• Journal of the Korean Applied Science and Technology
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• v.30 no.2
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• pp.297-304
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• 2013

Free-radical copolymerization of glycidyl methacrylate(GMA) and N-phthalimidoethyl acrylate(NPEA) were carried out at $60^{\circ}C$ in dimethylformamide(DMF) solution in the presence of benzoylperoxide(BPO) at low conversion. The polymers were characterized by IR and $^1H$-NMR. The compositions of the copolymer was analyzed by ultra violet(UV/Vis) spectrophotometry. The reactivity ratios of the monomer was determined by the application of Fineman-Ross(FR) and Kelen-T$\ddot{u}$d$\ddot{o}$s(KT) methods. The monomer reactivity ratios of the system and Alfrey-Price's resonance effect(Q) and polar effect(e) value for NIEA were determined as follow. The reactivity ratios of the monomer obtained from FR and KT are found to be $r_1$=0.87, $r_2$=0.98 and $r_1$=0.88, $r_2$=0.99 respectively. The Q and e values of poly(GMA-co-NPEM) calculated from $r_1$ and $r_2$ was Q= 1.31, e=0.75 respectively.

• Macromolecular Research
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• v.13 no.1
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• pp.39-44
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• 2005

Ion-exchange polymeric stationary phases presenting amino acid and amino groups were prepared by the surface grafting of glycidyl methacrylate onto a silica gel surface and subsequent amination. Three kinds of amino acids-L-arginine (Arg), D-lysine (Lys), and D-histine (His)-were used in this study. An ion-exchange polymeric stationary phase presenting ethylene diamine (EDA) was also prepared by surface graft polymerization. Separation of the model proteins bovine serum albumin (BSA), chick egg albumin (CEA), and hemoglobin (Hb) was performed using the amino acid- and amine-derived columns. In separating the CEA/BSA mixture, the resolution time of BSA was longer than that of CEA when using the EDA column, whereas the resolution time of BSA was shorter than that of CEA when using the Arg, Lys, and His columns. In the separation of the Hb/BSA mixture, the resolution time of BSA was longer than that of Hb in the EDA column, whereas the resolution time of BSA was shorter than that of Hb in the amino acid columns (D-Lys, L-Arg, and D-His).

• Nuclear Engineering and Technology
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• v.11 no.2
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• pp.119-126
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• 1979

The reaction of 4,4'-dihydroxydiphenl methane (4,4'-DPM) with glycidyl methacrylate (GMA) catalyzed by triethylbenzyl ammonium chloride (TEBAC) has been studied for the purpose of synthesis of electron beam curable prepolymer. The reaction was in good agreement with third-order kinetics. according to -d[GMA]/dt=k[TEBAC][DPM][GMA] and the apparent activation energy was about 33.4kca1/mole. However, the reaction rates were increased if tile reaction proceeded after the mixtures exposed to air for 24 hrs at room temperature. The effects of the catalyst and the difference in the reactivity between 2.2'-DPM to GMA were discussed. The plausible reaction mechanism was proposed on basis of experimental data obtained.

• Journal of Adhesion and Interface
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• v.14 no.1
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• pp.1-12
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• 2013

Multi core-shell composite particles were prepared by the water-born emulsion polymerization of various core monomers such as methyl methacrylate (MMA), ethyl methacrylate (EMA) and shell monomers such as MMA, EMA, 2-hydroxyl ethyl methacrylate (2-HEMA), glycidyl methacrylate (GMA) and methacrylic acid (MAA) in the presence of different concentrations of sodium dodecyl benzene sulfonate (SDBS). The following conclusions are drawn from the conversion, particle size and distribution, average molecular weight, molecular structure, glass transition temperature with DSC, contact angle after plasma treatment, tensile strength and isothermal decomposition kinetics. In the case of the concentration of 0.02 wt% SDBS, the conversion of MMA core-(EMA/GMA) shell composite particles was excellent as 98.5%. In the case of the concentration of 0.03 wt% SDBS, the particle size of EMA core-(MMA/GMA) shell composite particles was high as $0.48{\mu}m$. We confirmed that 3 points of glass transition temperatures appear for multi core-shell composite particles compared to 1~2 points of glass transition temperatures appear for general copolymer particles. Overall, the adhesion strength of shell composite particles was in the order of EMA/MAA > EMA/2-HEMA > EMA/GMA.

• Membrane Journal
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• v.20 no.2
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• pp.151-158
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• 2010

This paper presents the synthesis of ampholyte immobilized hollow-fiber membranes and adsorption characteristic of metallic ions. This is prepared by radiation induced grafting polymerization of an epoxy group containing Glycidyl methacrylate (GMA) onto an existing polyethylene porous hollow-fiber membrane. Ampholyte ion-exchanged alkalic group, $-NH_2$ (amine function) of Taurine (TAU) is reacted with glycidyl of GMA for the synthesis of stable membrane. However, Sodium sulfite (SS) membrane is also prepared by making chemical bonds with GMA of porous hollow-fiber membrane for the comparison of adsorption characteristic of metallic ions. These are called as TAU and SS membranes, respectively. It is shown that TAU membrane shows a steady flux, 0.9 m/h regardless of the density of TAU, while the flux of SS membrane decreases rapidly as the density of $SO_3H$ group increases. SS membrane showed a negligible flux. TAU membrane with the density 0.8 mmol/g shows the amount of metallic ions adsorbed in the following order, Cu > Cd > Mg > Sb > Pb. In general, TAU membrane with high density and reaction time showed the high amount of metallic ions adsorbed and flux.

