• Journal of the Korean Electrochemical Society
• /
• v.8 no.1
• /
• pp.47-54
• /
• 2005

This article covers the fundamentals of stress-induced diffusion, focusing on the theoretical model for hydrogen transport through self-stressed electrode. First, the relationship between hydrogen diffusion and macroscopic deformation of the electrode specimen was briefly introduced, and then it was classified into the diffusion-elastic and elasto-diffusive phenomena. Next, the transport equation for the flux of hydrogen caused simultaneously by both the concentration gradient and the stress gradient was theoretically derived. Finally, stress-induced diffusion was discussed on the basis of the numerical solutions to the derived transport equation under the permeable and impermeable boundary conditions.

• Journal of IKEEE
• /
• v.23 no.3
• /
• pp.793-799
• /
• 2019

In this study, the diffusion process and the thermal energy distribution gradient of the sensor were confirmed by using the finite element analysis program (COMSOL) of the mesh method to analyze the thermal diffusion in the wearable fabric (Nylon) + MWCNT gas sensor. To analyze the diffusion process of thermal energy, the structure of the gas sensor was modeled in a two dimension plane. The proposed modeling was presented with the characteristic value for the component of the sensor, and the gas sensor designed using the mesh finite element method (FEM) was proposed and analyzed by suggesting the one-way partial differential equation in the governing equation to know the degree of thermal energy diffusion and the thermal energy gradient. In addition, the temperature gradient 10[K/mm] of the anode-cathode electrode layer and the gas detection unit was investigated by suggesting the heat velocity transfer equation.

• Membrane Journal
• /
• v.12 no.2
• /
• pp.90-96
• /
• 2002

A novel methodology on the calculations of osmotic pressure and gradient diffusion coefficient has been provided ill the present study, by applying a succinct numerical analysis on the experimental results. Although both the osmotic pressure and the gradient diffusion coefficient represent a fundamental characteristic in related membrane filtrations such as microfiltration and ultrafiltration, neither theoretical analysis nor experiments can readily determine them. The osmotic pressure of colloidal suspension has been successfully determined from a relationship between the data of the time-dependent permeate flux, their numerical accumulations, and their numerical derivatives. It is obvious that the osmotic pressure is gradually increased, as the particle concentration increases. The thermodynamic coefficient was calculated from the numerical differentiation of the correlation equation of osmotic pressure, and the hydrodynamic coefficient was evaluated from the previously developed relation for an ordered system. Finally, the estimated gradient diffusion coefficient, which entirely depends on the particle concentration, was compared to the previous results obtained from the statistical mechanical simulations.

• Transactions of the Korean Society of Mechanical Engineers
• /
• v.11 no.3
• /
• pp.528-536
• /
• 1987

In a turbulent free shear flow, the large scale motion is characterized by the intermittent flow which arises from the interaction between the turbulent fluid and the irrotational fluid of the environment through the mean velocity gradient. This large scale motion causes a bulk convection whose effect is similar to the spatial diffusion process. In this paper, the total diffusion process is proposed to be approximated by weighted sum of the bulk convection due to the large scale motion and the usual gradient diffusion due to small scale motion. The diffusion term in conventional .kappa.-.epsilon. model requires on more equation of the intermittency transport equation. A production term of this equation means mass entrainment from the irrotational fluid to the turbulent one. In order to test the validity of the proposed model, a plane jet is predicted by this method. Numerical results of this model is found to yield better agreement with experiment than the standard .kappa.-.epsilon. model and Byggstoyl & Kollmann's model(1986). Present hybrid diffusion model requires further tests for the check of universality of model and for the model constant fix.

• Nuclear Engineering and Technology
• /
• v.51 no.5
• /
• pp.1181-1194
• /
• 2019

A new moving-mesh Finite Volume Method (FVM) for the efficient solution of the two-dimensional neutron diffusion equation is introduced. Many other moving-mesh methods developed to solve the neutron diffusion problems use a relatively large number of sophisticated mathematical equations, and so suffer from a significant complexity of mathematical calculations. In this study, the proposed method is formulated based on simple mathematical algebraic equations that enable an efficient mesh movement and CV deformation for using in practical nuclear reactor applications. Accordingly, a computational framework relying on a new moving-mesh FVM is introduced to efficiently distribute the meshes and deform the CVs in regions with high gradient variations of reactor power. These regions of interest are very important in the neutronic assessment of the nuclear reactors and accordingly, a higher accuracy of the power densities is required to be obtained. The accuracy, execution time and finally visual comparison of the proposed method comprehensively investigated and discussed for three different benchmark problems. The results all indicated a higher accuracy of the proposed method in comparison with the conventional fixed-mesh FVM.

