• Title/Summary/Keyword: Geological storage

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The Effect of Chloride Additives and pH on Direct Aqueous Carbonation of Cement Paste (시멘트 풀의 직접수성탄산화에서 Chloride 첨가제와 pH의 영향)

  • Lee, Jinhyun;Hwang, Jinyeon;Lee, Hyomin;Son, Byeongseo;Oh, Jiho
    • Journal of the Mineralogical Society of Korea
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    • v.28 no.1
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    • pp.39-49
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    • 2015
  • Recently, carbon capture and storage (CCS) techniques have been globally studied. This study was conducted to use waste cement powder as an efficient raw material of mineral carbonation for $CO_2$ sequestration. Direct aqueous carbonation experiment was conducted with injecting pure $CO_2$ gas (99.9%) to a reactor containing $200m{\ell}$ reacting solution and the pulverized cement paste (W:C = 6:4) having particle size less than 0.15 mm. The effects of two additives (NaCl, $MgCl_2$) in carbonation were analyzed. The characteristics of carbonate minerals and carbonation process according to the type of additives and pH change were carefully evaluated. pH of reacting solution was gradually decreased with injecting $CO_2$ gas. $Ca^{2+}$ ion concentration in $MgCl_2$ containing solution was continuously decreased. In none $MgCl_2$ solution, however, $Ca^{2+}$ ion concentration was increased again as pH decreased. This is probably due to the dissolution of newly formed carbonate mineral in low pH solution. XRD analysis indicates that calcite is dominant carbonate mineral in none $MgCl_2$ solution whereas aragonite is dominant in $MgCl_2$ containing solution. Unstable vaterite formed in early stage of experiment was transformed to well crystallized calcite with decreasing pH in the absence of $MgCl_2$ additives. In the presence of $MgCl_2$ additives, the content of aragonite was increased with decreasing pH whereas the content of calite was decreased.

A Study on the Operational Plan and Acquisition Method for CO2 Carrier by Retrofitting Existing Vessels and New Ship-Building (중고선 개조와 신조에 의한 CO2 운송선 확보 및 운용방안에 관한 연구)

  • Shin, Myung-Soo;Park, Beom Jin;Ki, Min Suk;Lee, Dae Hak
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.18 no.1
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    • pp.15-21
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    • 2015
  • This paper presents the feasibility study on $CO_2$ carrier for carbon dioxide marine geological storage. Conceptual design was carried out to acquire $CO_2$ carriers by retrofitting existing vessels and new ship-building. Based on conceptual design, the acquisition cost of $CO_2$ carriers was estimated. Finally, necessary expense and number of ships were estimated based on operational plans for the assumed scenario.

Status of Manganese Nodule Samples in the Library of Marine Samples (해양시료도서관에 입고된 심해저 망간단괴 시료 현황)

  • Lee, Hyun-Bok;Kim, Wonnyon;Ko, Young-Tak;Oh, Jae-Ryong;Chi, Sang-Bum
    • Ocean and Polar Research
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    • v.36 no.4
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    • pp.515-524
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    • 2014
  • The Korea Institute of Ocean Science and Technology has acquired detailed biological, chemicophysical, and geological data in the northeastern Pacific through a manganese nodule program since 1983. Plenty of manganese nodules were collected to estimate the amount of resources by free-fall grab and box corer. The collected manganese nodules have been archived systematically in the rock and mineral storage section of the Library of Marine Samples (LIMS) since 2012. The LIMS provides essencial information on the stored samples including sample name, nodule type, sampling location, depth, and equipment. Although a high quality database of the information system is under construction, the samples have tagged information for manganese nodules like chemical composition, morphology, weight, size, abundance, and photograph. In this study, we attempted to provide information on the well-organized and easily accessible archived manganese nodule samples for future studies and to introduce the usefulness of the LIMS.

An Analysis of the Deep Geological Disposal Concepts Considering Spent Fuel Rods Consolidation (사용후핵연료봉 밀집을 고려한 심지층처분 개념 분석)

