• 한국진공학회:학술대회논문집
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• 한국진공학회 2015년도 제49회 하계 정기학술대회 초록집
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• pp.126.1-126.1
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• 2015

A quantitative relationship between Leidenfrost point and surface characteristics such as surface material and roughness is investigated. Based on the relationship, we have fabricated the surfaces with their Leidenfrost points (LFP) tuned by controlling surface coating and structures. As discovered by Leidenfrost, liquids placed on a hot plate levitate on the gas phase-air gap formed by the vaporization of liquids. This phenomenon is called 'Leidenfrost effect'. A change of LFP has attracted many researchers for several years but the ability to tune LFP is still a remaining issue. Many of previous work has progressed for various conditions so the systematic approach and analysis are needed to clearly correlate the LFP and the surface conditions. In this report, we investigate a relation of surface energy and LFP using various coating materials such as Octadecyltrichlorosilane (OTS) and 1H, 1H, 2H, 2H-Perfluorooctyltrichlorosilane (FOTS). Also, we analyze how surface roughness affects LFP via surface micro structuring with ICP-RIE fabrication process. The improved understanding can have potential applications such as the control of liquid droplet behavior at elevated temperatures for efficient cooling system.

• 산업기술연구
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• 제39권1호
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• pp.41-45
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• 2019

Hydrogen sulfide ($H_2S$) is mainly produced along with methane and hydrocarbons in many gas fields as well as hydrodesulfurization processes of crude oils containing sulfur compounds and the emission of $H_2S$ has a considerable effect on both environmental problem and human health aspects due to formation of, e.g. acid rain and smog. In recent years, ionic liquids (ILs) have been proposed as the most promising solvents for $CO_2$ and hazardous pollutants capture, such as $H_2S$ and sulfur dioxide ($SO_2$). In this work, we demonstrate the use of the predictive COSMO-SAC model for the prediction of Henry's law constant of $H_2S$ in ILs. Furthermore, the method is used to screen for potential IL candidates for $H_2S$ capture from a set of 2,624 ILs formed from 82 cations and 32 anions. The effects of cation on the Henry's law constant of $H_2S$ such as (i) the variation of the alkyl chain length on cation, (ii) the substituent of methyl group ($-CH_3$) for H in C(2) position and (iii) the change of ring structure for cation family are clearly predicted by COSMO-SAC model.

• 공학논문집
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• 제2권1호
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• pp.147-149
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• 1997

이산화질소는 Linde Molecular Sieve 칼럼에 흡수된 물에 의해 일산화질소로 급속히 전환된다. 합성된 파형은 칼럼에 도입된 순수 일산화질소의 것과 구별할 수 없는 것이다. 따라서 저비점 일산화질소로 전환함으로써 유기분배액의 산화의 복잡성은 미연에 방지된다.

• 한국가스학회지
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• 제27권1호
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• pp.63-69
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• 2023

대한민국은 세계 1위의 반도체 생산 국가임에도 불구하고 산업 보호를 위한 현장의 폐쇄성으로 대부분의 연구가 단순한 물질 위험에 대한 위험성평가로 이루어지고 있다. 산업 안전 측면에서 유해위험물질의 누출 상태를 파악하는 가스 감지기 등의 모니터링 시스템 등을 구축하고 있으나, 누출 시 유해위염 물질을 효과적으로 배기하기 위한 연구는 최근에서야 시작되었다. 인화성 물질이 다량 취급되는 반도체 제조설비(가스박스)는 현재 가스 감지기 및 공기투입구를 막는 방법으로 안전관리를 하고 있는데, 공기투입구가 없으면 박스 내부를 음압으로 관리할 수는 있으나 내부 기류가 원활히 생성되지 않아 인화성 물질 누출 시 단시간 희석이 어렵다. 따라서 본 연구에서는 여러 기준들을 기본으로 하여 가스박스 규모에 따른 덕트 사이즈의 결정, 공기 투입구의 적정크기 연구를 통하여 인화성 누출 시 유해화학물질이 외부로 노출되지 않으면서 배기 성능 요구량을 최소로 할 수 있는 최적 배기 설계를 해보고자 한다.

• 한국안전학회지
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• 제29권6호
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• pp.68-75
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• 2014

It is very important to classify explosion hazardous area (EHA) suitably and to use proper explosion-proof electric installations for facilities using flammable gases and liquids. In the past, various examples in the Notification of Ministry of Employment and Labor were referred to in classifying EHA. But, at present, many companies use the hypothetical volume in Korean Standards (KS). This study reviews the validity of EHA classification based on the hypothetical volume by comparing the calculated radii of EHA with those obtained by a consequence analysis program called PHAST and a mathematical approach in British Standards (BS). The radii of EHA by the hypothetical volume were found to be slightly larger than those by the other two methods. This was attributed to rather conservative uses of a safety factor(k) and a correction factor(f) for availability of ventilation in calculating the hypothetical volume. Since the differences are not so conspicuous, however, it is concluded that the hypothetical volume in KS is a valid means for the classification of EHA. This study also presents a table of the radii of EHA for easy reference by small-scale companies using city gas, C3-LPG and flammable liquid(toluene), respectively. The table consists of 25 leakage scenarios corresponding to combinations of 5 pipe(nozzle) sizes and 5 operating conditions for each flammable gas and liquid.

