• 한국재료학회지
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• 제20권4호
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• pp.204-209
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• 2010

Recent high efficiency electronic devices have been found to have heat emission problems. As for LEDs, an excessive increase in the device temperature causes a drop of the luminous efficiency and circuit lifetime. Therefore, heat release in the limited space of such electronic parts is very important. This is a study of the possibility of using a coating of carbon materials as a solution for the thermal emission problem of electronic devices. Powdered carbon materials, cokes, carbon blacks, amorphous graphite, and natural flakes were coated with an organic binder on an aluminum sheet and the subsequent thermal emissivity was measured with an FT-IR spectrometer and was found to be in the range of $5{\sim}20\;{\mu}m$ at $50^{\circ}C$. The emissivity of the carbon materials coated on the aluminum sheet was shown to be over 0.8 and varied according to carbon type. The maximum thermal emissivity on the carbon black coated-aluminum surface was shown to be 0.877. The emissivity of the anodized aluminum sheets that were used as heat releasing materials of the electronic parts was reported to be in the range of 0.7~0.8. Therefore, the use of a coating of carbon material can be a potential solution that facillitates heat dissipation for electronic parts.

• 공업화학
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• 제9권7호
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• pp.1059-1064
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• 1998

본 연구는 리튬이온 이차전지용 탄소전극을 개발하기 위하여 다양한 종류의 흑연과 MCMB6-28을 대상으로 이루어졌다. 이들의 층간거리는 $3.358{\sim}3.363{\AA}$, BET 비 표면적은 $2.95{\sim}26.15m^2/g$이었다. 이들의 전기화학적 특성은 층간거리가 크고 적절한 크기의 BET 비 표면적을 가질 때 리튬의 삽입과 탈삽입 거동이 우수하였다. 다양한 결정성계 탄소전극 활물질에 도전재로 KJ-Black을 0, 3, 5wt% 첨가하였을 때 도전제의 함량이 많을수록 전극과 전해질의 계면저항은 작아지나 3wt%를 첨가하였을 때 우수한 가역성을 보였다. 정전류 충 방전 시 인가되는 전류밀도를 증가시킴에 따라 탄소부극의 방전용량은 작아졌다.

• Steel and Composite Structures
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• 제26권4호
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• pp.473-484
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• 2018

Free vibration of cross-ply laminated plates using a higher-order shear deformation theory is studied. The arbitrary number of layers is oriented in symmetric and anti-symmetric manners. The plate kinematics are based on higher-order shear deformation theory (HSDT) and the vibrational behaviour of multi-layered plates are analysed under simply supported boundary conditions. The differential equations are obtained in terms of displacement and rotational functions by substituting the stress-strain relations and strain-displacement relations in the governing equations and separable method is adopted for these functions to get a set of ordinary differential equations in term of single variable, which are coupled. These displacement and rotational functions are approximated using cubic and quantic splines which results in to the system of algebraic equations with unknown spline coefficients. Incurring the boundary conditions with the algebraic equations, a generalized eigen value problem is obtained. This eigen value problem is solved numerically to find the eigen frequency parameter and associated eigenvectors which are the spline coefficients.The material properties of Kevlar-49/epoxy, Graphite/Epoxy and E-glass epoxy are used to show the parametric effects of the plates aspect ratio, side-to-thickness ratio, stacking sequence, number of lamina and ply orientations on the frequency parameter of the plate. The current results are verified with those results obtained in the previous work and the new results are presented in tables and graphs.

• 한국분말재료학회지
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• 제9권6호
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• pp.441-448
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• 2002

