % under illumination with AM 1.5 simulated sunlight.

Properties of Indium Tin Oxide Transparent Conductive Thin Films at Various Substrate and Annealing Temperature

  • Jeong, Woon-Jo;Kim, Seong-Ku;Kim, Jong-Uk;Park, Gye-Choon;Gu, Hal-Bon
    • Transactions on Electrical and Electronic Materials
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    • v.3 no.1
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    • pp.18-22
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    • 2002
  • ITO thin films with thickness of 3000 $\AA$ were fabricated by rf magnetron sputtering system with a 10 mol % SnO$_2$-90 mol % In$_2$O$_3$target at various substrate temperature and annealing temperature in air. And we investigated structural, electrical and optical characteristics of them. It's resistivity, carrier concentration and Hall mobility was 2$\times$10$\^$-4/ Ωcm, 7$\times$10$\^$20/∼ 9$\times$10$\^$20/ cm$\^$-3/ and 21∼23 cm$^2$/V$.$sec respectively. And it's optical transmittance and energy band gap was above 85 % in the visible range and 3.53 eV respectively.

Electrochemical Properties of LiFePO4 Cathode Materials for Lithium Polymer Batteries (리튬폴리머전지용 정극활물질 LiFePO4의 전기화학적 특성)

  • Kong Ming-Zhe;Kim Hyun-Soo;Gu Hal-Bon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.6
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    • pp.519-523
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    • 2006
  • $LiFePO_4$ has been received attention as a potential cathode material for the lithium secondary batteries. In our study, $LiFePO_4$ cathode active materials were synthesized by a solid-state reaction. It was modified by coating $TiO_2$ and carbon in order to enhance cyclic performance and electronic conductivity. $TiO_2$ and carbon coatings on $LiFePO_4$ materials enhanced the electronic conductivity and its charge/discharge capacity. For lithium polymer battery applications, $LiFePO_4$/solid polymer electrolyte (SPE)/Li and $LiFePO_{4}-TiO_{2}/SPE/Li$ cells were characterized by a cyclic voltammetry and charge/discharge cycling. The electrode with $LiFePO_{4}-carbon-TiO_{2}$ in PVDF-PC-EC-$LiClO_{4}$ electrolyte showed promising capacity of above 100 mAh/g at 1C rate.

The Impeditive Properties and Charge/Discharge of Positive Active Material $LiMnO_2$ (정극 활물질 LiMnO2 충.방전과 임피던스 특성)

  • Wi, Seong-Dong;Kim, Jong-Ok;Gu, Hal-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.05c
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    • pp.299-305
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    • 2003
  • The battery industries have been developed to the implementation of lithium ion secondary cell from the cell of Ni/Cd and Ni/MH in the past to be asked of an age of high technology from low technology. Also in resent the polymeric cell to get a good high function with an age of new advanced information system is changed from the 21 century to the secondary batteries society. The properties of lithium secondary batteries have the high energy density, the long cycle time, the low self discharge area and the high active voltage. The wanted properties of secondary batteries for the motion of an apparatuses of industries of an high skill age have a small type trend of the energy density and it is become with a strong asking of the industrial society market about the storable medium of the convenience and new power energy. The electrochemical properties is researched for the cell to be synthesised and crystallized the positive active material LiMnO2 of the secondary cell at 9250C to get a new improved data of the electric discharge for that the capacitance of the LiMnO2 thin film that is improving and researching with the properties and a merit and demerit in the this kind of asking.

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Phase Transition of Biology Thin Film and Molecule Arrangement Properties (생체박막의 상전이와 분자배열특성)

  • Kim, Byung-Geun;Chon, Dong-Kyu;Kim, Young-Keun;Gu, Hal-Bon;Lee, Woo-Sun;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.05c
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    • pp.103-106
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    • 2003
  • It is well known that the state of existence of molecules on the surface of water changes during compression of the molecules. Electric methods, such as measurement of the surface potential or displacement current are also useful for investigating dynamic changes of molecular state on the water surface during compression. In this paper, We studied on the Bio thin film by Langmuir-Biodgett(LB) method. The Experiment method used displacement current, $\pi-A$ isotherm and BAM (Brewster Angle Microscopy). using the BAM, we can to the molecular orientation of monolayer on the water surface and directly see the morphology of the films on water subphase as well as that of the films.

