• Journal of the Korean Ceramic Society
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• v.45 no.1
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• pp.1-29
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• 2008

In last two decades, an impressive progress has been recorded in terms of developing new materials or refining existing material composition/microstructure in order to obtain better performance in biomedical applications. The success of such efforts clearly demands better understanding of various concepts, e.g. biocompatibility, host response, cell-biomaterial interaction. In this article, we review the fundamental understanding that is required with respect to biomaterials development, as well as various materials and their properties, which are relevant in applications, such as hard tissue replacement. A major emphasize has been placed to present various design aspects, in terms of materials processing, of ceramics and polymer based biocomposites, Among the bioceramic composites, the research results obtained with Hydroxyapatite (HAp)-based biomaterials with metallic (Ti) or ceramic (Mullite) reinforcements as well as $SiO_2-MgO-Al_2O_3-K_2O-B_2O_3-F$ glass ceramics and stabilized $ZrO_2$ based bioinert ceramics are summarized. The physical as well as tribological properties of Polyethylene (PE) based hybrid biocomposites are discussed to illustrate the concept on how can the physical/wear properties be enhanced along with biocompatibility due to combined addition of bioinert and bioactive ceramic to a bioinert polymeric matrix. The tribological and corrosion properties of some important orthopedic metallic alloys based on Ti or Co-Cr-Mo are also illustrated. At the close, the future perspective on orthopedic biomaterials development and some unresolved issues are presented.

• Steel and Composite Structures
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• v.22 no.6
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• pp.1337-1358
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• 2016

The current study focuses on the assessment and interface response of reinforced concrete elements with composite materials (carbon fiber reinforced polymers-CFRPs, glass fiber reinforced polymers-GFRPs, textile reinforced mortars-TRM's, near surface mounted bars-NSMs). A description of the transfer mechanisms from concrete elements to the strengthening materials is conducted through analytical models based on failure modes: plate end interfacial debonding and intermediate flexural crack induced interfacial debonding. A database of 55 in total reinforced concrete columns (scale 1:1) is assembled containing elements rehabilitated with various techniques (29 wrapped with CFRP's, 5 wrapped with GFRP's, 4 containing NSM and 4 strengthened with TRM). The failure modes are discussed together with the performance level of each technique as well as the efficiency level in terms of ductility and bearing/ bending capacity. The analytical models' results are in acceptable agreement with the experimental data and can predict the failure modes. Despite the heterogeneity of the elements contained in the aforementioned database the results are of high interest and point out the need to incorporate the analytical expressions in design codes in order to predict the failure mechanisms and the limit states of bearing capacities of each technique.

• Smart Structures and Systems
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• v.19 no.1
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• pp.57-66
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• 2017

Nanocomposites reinforced with carbon nanotube fibers exhibit greater stiffness, strength and damping properties in comparison to conventional composites reinforced with carbon/glass fibers. Consequently, most of the nanocomposite research is focused in understanding the dynamic characteristics, which are highly useful in applications such as vibration control and energy harvesting. It has been observed that those nanocomposites show better stiffness when the geometry of nanotubes is straight as compared to curvilinear although nanotube agglomeration may exist. In this work the damping behavior of the nanocomposite is characterized in terms of loss factor under the presence of nanotube agglomerations. A micro stick-slip damping model is used to compute the damping properties of the nanocomposites with multiwall carbon nanotubes. The present formulation considers the slippage between the interface of the matrix and the nanotubes as well as the slippage between the interlayers in the nanotubes. The nanotube agglomerations model is also presented. Results are computed based on the loss factor expressed in terms of strain amplitude and nanotube agglomerations. The results show that although-among the various factors such as the material properties (moduli of nanotubes and polymer matrix) and the geometric properties (number of nanotubes, volume fraction of nanotubes, and critical interfacial shear stresses), the agglomeration of nanotubes significantly influences the damping properties of the nanocomposites. Therefore the full potential of nanocomposites to be used for damping applications needs to be analyzed under the influence of nanotube agglomerations.

