• Bulletin of the Korean Chemical Society
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• v.22 no.7
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• pp.703-708
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• 2001

K2NiF4-type organic-based perovskites of the (C4H9NH3)2FexPb1-xCl4 (x=0.00, 0.25, 0.50, and 0.75) system have been synthesized using a low-temperatu re solution method under a flowing argon gas. When stoichiometric butylamine, iron chloride, and lead chloride are mixed, a yellow solution are obtained from slow cooling of 90 to -10 $^{\circ}C.$ The final product is a plate-like yellow crystal. The X-ray crystallographic analysis has been carried out using XRD in the range of $5^{\circ}{\leq}$ 2${\theta}$ ${\leq}80^{\circ}.$ The local symmetry around the absorbing Pb atom of the samples has been determined by the EXAFS spectroscopic study. The crystals assign to orthorhombic system by the XRD analysis. The FT-IR spectra are analyzed in the range of 600 to 3300 cm-1 . DSC and TGA are measured to detect thermal stability between 30 and 300 $^{\circ}C.$ Two endothermic peaks are detected in all samples. The electrical conductivity has been measured using the four-probes technique for the (C4H9NH3)2FexPb1-xCl4 system in 300-460 K. Photoluminescence phenomenon was also investigated at room-temperature.

• Journal of the Korean Society of Propulsion Engineers
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• v.6 no.4
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• pp.1-6
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• 2002

A numerical heat transfer analysis and the structural analysis were performed for the design of sub-scale combustion chamber's coolant passage. The heat flux through the combustion chamber wall was estimated by 2-D heat transfer analysis of compressible hot gas and the result was applied as a thermal boundary condition of 3-D analysis. The heat flux estimated by the present method agreed well with the experimental correlation and proved to be insensitive to cooling condition. So the same thermal boundary condition was applied for various operating conditions. The maximum temperature of combustion chamber wall was predicted by 3-D analysis for single coolant passage and the result will be used for the development of a regeneratively cooled combustion chamber. Also estimated were the stress distribution and structural safety of coolant passage through the static structural analysis.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.12 no.3
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• pp.258-266
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• 2000

Experimental investigation and cycle simulation of a capacity modulation of a heat pump system using a hydrofluorocarbon (HFC) refrigerant mixture, R32/134a as an alternative to R22, have been done. In the cycle simulation, the refrigeration system was operated by assigning the temperatures of the external heat transfer fluids with the heat exchangers generalized by an average effective temperature difference. Heating capacity, cooling capacity, and coefficient of performance (COP) of the system were investigated at several operating conditions. Experimental apparatus which had a refrigeration part and a composition changing part was built, and the performance of the heat pump system filled with R32/134a mixture was investigated. A gas-liquid separator was used in the experiment to change the composition by collecting the vapor and the liquid Phase separately, The mass fraction of the charged refrigerant in the heat pump system was 40/60 and 70/30 by weight percentage. The composition of the refrigerant with initial composition of 40/60 varied from 29/71 to 41/59 in the refrigeration cycle. For the refrigerant with initial composition of 70/30, the composition varied from 65/35 to 75/25.

• The Journal of Sustainable Design and Educational Environment Research
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• v.17 no.3
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• pp.1-8
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• 2018

We suggest improvement direction of energy-saving design based on analysis of current situation in school facilities. School facilities have large area among public buildings. While the number of students is decreasing, the number of school and energy consumption is increasing year after year. School facilities have excellent heat insulation property, but it requires further examination about excessive heat insulation plan. School facilities are using gas heat pump actively for cooling and heating, but has difference in use ratio of ground source heat pump by region. Thus School facilities requires active using of ground source heat pump and BIPV(Building Integrated Photovoltaic System).

• Journal of the Korean Society for Geothermal and Hydrothermal Energy
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• v.14 no.4
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• pp.1-6
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• 2018

In this study, the energy consumption of the typical floor was compared by the total energy comsumption of the building in highrise building. In gerneral, many researchers are studying on the typical floor in highrise buildings for avoiding complexity in energy simulation. But few papers are studied on energy consumption along the floors. In the model bulding, the energy consumption data were acquired by BEMS system in 2011. According the data, the total net energy consumption was $193.99kWh/m^2$ for all area and the total net energy consumption was $247.61kWh/m^2$ for HVACR area. The total electricity and gas energy are used 47.7% for heating and cooling, 33.5% for lighting and plug, 12.9% for conveyance power and 5.9% for restaurant. In comparison of only ground floor, amount of energy consumption in the lobby is 10%, and 90% of total energy consumption is used in the typical floor. For this result, energy simulation on the typical floor is acceptable for calculating the total energy consumption in the highrise building.