• Nuclear Engineering and Technology
• /
• v.52 no.3
• /
• pp.485-498
• /
• 2020

A diffusion synthetic acceleration (DSA) technique for the S_N transport equation discretized with the linear discontinuous expansion method with subcell balance (LDEM-SCB) on unstructured tetrahedral meshes is presented. The LDEM-SCB scheme solves the transport equation with the discrete ordinates method by using the subcell balances and linear discontinuous expansion of the flux. Discretized DSA equations are derived by consistently discretizing the continuous diffusion equation with the LDEM-SCB method, however, the discretized diffusion equations are not fully consistent with the discretized transport equations. In addition, a fine mesh rebalance (FMR) method is devised to accelerate the discretized diffusion equation coupled with the preconditioned conjugate gradient (CG) method. The DSA method is applied to various test problems to show its effectiveness in speeding up the iterative convergence of the transport equation. The results show that the DSA method gives small spectral radii for the tetrahedral meshes having various minimum aspect ratios even in highly scattering dominant mediums for the homogeneous test problems. The numerical tests for the homogeneous and heterogeneous problems show that DSA with FMR (with preconditioned CG) gives significantly higher speedups and robustness than the one with the Gauss-Seidel-like iteration.

• Journal of Mechanical Science and Technology
• /
• v.17 no.7
• /
• pp.1054-1062
• /
• 2003

The numerical simulations of flow and pollutant particle dispersion are described for two-dimensional bell shaped hills with various aspect ratios. The Reynolds-averaged incompressible Navier-Stokes equations with low Reynolds number $\kappa$-$\varepsilon$ turbulent model are used to simulate the flowfield. The gradient diffusion equation is used to solve the pollutant dispersion field. The code was validated by comparison of velocity, turbulent kinetic energy, Reynolds shear stress, speed-up ratio, and ground level concentration with experimental and numerical data. Good agreement has been achieved and it has been found that the pollutant dispersion pattern and ground level concentration have been strongly influenced by the hill shape and aspect ratio, as well as the location and height of the source.

• Journal of the Korean Ceramic Society
• /
• v.40 no.9
• /
• pp.827-831
• /
• 2003

In proton-conducting perovskites, oxygen ions and protons make a diffusion pair for a chemical diffusion and thus lead to the transport of $H_2O$ under its chemical potential gradient. The present manuscript develops relationships between the chemical diffusion coefficient of $H_2O$ and the diffusion coefficients of protons and oxygen vacancies with an emphasis on the thermodynamic behavior of the oxygen vacancies. Depending on the degree of hydration X, two different expressions of the chemical diffusion coefficient were obtained : equation omitted and equation omitted.

• Journal of the Korean Applied Science and Technology
• /
• v.19 no.4
• /
• pp.339-348
• /
• 2002

Self-diffusion coefficients of colloidal ass9Ciation structures in the aqueous solutions of anionic ammonium dodecyl sulfate (ADS) and cationic octadecyltrimethylammonium chloride (OTAC) surfactants were measured by pulsed-gradient spin echo NMR. The results were interpreted on the basis of the ADS/OTAC/water phase diagram. Crossing the phase boundaries, significant changes in self diffusion coefficients were observed and well correlated to the phase diagram. For the micelles their apparent radii were obtained from Stokes-Einstein equation. Their values were 15 for the ADS micelles and 54 ${{\AA}}$ for the OTAC micelles, respectively. For vesicles which were formed spontaneously at different relative amounts of the surfactants and total surfactant concentrations, the radius was measured as 50 to 200 nm. This result is in fair agreement with those by TEM and light scattering.

• Design & Manufacturing
• /
• v.12 no.1
• /
• pp.1-6
• /
• 2018

In this study, we calculated the redistribution of vacancy concentration in metal specimens induced by stress-induced diffusion at a high temperature. To deduce the governing equation, we associated the unit volume change equation of strains with a differential equation of vacancy concentration as a function of stress using the stress-strain relationship. In this governing equation, we considered stress as the only chemical potential parameter to stay in the scope of this study, which provided the vacancy concentration equation as of stress gradient in metals. The equation was then mathematically delineated to derive a analytical solution for a transient, one-dimensional diffusion case. With the help of Korhonen's approximation and the boundary conditions, we successfully deduced a general solution from the governing equation. To visualize the feasibility of our solutions, we applied the solution to two different stress-induced cases - a rod with fixed concentrated stresses at both ends and a rod with varying concentrated stresses at both ends. Although it is necessary to legitimatized the model in the future for improvement, our results showed that the model can be used to interpret the location of structural defects, the formation of vacancy, and furthermore the high temperature behavior of metals.