• 제목/요약/키워드: H&R

검색결과 14,158건 처리시간 0.044초

Amine and Olefin Complexes of Pt(II) Having a PCP-Pincer Ligand

  • Park, Soon-Heum
    • Bulletin of the Korean Chemical Society
    • /
    • 제23권1호
    • /
    • pp.132-136
    • /
    • 2002
  • $Pt(2,6-(Cy_2PCH_2)_2C_6H_3)(OTf)\;(OTf=CF_3SO_3^-)$ readily reacts with various amines to afford cationic amine complexes $[Pt(2,6-(Cy_2PCH_2)_2C_6H_3)(amine)](OTf)\;(amine=NH_3,\;NHMe_2,\;NHC_4H_8,\;NH_2Ph,\;NH_2(Tol-p))$ in high yields. These complexes have been fully characterized by IR, $^1H-,\;^{19}F{^1H}-,\;and\;^{31}P{^1H}-NMR$ spectroscopy, and elemental analyses. Reaction of $Pt(2,6-(Cy_2PCH_2)_2C_6H_3)(OTf)$ with acrylonitrile quantitatively produced the ${\pi}$-olefinic complex $Pt(2,6-(Cy_2PCH_2)_2C_6H_3)(CH_2=CHCN)](OTf)$ which is only stable in solution in the presence of acrylonitrile. Attempt at isolating this complex in the pure solid state was failed due to partial decomposition into $Pt(2,6-(Cy_2PCH_2)_2C_6H_3)(OTf)$ The equilibrium constants $(K_{eq}=[Pt(PCP)-(NH_2R)^+][CH_2=CHCN]/[Pt(PCP)(CH_2=CHCN)^+][NH_2R]:\;[Pt(2,6-(Cy_2PCH_2)_2C_6H_3)(CH_2=CHCN)]^++NH_2R{\rightleftarrows}[Pt(2,6-(Cy_2PCH_2)_2C_6H_3)(NH_2R)]^++CH_2=CHCN=Ph,\;p-tolyl)$ were calculated to be 0.28 (for R = Ph) and 3.1 (R = p-tolyl) at $21^{\circ}C$. The relative stability of the ${\sigma}$-donor amine versus the ${\pi}$-olefinic acrylonitrile complex has been found largely dependent upon the amine-basicity $(pK_b)$, implicating that acrylonitrile practically competes with amine in the platinum coordination sphere. On the contrary to the formation of the acrylonitrile complex, no reaction of $Pt(2,6-(Cy_2PCH_2)_2C_6H_3)(OTf)$ with other olefins such as ethylene, styrene and methyl acrylate was observed.

핸드오프를 지원하는 H.323 게이트키퍼 구조 (An H.323 Gatekeeper Architecture Providing Handoff function)

  • 이영신;최기무;강환종
    • 대한전자공학회:학술대회논문집
    • /
    • 대한전자공학회 2001년도 하계종합학술대회 논문집(1)
    • /
    • pp.341-344
    • /
    • 2001
  • H.323 proposes to use Mobile IP and H.323 ad hoc conference signaling to provide Handoff function to an H.323 mobile terminal. But the H.323 ad hoc conference signaling has a drawback. It requires an H.323 terminal to do a complex conference signaling which takes a longer signaling time. In this paper, we propose an GK architecture that provides Handoff function effectively using 3$^{rd}$ P'||'||'||'||'||'&'||'||'||'||'||'R(Third party initiated Pause and Rerouting) signaling which are done through H.245 logical channel. The GK which is implementing 3$^{rd}$ P'||'||'||'||'||'&'||'||'||'||'||'R signaling only requires an H.323 endpoint to do the H.323 basic signaling in reestablishing media channel and gives the faster Handoff signaling. To do this, our GK has derived H.245 control channel using tunneling f3r all H.323 calls including the fast connect calls which enable terminals communicate each other if they doesn't have H.245 control channel .municate each other if they doesn't have H.245 control channel .