• Applied Chemistry for Engineering
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• v.3 no.3
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• pp.499-506
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• 1992

Copolymer of Styrene and GMA(glycidyl methachylate), having reactive ratios of $r_1=0.53$, $r_2=0.44$, was synthesized in dioxane using AIBN as free radical initiator. Followed by the reaction of ethylene diamine with copolymer PGS, amine groups were introduced to the PGS(NPGS). The composition of copolymer was determined by elemental analyzer. Poly(glycidyl methacrylate) (PGMA) was obtained in benzene using AIBN as free radical initiator. The NPGS-PGMA blend of 50/50 composition was prepared by mixing these polymers in THF at $65^{\circ}C$. Glass transition temperature (Tg) of NPGS-PGMA blend was measured by DSC. The blend showed a single Tg. Accordingly, it was clear that the NPGS was compatible with PGMA. An intermolecular reaction between amine groups of NPGS and epoxy groups of PGMA imparts compatibility in the NPGS-PGMA blend. When the NPGS-PGMA blend was added to the incompatible PS-PGMA blend, PS-PGMA blend showed Tg change. Scanning Electron Micrograph(SEM) showed a fine morphology in this blend. Consequently, it was apparent that the NPGS-PGMA blend acted as a compatibilizer for the PS-PGMA blend.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.16 no.11
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• pp.1014-1018
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• 2003

A photoalignment material of a PGMAcr, poly[3-(acryloyloxy)-2-hydroxypropyl methacrylate] using a photopolymerized the acrylate unit by photo-initiator and a PGMA4Ch, poly[3(4-chalconyloxy)-2-hydroxypropyl methacrylate] using a photodimerization by chalcone group were synthesized. Also, the liquid crystal (LC) aligning capabilities on the photopolymer layers were studied. A good LC alignment with UV exposure on the PGMAcr surface can be obtained. However, the LC alignment defects were observed on the PGMA4Ch surface. The LC aligning capabilities of the PGMAcr surface by photo-initiator were better than that of the PGMA4Ch surface by chalcone group as photosensitive moiety.

• Journal of Sericultural and Entomological Science
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• v.27 no.1
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• pp.47-50
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• 1985

The physical properties of graft polymerized silk fibre were investigated with various vinyl monomers. 1. The graft polymerization of styrene and methyl methacrylate onto raw silk reduced the tenacity and elongation of raw silk due to fixation of sericin covering silk fibre in, but the styrene grafting was more effective for sericin fixation of raw silk than the methyl methacrylate one. 2. The water absorbability of glycidyl methacrylate grafted silk increased 14.6% greater than that of methyl methacrylate grafted silk at the same degree of grafting polymerization. 3. The degree of grafting polymerization was increased mostly with ethylene glycol methacrylate. The water absorbability of ethylene glycol methacrylate grafted silk was higher than that of glycidyl methacrylate or ethyl acrylate grafted silk. But the grafted silk fabric increased the fabric flexural rigidity which was negatively related with the favorability of fabric hand-touch, as compared with that of nongrafted silk fabric. 4. The evenness of graft polymerization could be improved by agitating the polymerization bath at the fixed interval by reducing the inter size deviation of grafted silk skein and the thickness deviation of grafted silk fabric.

• Elastomers and Composites
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• v.29 no.5
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• pp.444-452
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• 1994

Emulsion graft copolymerizations of vinyl monomers, butyl acrylate(BA), methyl methacrylate(MMA), 2-ethylhexyl acrylate (EHA), glycidyl methacrylate (GMA), 2-hydroxyethyl methacrylate(HEMA), methacrylonitrile(MAN), dimethylaminoethyl methacrylate(DAMA) or 2-vinyl pyridine(VP), onto carboxyl-terminated SBR latex were carried out under different experimental conditions. In case of synthesizing SBR-g-poly(butyl acrylate), the degree of grafting was increased with increasing the amount of emulsifier, polymerization temperature and the amount of initiator. Pull-out strength of resorcinol-formaldehyde-latex(RFL) adhesives formulated with modified latexes was very higher than that of RFL adhesive formulated with ungrafted latex. When the modified latexes with GMA, HEMA, MAN, DAMA or VP were used, the break occurred at cords. Peel strength of RFL adhesives formulated with SBR-g-poly(GMA), SBR-g-poly(HEMA) or SBR-g-poly(VP) was higher by about 1.3 times than that of RFL adhesives formulated with unmodified SBR against nylon cord and was higher by about 2.0 times against polyester cord.

• Macromolecular Research
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• v.16 no.2
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• pp.120-127
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• 2008

Glycidyl methacrylate linked poly(dimethylsiloxane) (GMA-PDMS) was synthesized and used as a stabilizer for the dispersion polymerization of methyl methacrylate (MMA) in supercritical $CO_2$. This study examined the effect of the concentrations of the stabilizer, 2,2'-azobisisobutyronitrile (AIBN) initiator, and MMA on the yield, molecular weight, and morphology of the poly(methyl methacrylate) (PMMA) product. PMMA was obtained in 94,6% yield using only 0,87 wt% GMA-PDMS, When the AIBN concentration was increased from 025 to 1.06 wt%, the molecular weight and particle size of the PMMA decreased from 56,600 to 21,600 and from 4.1 to $2.7{\mu}m$, whereas the particle size distribution increased from 1.3 to 1.9. The $M_n$ of the PMMA product ranged from 41,600 and 55,800 under typical polymerization conditions. The PMMA particle diameter ranged from 1.8 to $11.0{\mu}m$ and the particle size distribution ranged from 1.4 to 1.8.