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Electronic Temperature and Density of Mixed Gases in Inductively Coupled Plasma Lighting System (Ne:Xe) (Inductively Coupled Plasma 광원 시스템의 Ne:Xe 혼합가스의 전자온도 및 전자밀도 특성)

  • Choi, Yong-Sung;Gu, Hal-Bon;Lee, Jin;Lim, Jong-Yeol;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.12a
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    • pp.91-95
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    • 2006
  • In whole world consciousness of environment maintenance have increased very quickly for the end of the 20th century. To use and disuse toxic substances have been controled at the field of industry. Also the field of lighting source belong to environmental control. And in the future the control will be strong. In radiational mechanism of fluorescence lamp mercury is the worst environmental problem. In radiational mechanism of fluorescence lamp mercury is the worst environmental problem root. In the mercury free lighting source system the Xe gas lamp is one type. And the Ne:Xe mixing gas lamp improvements firing voltage of Xe gas lamp. Purpose and subject of this study are understand, efficiency, ideal of Ne:Xe plasma which mercury free lamp. Before ICP was designed, basic parameters of plasma, which are electron temperature and electron density, were measured and calculated by langmuir probe data. Property of electron temperature and electron density were confirmed by changing ratio of Ne:Xe.

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Emission Characteristics of Red OLEDs in the Emitting Layer Position Doped with DCM2 and Rubrene (DCM2와 Rubrene이 첨가된 발광층 위치에 따른 적색 OLED의 발광 특성)

  • Jung, Haeng-Yun;Gu, Hal-Bon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.8
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    • pp.664-668
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    • 2011
  • In this study, we have fabricated the red OLED (organic light emitting diode). The basic device structure is ITO/hole transporting layer, TPD(500 $\AA$)/red emitting layer, Alq3 doped with DCM2:rubrene(20 $\AA$)/electron transporting layer, Alq3(M) (500 $\AA$-M $\AA$)/LiF(15 $\AA$)/Al(1,000 $\AA$). The thickness of electron transporting layer(500 $\AA$-M $\AA$) changed 0, 20, 40, 60 $\AA$. Turn on voltage of the red OLED was 5 V, 6 V, 6.5 V and 7.5 V, respectively with electron transfer layer changed ratio. Luminance of red OLED was 4,504, 1,840, 1,490 and 1,130 cd/$m^2$, respectively. Optimized electron transfer layer position changed ratio of the red OLED was 0 $\AA$.

Use of Converter Dust as Desiliconization Agent for Molten Pig Iron (전로분진의 용선탈규특성)

  • 김동수;주선헌;구성은;반봉찬
    • Resources Recycling
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    • v.8 no.5
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    • pp.19-27
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    • 1999
  • The desilica~ilalioc~h~ar .~ctcrisocs or conveutcu dust for molten pg iron has bee11 sludled for the pulposc of converter dust reuse. Desiloconizalir~ne ff~c~encwya s observed 10 be increased with increasing feeding rate of dust, and there was 110 cffccl to Lhe des~lica~~iratiearlfli cio~cyfo r the addtioolI CaO Ln dust. In ~noslc ases, the dcs~l~conizaliornea ction was ucconlpl~shed wrthin 10 minutes regadless of thc dust cornpasilim In addition lo the desil~comzat~oenfl ect, the rzmow~lc hal-i~cteristo~fs M u, P. C, and S from mallen iron by convcrtcr dust also have been in\~esligataled. CuO m thc converlel. dust was observed to ~educc the demanganizi~tion eflect and slag laming phenomenon and make thc dephosphoriralion pn,ce*s easler.

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