• Structural Engineering and Mechanics
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• v.57 no.1
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• pp.105-126
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• 2016

In the present study, modelling and vibration control of axially moving laminated Carbon nanotubes/fiber/polymer composite (CNTFPC) plate under initial tension are investigated. Orthotropic visco-Pasternak foundation is developed to consider the influences of orthotropy angle, damping coefficient, normal and shear modulus. The governing equations of the laminated CNTFPC plates are derived based on new form of first-order shear deformation plate theory (FSDT) which is simpler than the conventional one due to reducing the number of unknowns and governing equations, and significantly, it does not require a shear correction factor. Halpin-Tsai model is utilized to evaluate the material properties of two-phase composite consist of uniformly distributed and randomly oriented CNTs through the epoxy resin matrix. Afterwards, the structural properties of CNT reinforced polymer matrix which is assumed as a new matrix and then reinforced with E-Glass fiber are calculated by fiber micromechanics approach. Employing Hamilton's principle, the equations of motion are obtained and solved by Hybrid analytical numerical method. Results indicate that the critical speed of moving laminated CNTFPC plate can be improved by adding appropriate values of CNTs. These findings can be used in design and manufacturing of marine vessels and aircrafts.

• Elastomers and Composites
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• v.56 no.3
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• pp.152-163
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• 2021

Liquid butadiene rubber (LqBR) is used as a processing aid and plays a vital role in the manufacture of high-performance tire tread compounds. In this study, center-functionalized LqBR (C-LqBR) was polymerized with different vinyl content via anionic polymerization. The effects of the vinyl content on the properties of the compounds were investigated by partially replacing the treated distillate aromatic extract (TDAE) oil with C-LqBR in silica-filled rubber compounds. C-LqBR compounds showed a low Payne effect and Mooney viscosity regardless of the vinyl content, because of improved silica dispersion due to the ethoxysilyl group. As the vinyl content of C-LqBR increased, the optimum cure time (t₉₀) increased owing to a decrease in the number of allylic hydrogen. Moreover, the glass transition temperature (T_g) of the compound increased, and snow traction and abrasion resistance performance decreased, whereas wet grip improved. The energy loss characteristics revealed that the hysteresis attributed to the free chain ends of C-LqBR was dominant.

• Structural Engineering and Mechanics
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• v.71 no.3
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• pp.283-290
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• 2019

In global competition manufacturing companies have to produce modern, new constructions from advanced materials in order to increase competitiveness. The aim of my research was to develop a new composite cellular plate structure, which can be primarily used for structural elements of road, rail, water and air transport vehicles (e.g. vehicle bodies, ship floors). The new structure is novel and innovative, because all materials of the components of the newly developed structure are composites (laminated Carbon Fiber Reinforced Plastic (CFRP) deck plates with pultruded Glass Fiber Reinforced Plastic (GFRP) stiffeners), furthermore combines the characteristics of sandwich and cellular plate structures. The material of the structure is much more advantageous than traditional steel materials, due mainly to its low density, resulting in weight savings, causing lower fuel consumption and less environmental damage. In the study the optimal construction of a given geometry of a structural element of a road truck trailer body was defined by single- and multi-objective optimization (minimal cost and weight). During the single-objective optimization the Flexible Tolerance Optimization method, while during the multi-objective optimization the Particle Swarm Optimization method were used. Seven design constraints were considered: maximum deflection of the structure, buckling of the composite plates, buckling of the stiffeners, stress in the composite plates, stress in the stiffeners, eigenfrequency of the structure, size constraint for design variables. It was confirmed that the developed structure can be used principally as structural elements of transport vehicles and unit load devices (containers) and can be applied also in building construction.