Dispersions of non-soluble ceramic particles in a metallic matrix can enhance the strength and heat resistance of materials. With the advent of mechanical alloying it became possible to put the theoretical concept into practice by incorporating very fine particles in a flirty uniform distribution into often oxidation- and corrosion- resistant metal matrices. e.g. superalloys. The present paper will give an overview about the mechanical alloying technique as a dry, high energy ball milling process for producing composite metal powders with a fine controlled microstructure. The common way is milling of a mixture of metallic and nonmetallic powders (e.g. oxides. carbides, nitrides, borides) in a high energy ball mill. The heavy mechanical deformation during milling causes also fracture of the ceramic particles to be distributed homogeneously by further milling. The mechanisms of the process are described. To obtain a homogeneous distribution of nano-sized dispersoids in a more ductile matrix (e.g. aluminium-or copper based alloys) a reaction milling is suitable. Dispersoid can be formed in a solid state reaction by introducing materials that react with the matrix either during milling or during a subsequent heat treatment. The pre-conditions for obtaining high quality materials, which require a homogeneous distribution of small dis-persoids, are: milling behaviour of the ductile phase (Al, Cu) will be improved by the additives (e.g. graphite), homogeneous introduction of the additives into the granules is possible and the additive reacts with the matrix or an alloying element to form hard particles that are inert with respect to the matrix also at elevated temperatures. The mechanism of the in-situ formation of dispersoids is described using copper-based alloys as an example. A comparison between the in-situ formation of dispersoids (TiC) in the copper matrix and the milling of Cu-TiC mixtures is given with respect to the microstructure and properties, obtained.

• Korean Chemical Engineering Research
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• 제48권3호
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• pp.292-299
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• 2010

그래핀(graphene)은 $sp^2$ 탄소원자들이 벌집 격자를 이룬 형태의 2차원 나노시트를 의미하며, 높은 비표면적(이론치 $2600m^2\;g^{-1}$)과 우수한 전기전도도(전형치 $8{\times}10^5S\;cm^{-1}$) 및 기계적 강도로 인해 리튬이온전지의 음전극 활물질 및 초고용량 커패시터의 전극 활물질로서 사용 가능성이 높아지고 있다. 본 총설에서는 현재까지 알려진 그래핀 나노시트와 그래핀을 기반으로 하는 나노복합체의 제조법을 소개하고, 이를 리튬이온전지와 초고용량 커패시터의 전극소재로 적용하였을 때의 특성을 그 나노구조적 관점과 연관하여 논의하였다.

• Elastomers and Composites
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• 제46권2호
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• pp.102-111
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• 2011

타이어 인너라이너(innerliner)는 타이어 내부의 고무층으로 타이어의 공기압 유지 및 내구성능을 유지하는 중요한 역할을 한다. 일반적으로 인너라이너용 고무는 공기 투과속도가 낮은 halogenated butyl rubber(HIIR)를 가장 많이 사용하고 있다. 수년 전부터 chloronated butyl rubber(CIIR), brominated poly(isobutylene-co-isoprene)(BIIR), brominated polyisobutylene-co-paramethylstyrene(BIMS) 고무와 높은 종횡비를 지닌 충전제를 복합화하여 고무기질내의 공기 투과 거리를 증가시켜 공기 차단 특성을 향상시키는 나노복합체 연구가 활발히 이루어지고 있다. 인너라이너의 고차단화 기술은 인너라이너의 두께 조절이 가능하고, 일정한 공기압 유지를 통한 타이어의 내구성능을 향상시킬 수 있는 장점을 가지고 있다. 따라서, 고무 소재의 공기 차단 특성을 부여할 수 있는 차단성 소재 및 나노복합체 제조 기술에 대해서 살펴보았다.

• 대한용접접합학회:학술대회논문집
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• 대한용접접합학회 2002년도 Proceedings of the International Welding/Joining Conference-Korea
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• pp.726-731
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• 2002

Reaction synthesis is a process to form ceramics, intermetallics and their composites from elemental powder mixture. Application of this process to a surface modification techniques has a possibilities to enable the process at a lower temperature or for a shorter time, although synthesized materials are likely to include voids and unreacted elements. This paper intend to examine the effect of Si addition to the mixture of Al and Ni on the densification of synthesized Ni-Al intermetallic compounds and to evaluate the surface properties of obtained coatings. By the Si addition, exothermic reaction temperature to form Ni-Al intermetallic was lowered to be below the melting point of Al. Si soluted $Al_3$Ni$_2$, $Al_3$Ni and $Al_{6}$Ni$_3$Si were mainly formed in the coating layer when powder mixture was heated to 973K for 300s. Besides, densification was enhanced by increasing hot press pressure, Si additions and heating rate. When the composition of eutectic Al-Si reaches 78%, void ratio of sintered compact reduced to 0.4%. It is caused by higher flowability of Al-Si liquid phase generated and its infiltration into the void. Since the hardness of NiAl(Si) compound (about 600HV) formed in the coating layer is higher than that of Ni-Al compound (about 400HV), coating layer with high density and superior wear property is obtained by hot press using reaction synthesis from Al-Ni-Si powder mixture.