• 한국수소및신에너지학회논문집
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• 제25권3호
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• pp.247-254
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• 2014

The synthesis of Fischer-Tropsch oil is the catalytic hydrogenation of CO to give a range of products, which can be used for the production of high-quality diesel fuel, gasoline and linear chemicals. Our cobalt based catalyst was prepared Co/alumina, silica and titania by the incipient wet impregnation of the nitrates of cobalt and promoter with supports. Cobalt catalysts was calcined at $350^{\circ}C$ before being loaded into the FT reactors. After the reduction of catalyst has been carried out under $450^{\circ}C$ for 24hrs, FT reaction of the catalyst has been carried out at GHSV of 4,000/hr under $200^{\circ}C$ and 20atm. From these test results, we have obtained the results as following ; in case of 12wt% Co-supported $Al_2O_3$, $SiO_2$ and $TiO_2$ catalysts, maximum activities of the catalysts were appeared at the promoters of Mn, Mo and Ce respectively. The activity of 12wt% $Co/Al_2O_3$ added a Mn promoter was about 3 times as high as that of 12wt% $Co/Al_2O_3$ catalyst without promoters. When it has been the experiment at the range of reaction temperature of $200{\sim}220^{\circ}C$ and GHSV of 1,546~5,000/hr, the results have shown generally increasing the activities with the increase of reaction temperature and GHSV.

• 한국수소및신에너지학회논문집
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• 제25권2호
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• pp.114-121
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• 2014

The synthesis of Fischer-Tropsch oil is the catalytic hydrogenation of CO to give a range of products, which can be used for the production of high-quality diesel fuel, gasoline and linear chemicals. Our cobalt catalyst was prepared Co/alumina, Co/silica and Co/titania by the incipient wetness impregnation of the nitrates of cobalt with supports. Co-based catalysts was calcined at $400^{\circ}C$ before being loaded into the FT reactors. After the reduction of catalyst has carried out under $450^{\circ}C$, FT reaction of the catalyst has carried out at GHSV of 4,000 under $200^{\circ}C$ and 20atm. From test results, the order of increasing activity for the catalyst was Co/alumina > Co/silica > Co/titania. When the content of Co metal such as 5, 12, 20 and 30wt% was changed, an CO conversion increased as the content of Co metal increased. The activity of catalyst has obtained the best value at 12wt% Co content.

• EDISON SW 활용 경진대회 논문집
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• 제4회(2015년)
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• pp.151-155
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• 2015

The molecular interactions between the nucleic acid bases and water molecules are important in organism. Despite Adenine-Thymine Hoogsteen base pair and Guanine-Cytosine Watson-Crick base pair have been demonstrated to be most stable in a gas phase, the effect of water on the stability of these base pairs remains elusive. Here we report the structural and thermodynamic characteristics on possible Adenine-Thymine and Guanine-Cytosine base pairs in a gas phase as well as in an aqueous phase by using quantum mechanical method and statistical mechanical calculations. First, we optimized the direct base-pair interaction energies of four Adenine-Thymine base pairs (Hoogsteen base pair, reverse Hoogsteen base pair, Watson-Crick base pair, and reverse Watson-Crick base pair) and three Guanine-Cytosine base pairs (GC1 base pair, GC2 base pair, and Watson Crick base pair) in a gas phase at the $B3LYP/6-31+G^{**}$ level. Then, the effect of solvent was quantified by the electronic reorganization energy and the solvation free energy by statistical mechanical calculations. Thereby, we discuss the effect of water on the stability of Adenine-Thymine and Guanine-Cytosine base pairs, and argue why Adenine-Thymine Watson-Crick base pair and Guanine-Cytosine Watson-Crick base pair are most stable in an aqueous environment.

• 한국안전학회지
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• 제33권4호
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• pp.21-29
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• 2018

In many companies handling flammable liquids, explosion-proof electrical equipment have been installed according to the Korean Industrial Standards (KS C IEC 60079-10-1). In these standards, hazardous area for explosive gas atmospheres has to be classified by the evaluation of the evaporation rate of flammable liquid leakage. The evaporation rate is an important factor to determine the zones classification and hazardous area distance. However, there is no systematic method or rule for the estimation of evaporation rate in these standards and the first principle equations of a evaporation rate are very difficult. Thus, it is really hard for industrial workplaces to employ these equations. Thus, this problem can trigger inaccurate results for evaluating evaporation range. In this study, empirical models for estimating an evaporation rate of flammable liquid have been developed to tackle this problem. Throughout the sensitivity analysis of the first principle equations, it can be found that main factors for the evaporation rate are wind speed and temperature and empirical models have to be nonlinear. Polynomial regression is employed to build empirical models. Methanol, benzene, para-xylene and toluene are selected as case studies to verify the accuracy of empirical models.

• 멤브레인
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• 제30권3호
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• pp.149-157
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• 2020

유기 양이온과 유기/무기 음이온을 포함하고 있는 이온성 액체는 저온 용융 염의 종류이며 이산화탄소 분리 기능에 대한 잠재력을 갖고 있다. 지구 온난화와 기후 변화의 문제점을 극복하기 위해 이온성 액체를 기반으로 한 막을 개발하여 연도가스에서 이산화탄소를 걸러내는 연구가 활발히 진행되고 있다. 본 리뷰에서는 홀로 설 수 있는 중합 이온성 액체(PIL), 이온성 액체와 이온성 액체 복합 막의 혼합의 기술이 논의될 것이다. 새로운 이온성 액체의 모노머 도입, 그리고 중합 이온성 액체 막과 복합 막의 미세구조변형은 막의 기계적 특성을 향상시켜 가스투과율과 선택도를 크게 향상 시키는데 시용되어 왔다. 이온성 액체 모너머의 양이온과 음이온의 다양한 변형은 막의 가스 분리성에 큰 영향이 있다.