  • PDF

ON THE SUPERSTABILITY OF SOME FUNCTIONAL INEQUALITIES WITH THE UNBOUNDED CAUCHY DIFFERENCE (x+y)-f(x)f(y)

  • Jung, Soon-Mo
    • 대한수학회논문집
    • /
    • 제12권2호
    • /
    • pp.287-291
    • /
    • 1997
  • Assume $H_i : R_+ \times R_+ \to R_+ (i = 1, 2)$ are monotonically increasing (in both variables), homogeneous mapping for which $H_1(tu, tv) = t^p(H_1(u, v) (p > 0)$ and $H_2(u, v)^{t^q} (q \leq 1)$ hold for $t, u, v \geq 0$. Using an idea from the paper of Baker, Lawrence and Zorzitto [2], the superstability problems of the functional inequalities $\Vert f(x+y) - f(x)f(y) \Vert \leq H_i (\Vert x \Vert, \Vert y \Vert)$ shall be investigated.

  • PDF

EXISTENCE OF RESONANCES FOR DIFFERENTIAL OPERATORS

  • Kim, In-Suk
    • 대한수학회논문집
    • /
    • 제9권2호
    • /
    • pp.337-353
    • /
    • 1994
  • Let H be a Schrodinger operator in $L^2$(R) H =(equation omitted) + V(x), with supp V ⊂ [-R, R]. A number $z_{0}$ / in the lower half-plane is called a resonance for H if for all $\phi$ with compact support 〈$\phi$, $(H - z)^{-l}$ $\phi$〉 has an analytic continuation from the upper half-plane to a part of the lower half-plane with a pole at z = $z_{0}$ . Thus a resonance is a sort of generalization of an eigenvalue. For Im k > 0, ($H - k^2$)$^{-1}$ is an integral operator with kernel, given by Green's function(omitted)

  • PDF

PROJECTION PROCESSES OF H-SSSIS RANDOM FIELDS

  • Kim, Joo-Mok
    • 충청수학회지
    • /
    • 제9권1호
    • /
    • pp.115-121
    • /
    • 1996
  • Let $\{X(t);\;t{\in}R^n\}$ be a measurable, separable and H-sssis random fields. Here, we suppose that the increments are invariant under all Euclidean rigid body motions. We investigate some properties of H-sssis random fields and monotonicity of projection process $\{X_e(t);\;t{\in}R^1\}$ in any direction $e{\in}R^n$.

  • PDF

HOMOCLINIC ORBITS FOR HAMILTONIAN SYSTEMS

  • Kim, June-Gi
    • 대한수학회보
    • /
    • 제32권1호
    • /
    • pp.1-11
    • /
    • 1995
  • Let $p, q \in R^2 and H : R^{2n} \to R^n$ be differentiable. An autonomous Hamiltonian system has the form $$ (0.1) \dot{p} = -\frac{\partial q}{\partial H}(p, q), \dot{q} = \frac{\partial p}{\partial H}(p, q) $$.

  • PDF

Recent Trend of Low Temperature Poly Silicon Technologies in TFT-LCD

  • Kim, C.W.;Kim, H.J.;Lee, H.G.;Min, H.G.;Hwang, J.W.;Cho, S.W.;Ryu, C.K.;Lee, C.;Kang, M.K.;Chung, K.H.
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 한국정보디스플레이학회 2002년도 International Meeting on Information Display
    • /
    • pp.46-49
    • /
    • 2002
  • Recent trends of low-temperature polycrystalline Si (LTPS) TFT technologies are presented. Characteristics of LTPS TFT processes are compared with those of a-Si TFT's. In order to compete with well-established a-Si TFT-LCD technology, LTPS process has to be as simple as possible. One of the most critical processes, recrystallization of a-Si thin films, could be the process for the differentiation of LTPS technology. Along with these technical reviews, a recent development of the 5.0-inch LTPS TFT-LCD is presented. In order to achieve high-performance display characteristics and save the power consumption, the transflective mode is adopted. The 5.0-inch display with 186 pixel-per-inch, high-resolution LCD was measured to be 10% for the reflectance and 70:1 for the contrast ratio. This display is designed for a high information content hand-held PC (HHPC) application.

  • PDF