• Carbon letters
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• 제28권
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• pp.38-46
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• 2018

Modified pitch A (MPA) and modified pitch B (MPB) were prepared by oxidative polymerization and thermal polycondensation reaction with refined pitch as the raw material, respectively. The toluene soluble components (TS-1 and TS-2) were obtained by solvent extraction from MPA and MPB, separately. The Flynn-Wall-Ozawa method and Kissinger-Akahira-Sunose method were used to calculate the pyrolysis activation energy of TS. The Satava-Sestak method was used to investigate the pyrolysis kinetic parameters of TS. Moreover, the optical microstructure of the thermal conversion products (TS-1-P and TS-2-P) by calcination shows that TS-1-P has more contents of mosaic structure and lower contents of fine fiber structure than TS-2-P. The research result obtained by a combination of X-ray diffraction and the curve-fitting method revealed that the ratios of ordered carbon crystallite (Ig) in TS-1-P and TS-2-P were 0.3793 and 0.4417, respectively. The distributions of carbon crystallite on TS-1-P and TS-2-P were calculated by Raman spectrum and curve-fitting analysis. They show that the thermal conversion product of TS-2 has a better graphite crystallite structure than TS-1.

• 콘크리트학회논문집
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• 제28권4호
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• pp.395-405
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• 2016

이 연구에서는 태양열 에너지 저장용도로 사용하기 위한 섬유보강 모르타르의 열적 및 역학적 특성을 파악하였다. 다양한 시멘트 복합재료의 배합이 섬유보강 모르타르의 열적 및 역학적 특성에 미치는 영향을 파악하기 위한 실험연구를 수행하였다. 섬유보강 모르타르의 역학적 특성으로서 열싸이클 전과 후의 압축강도 및 인장강도를 측정하였다. 또한, 섬유보강 모르타르의 열적 특성으로서 열전도율과 비열을 측정하였다. OPC와 그라파이트를 포함한 배합의 잔류압축강도가 가장 크게 나타난다. 알루미나 시멘트를 혼합한 배합의 비열이 크게 나타나며, 이는 알루미나시멘트가 열저장 시스템의 효율적인 축열과 방열에 유리함을 의미한다. 또한, 그라파이트의 첨가는 섬유보강 복합재료의 비열을 증가시킨다. 실험연구결과는 콘크리트를 $450^{\circ}C$ 이상의 열저장 매체로 활용하기 위한 프로토타입 시스템 설계에 실제적인 기초자료로 활용될 수 있을 것으로 사료된다.

• Design & Manufacturing
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• 제10권3호
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• pp.14-19
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• 2016

Thermally or electrically conductive filler reinforced polymer composites are extensively being developed as the demand for light weight material increases rapidly in industiral applications need good conductivity such as heat sink of the electronics or light. Carbon or ceramic materials like graphite, carbon nanotube or boron nitride are typical conductive fillers with good thermal or electical conductivity. Using these conductive fillers, the polymer composites in the market show wide range of thermal conductivity from approximately 1 W/mK to 20 W/mK, which is quite enhanced considering the thermal conductivity lower than 0.5 W/mK for most polymeric materials. The practical use of these composites, however, is yet limited to specific applications because most composites are still not conductive enough or too difficult to process, too brittle, too expensive for higher conductivity. For practical use of conductive composite, the thermal conductivity required depending on the heat releasing mode are studied first for simplified unit cooling geometry to propose thermal conductivities of the composites for reasonable cooling performance comparing with the metal heat sink as a reference. Also, as a practical design for heat sink based on polymer composite, composite and metal sheet hybrid structures are investigated for LED lamp heat sink and audio amplication module housing to find that this hybrid structure can be a good solution considering all of the cooling performance, manufacturing, mechanical performance, cost and weight.