  • Lee, Jongyoul;Kim, Hyeona;Lee, Minsoo;Kim, Geonyoung;Choi, Heuijoo
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.12 no.4
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    • pp.287-297
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    • 2014
  • For several decades, many countries operating nuclear power plants have been studying the various disposal alternatives to dispose of the spent nuclear fuel or high-level radioactive waste safely. In this paper, as a direct disposal of spent nuclear fuels for deep geological disposal concept, the rod consolidation from spent fuel assembly for the disposal efficiency was considered and analyzed. To do this, a concept of spent fuel rod consolidation was described and the related concepts of disposal canister and disposal system were reviewed. With these concepts, several thermal analyses were carried out to determine whether the most important requirement of the temperature limit for a buffer material was satisfiedin designing an engineered barrier of a deep geological disposal system. Based on the results of thermal analyses, the deposition hole distance, disposal tunnel spacing and heat release area of a disposal canister were reviewed. And the unit disposal areas for each case were calculated and the disposal efficiencies were evaluated. This evaluation showed that the rod consolidation of spent nuclear fuel had no advantages in terms of disposal efficiency. In addition, the cooling time of spent nuclear fuels from nuclear power plant were reviewed. It showed that the disposal efficiency for the consolidated spent fuel rods could be improved in the case that cooling time was 70 years or more. But, the integrity of fuels and other conditions due to the longer term storage before disposal should be analyzed.

The Development of Multi-channel Electrical Conductivity Monitoring System and its Application in the Coastal Aquifer (다채널 전기전도도 모니터링 시스템의 개발과 연안지역 공내수 모니터링에 대한 적용 사례)

  • Shin, Je-Hyun;Hwang, Se-Ho;Park, Kwon-Gyu;Park, Yun-Seong;Byun, Joong-Moo
    • Geophysics and Geophysical Exploration
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    • v.8 no.2
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    • pp.156-162
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    • 2005
  • Particularly in research related to seawater intrusion the change of fluid electrical conductivity is one of major concerns, and effective monitoring can help to optimize a water pumping performance in coastal areas. Special considerations should be given to the mounting of sensors at proper depth during the monitoring design since the vertical distribution of fluid electrical conductivity is sensitive to the characteristics of seawater intrusion zone. This tells us the multi-channel electrical conductivity monitoring is of paramount consequence. It, however, is a rare event when this approach becomes routinely available in that commonly used commercial stand-alone type sensors are very expensive and inadequate for a long term monitoring of electrical conductivity or water level due to their restricted storage and difficulty of real-time control. For this reason, we have developed a real-time monitoring system that could meet these requirements. This system is user friendly, cost-effective, and easy to control measurement parameters - sampling interval, acquisition range, and others. And this devised system has been utilized for the electrical conductivity monitoring in boreholes, Yeonggwang-gun, Korea. Monitoring has been consecutively executed for 24 hours, and the responses of electrical conductivity at some channels have been regularly increased or decreased while pumping up water. It, with well logging data implemented before/after pumping water, verifies that electrical conductivity changes in the specified depths originate from fluid movements through sand layer or permeable fractured rock. Eventually, the multi-channel electrical conductivity monitoring system makes an effective key to secure groundwater resources in coastal areas.

Analysis of the Latest Trends in Mineral Resource Exploration and Mining in China and its Implications (중국의 광물자원 탐사개발 최신동향 분석 및 시사점)

  • Kim, Seong-Yong;Heo, Chul-Ho
    • Korean Journal of Mineralogy and Petrology
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    • v.35 no.1
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    • pp.75-81
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    • 2022
  • Given that China's resource research, exploration and development and resource economy policies are closely related to Korea's industrial competitiveness in the field of global mineral energy resources, it is important to establish the domestic and overseas resource development strategies. In 2020, China will revise and set standards for mineral resources to ensure efficiency in exploration and development and storage management. China's Ministry of Natural Resources has established the National Mineral Resources Plan (2021-2025), aiming to achieve national goals and strategies, and local governments at all levels are also establishing and implementing regional mineral resources plans. As a result, the supervision and management of geological mineral exploration activities have been strengthened, and the safety of industrial production management in the field of geological mineral exploration and development has been strengthened. China has developed guidelines for high-quality geological exploration, surveying and mapping, improved the level of geological mineral exploration and strengthened the mining supervision and management system. According to China's standardization of mineral resources such as solid mineral resources and petroleum gas mineral resources, a new standard system for resource management will be established in China to improve scientific understanding, rational management and utilization.

Detection of Potential Flow Paths of Leaked CO2 from Underground Storage Using Electrical Resistivity Survey (전기비저항탐사 방법에 의한 지중 저장 이산화탄소 누출 가능 경로 탐지)