• Journal of Electrochemical Science and Technology
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• v.10 no.1
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• pp.61-68
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• 2019

Well aligned $SnO_2$-doped ZnO nanorods were prepared by single step or 2-step electrochemical depositions in a mixture solution of zinc nitrate hexahydrate, ammonium hydroxide solution and 0.1 M tin chloride pentahydrate. The morphologies of electrochemically deposited $SnO_2$-doped ZnO were transformed from plain (or network) structures at low reduction potential to needles on hills at high reduction potential. Well aligned ZnO was prepared at intermediate potential ranges. Reduction reagent and a high concentration of Zn precursor were required to fabricate $SnO_2$ doped ZnO nanorods. When compared to results obtained by single step electrochemical deposition, 2-step electrochemical deposition produced a much higher density of nanorods, which was ascribed to less potential being required for nucleation of nanorods by the second-step electrochemical deposition because the surface was activated in the first-step. Mechanisms of $SnO_2$ doped ZnO nanorods prepared at single step or 2-step was described in terms of applied potential ranges and mass-/charge- limited transfer.

• Steel and Composite Structures
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• v.31 no.2
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• pp.133-148
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• 2019

This paper reports on the energy absorption characteristics of a lattice-web reinforced composite sandwich cylinder (LRCSC) which is composed of glass fiber reinforced polymer (GFRP) face sheets, GFRP lattice webs, polyurethane (PU) foam and ceramsite filler. Quasi-static compression experiments on the LRCSC manufactured by a vacuum assisted resin infusion process (VARIP) were performed to demonstrate the feasibility of the proposed cylinders. Compared with the cylinders without lattice webs, a maximum increase in the ultimate elastic load of the lattice-web reinforced cylinders of approximately 928% can be obtained. Moreover, due to the use of ceramsite filler, the energy absorption was increased by 662%. Several numerical simulations using ANSYS/LS-DYNA were conducted to parametrically investigate the effects of the number of longitudinal lattice webs, the number of transverse lattice webs, and the thickness of the transverse lattice web and GFRP face sheet. The effectiveness and feasibility of the numerical model were verified by a series of experimental results. The numerical results demonstrated that a larger number of thicker transverse lattice webs can significantly enhance the ultimate elastic load and initial stiffness. Moreover, the ultimate elastic load and initial stiffness were hardly affected by the number of longitudinal lattice webs.

• Elastomers and Composites
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• v.54 no.1
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• pp.61-69
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• 2019

Poly(ethylene-co-vinyl acetate) (EVA) is a copolymer of ethylene and vinyl acetate (VA). It is important to determine the VA content of EVA, since the properties of EVA depend highly on the VA content. EVA copolymers have been used in a wide range of applications appropriate for the different VA contents. IR, NMR, and TGA are generally used for determination of the VA content of EVA copolymers. Of these, TGA is the most reliable method and can be applied to cured EVAs. Analytical methods for determination of the VA content and properties of EVA copolymers via TGA were herein reviewed. Thermal behaviors of EVA copolymers (glass transition temperature ($T_g$), melting point ($T_m$), and crystallization temperature ($T_c$)) determined by DSC were also reviewed. Analysis of the related literature revealed that the $T_g$, $T_m$, and $T_c$ decrease by about 0.46, 1.36, and $2.08^{\circ}C$, respectively, for every 1 wt% in VA content. A method for determining the degree of crosslinking of cured EVA copolymers was also reviewed, and the degree of crosslinking tends to increase with the decrease in the VA content.

• Elastomers and Composites
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• v.57 no.1
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• pp.13-19
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• 2022

Polycarbonate diol-based waterborne polyurethane (WPU) was prepared by prepolymer mixing process. The prepolymer mixture contained the polycarbonate diol, isophorone diisocyanate (IPDI), dimethylol propionic acid, triethylamine, and ethylenediamine (EDA). The NCO/OH ratio in the prepolymer was adjusted by controlling the molar ratio of IPDI, and its effects on the properties of WPU were studied. The structure of WPU was characterized by fourier transform infrared spectroscopy. The average particle size increased and viscosity decreased with increasing NCO/OH ratio and EDA content in WPU. The reduced phase separation between soft and hard segments increased glass transition temperature. The reduction in the thermal decomposition temperature could be attributed to the low bond energy of urethane and urea groups, which constituted the hard segment. Additionally, the polyurethane chain mobility was restricted, elongation decreased, and tensile strength increased. The hydrogen bond between the hard segments formed a dense structure that hindered water absorption.