• Journal of ILASS-Korea
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• v.27 no.2
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• pp.66-76
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• 2022

This study presents a prediction methodology of transport properties using the methane-based TRAPP (m-TRAPP) method in a wide range of temperature and pressure conditions including both subcritical and supercritical regions, in order to obtain thermo-physical properties for hydrocarbon aviation fuels and their products resulting from endothermic reactions. The viscosity and thermal conductivity are predicted in the temperature range from 300 to 1000 K and the pressure from 0.1 to 5.0 MPa, which includes all of the liquid, gas, and the supercitical regions of representative hydrocarbon fuels. The predicted values are compared with those data obtained from the NIST database. It was demonstrated that the m-TRAPP method can give reasonable predictions of both viscosity and thermal conductivity in the wide range of temperature and pressure conditions studied in this paper. However, there still exists large discrepancy between the current data and established values by NIST, especially for the liquid phase. Compared to the thermal conductivity predictions, the calculated viscosities are in better agreement with the NIST database. In order to consider a wide range of conditions, it is suggested to select an appropriate method through further comparison with another improved prediction methodologies of transport properties.

• Journal of the Korean Society of Propulsion Engineers
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• v.26 no.6
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• pp.10-20
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• 2022

The present study developed a design code for preburner of staged combustion cycle engines, which calculates preburnt gas at high-pressure oxidizer-rich conditions and predicts conjugate heat transfer and hydraulics of cryogenic fluid flow through cooling passages. It has been written based on the open-source library Cantera, into which this study has incorporated new source codes to predict correctly non-ideal thermodynamics and transport anomalies of the cryogenic fluid. For a preburner of 100 tonf-class booster engine currently under preliminary design, the present code demonstrated predictive capability and usability as a design code by comparing with CFD simulation.

• Journal of the Society of Naval Architects of Korea
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• v.60 no.3
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• pp.146-154
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• 2023

Efforts have been made to reduce the greenhouse gas emissions from ships by limiting the energy efficiency index, and net zero CO₂ emission was proposed recently. The most ideal measure to achieve zero emission ship is electrification, and fuel cells are considered as a practical power source of the electrified propulsion system. The electric efficiency in the electrochemical reaction of fuel cells can be achieved up to 60% practically. The remaining energy is converted to heat energy but most of them are dissipated by cooling. In the author's previous research, a hybrid propulsion system utilizing not only electricity but also heat was introduced by combining electric motor and steam turbine. In this article, long term efficiency is evaluated for the introduced hybrid propulsion system by considering a virtual 24,000 TEU class container carrier model. To reflect a more practical operating condition, the actual navigation data of a similar real ship in the real world were collected from automatic identification system data and applied. From the result, the overall efficiency of the hybrid propulsion system is expected to be higher than a conventional electric propulsion fuel cell ship by 30%.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.58 no.4
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• pp.359-366
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• 2022

In this study, the load fluctuation of the main engine is considered to be a disturbance for the jacket coolant temperature control system of the low-speed two-stroke main diesel engine on the ships. A nonlinear PID temperature control system with satisfactory disturbance rejection performance was designed by rapidly transmitting the load change value to the controller for following the reference set value. The feed-forwarded load fluctuation is considered the set points of the dual loop control system to be changed. Real-coded genetic algorithms were used as an optimization tool to tune the gains for the nonlinear PID controller. ITAE was used as an evaluation function for optimization. For the evaluation function, the engine jacket coolant outlet temperature was considered. As a result of simulating the proposed cascade nonlinear PID control system, it was confirmed that the disturbance caused by the load fluctuation was eliminated with satisfactory performance and that the changed set value was followed.

• Transactions of the Korean hydrogen and new energy society
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• v.35 no.1
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• pp.97-104
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• 2024

In this study, combustion experiments were conducted to assess engine performance and exhaust gas characteristics using four blends of 1-pentanol and diesel as fuel in a naturally aspirated 4-stroke diesel engine. The blending ratios of 1-pentanol were 5, 10, 15, and 20% by volume. The experiments were carried out under four different engine torque conditions (6, 8, 10, and 12 Nm) while maintaining a constant engine speed of 2,000 rpm for all fuel types. The results showed that the use of 1-pentanol/diesel blended fuel generally led to a decrease in brake thermal efficiency, attributed to the low calorific value of the blend and the cooling effect due to the latent heat of vaporization. Additionally, both brake specific energy consumption and brake specific fuel consumption increased. However, the use of the blended fuel resulted in a general decrease in NOx concentration, a decrease in CO concentration except some conditions, and a reduction in smoke opacity across all conditions.