  • Lim, Woo-Ri;Hamm, Se-Yeong;Hwang, Hak-Soo;Kim, Sung-Wook;Jeon, Hang-Tak
    • The Journal of Engineering Geology
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    • v.28 no.1
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    • pp.69-79
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    • 2018
  • The Korean government attempts to reduce $CO_2$ emissions by 37% to 314.7 Mt $CO_2$, down from the estimated 850.6 Mt $CO_2$ until 2030 in order to confront green house effect. In this context, in 2014, Korean government launched $CO_2$ Storage Environmental Management Research (K-COSEM) Center for carrying out pilot-scale research on $CO_2$ leakage from underground $CO_2$ storage facilities. For the detection of $CO_2$ leakage, it is necessary to identify hydrologeological and geophysical characteristics of the subject area. In the study site of Naesan-ri, Daeso-myeon, Eumseong-gun, Chungbuk Province, two times injection tests (June 28-July 24, 2017 and August 07-September 11, 2017) of $CO_2$ and $SF_6$ dissolved waters, respectively, was conducted to understand the leakage behavior of $CO_2$ from underground. The injection well was drilled to a depth of 24 m with a 21-m casing and screen interval of 21~24 m depth. Two times resistivity surveys on August 18, 2017 and September 1, 2017, were conducted for revealing the flow of the injected water as well as the electrical properties of the study site. The study results have shown that the high-resistivity zone and the low-resistivity zone are clearly contrasted with each other and the flow direction of the injected water is similar to natural groundwater flow. Besides, the low resistivity zone is widely formed from the depth of injection to the shallow topsoil, indicating that the weathered zone of high permeability has high $CO_2$ leakage potential.

Hydrogeological Performance Assessment for Underground Oil Storage Caverns (지하유류비축시설 수리안정성 평가방안)

  • 김천수;배대석;김경수;고용권;송승호
    • The Journal of Engineering Geology
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    • v.7 no.3
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    • pp.229-245
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    • 1997
  • There are Common aspects between the underground oil storage cavern and the radioactive waste disposal facility. Both facilities use appropriately the intrinsic natural berrier characteristics of the rock mass and additionally the engineered barrier system for the long term safety. The geological structures and their hydrogeological characteristics in a faactured rock mass act a major role in the safety and performance of the underground oil storage facility through the design, construction and the operation stages. Because the fracture system distributed in a fractured rock block is complicated owing to their own geometrical and hydrogeological attributes, the hydrogeological perforrmrnce of the facility would depend mainly upon the understandings of their characteristics. This study reviews the uncertainties and key issues which have to be considered to analyse the groundwater flow system in a fractured rock mass and proposes the techniques applicable to characterize the hydrogeological parameter.

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Coupled Hydrological-mechanical Behavior Induced by CO2 Injection into the Saline Aquifer of CO2CRC Otway Project (호주 오트웨이 프로젝트 염수층 내 CO2 주입에 따른 수리-역학적 연계거동 분석)

  • Park, Jung-Wook;Shinn, Young Jae;Rutqvist, Jonny;Cheon, Dae-Sung;Park, Eui-Seob
    • Tunnel and Underground Space
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    • v.26 no.3
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    • pp.166-180
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    • 2016
  • The present study numerically simulated the CO2 injection into the saline aquifer of CO2CRC Otway pilot project and the resulting hydrological-mechanical coupled process in the storage site by TOUGH-FLAC simulator. A three-dimensional numerical model was generated using the stochastic geological model which was established based on well log and core data. It was estimated that the CO2 injection of 30,000t over a period of 200 days increased the pressure near the injection point by 0.5 MPa at the most. The pressure increased rapidly and tended to approach a certain value at an early stage of the injection. The hydrological and mechanical behavior observed from the CO2 flow, effective stress change and stress-strength ratio revealed that the CO2 injection into the saline aquifer under the given condition would not have significant effects on the mechanical safety of the storage site and the hydrological state around the adjacent fault.

Establishment of Tailing Disposal Scenario in Open-Pit and Surface Pillar Stability Analysis (노천채굴적 내 광미 적치 시나리오 구축 및 천반 수평필러 안정성 분석)

  • Il-Seok Kang;Jae-Joon Song;Thomas Pabst
    • Tunnel and Underground Space
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    • v.34 no.1
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    • pp.54-70
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    • 2024
  • Utilization of completed open-pit for mining waste disposal is an alternative method of tailing storage facility (TSF), which can minimize the area and cost required for the installation of TSF. However, long-term tailing disposal into open-pit has a potential risk of reducing mechanical stability of surrounding rock mass by acting as an additional load. In this research, a realistic open-pit tailing disposal scenario of 60,400 hours was established based on the case of Marymia gold mine, Australia. Mechanical stability of surface pillar between open-pit and underground stope was analyzed numerically by using Sigma/W, under different stope geometry and rock mass conditions. Simulation results showed that long-term tailing disposal into open-pit can significantly increase the failure probability of surface piller. This result suggests that mechanical stability of mine geometry should be conducted beforehand of open-pit tailing disposal.